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Phenylphosphonic acid

Product Name
Phenylphosphonic acid
CAS No.
1571-33-1
Chemical Name
Phenylphosphonic acid
Synonyms
MPCP;PPOA;Benzolphosphonsαure;BENZENEPHOSPHONIC ACID;phenyl-phosphonicaci;PHENYLPHOSPHONIC ACID;Phosphonicacid,phenyl-;PhenylphosphonicAcid>Phenylphosphonicacid,98%;PHENYL PHOSPHODICHLORIDATE
CBNumber
CB8669061
Molecular Formula
C6H7O3P
Formula Weight
158.09
MOL File
1571-33-1.mol
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Phenylphosphonic acid Property

Melting point:
162-164 °C (lit.)
Boiling point:
241-243 °C(lit.)
Density 
1.412 g/mL at 25 °C(lit.)
vapor pressure 
0-0Pa at 20-25℃
refractive index 
n20/D 1.523(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Crystalline Powder
pka
pK1:1.83;pK2:7.07 (25°C)
color 
White to off-white
Water Solubility 
40.4 g/100 mL (25 ºC)
BRN 
2245168
LogP
-3.3-0.086 at 20-25℃ and pH4-7
Surface tension
71.2mN/m at 1g/L and 20℃
CAS DataBase Reference
1571-33-1(CAS DataBase Reference)
EPA Substance Registry System
Phosphonic acid, phenyl- (1571-33-1)
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Safety

Hazard Codes 
C,Xn
Risk Statements 
34-37-41-37/38-22-38
Safety Statements 
26-39-37/39-45-36/37/39
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
RTECS 
TD4393000
10
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29319090
Toxicity
mouse,LD50,intraperitoneal,110mg/kg (110mg/kg),"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 2, Pg. 55, 1950.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
P29006
Product name
Phenylphosphonic acid
Purity
98%
Packaging
5g
Price
$29.94
Updated
2024/03/01
Sigma-Aldrich
Product number
P29006
Product name
Phenylphosphonic acid
Purity
98%
Packaging
100g
Price
$56.9
Updated
2024/03/01
TCI Chemical
Product number
P0204
Product name
Phenylphosphonic Acid
Purity
>98.0%(T)
Packaging
25g
Price
$23
Updated
2024/03/01
TCI Chemical
Product number
P0204
Product name
Phenylphosphonic Acid
Purity
>98.0%(T)
Packaging
100g
Price
$58
Updated
2024/03/01
Alfa Aesar
Product number
B22939
Product name
Phenylphosphonic acid, 98%
Packaging
100g
Price
$63.65
Updated
2024/03/01
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Phenylphosphonic acid Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder

Uses

Intermediate in antifouling paint agents; catalyst in organic reactions.

Uses

Phenylphosphonic acid additive used with Noyori's catalyst for oxidation of sulfides to sulfones. Used as additive of unsaturated polyester PU resin. It also can be added into nylon to improve its polymerization degree. It can be used as extreme pressure agent of lube; used as catalyst of carboxylic acid & alcohol reaction; it can be used as fire retarding treatment of fiber used asganic materials.

Definition

ChEBI: Phenylphosphonic acid is a member of benzenes.

Hazard

Highly toxic.

Purification Methods

It is best to recrystallise it from H2O by concentrating an aqueous solution to a small volume and allowing to crystallise. Wash the crystals with ice cold H2O and dry them in a vacuum desiccator over H2SO4. [Lecher et al. J Am Chem Soc 76 1045 1954.] pK2 5 values in H2O are 7.07, and in 50% EtOH 8.26. [Jaffé et al. J Am Chem Soc 75 2209 1953, IR: Daasch & Smith Anal Chem 23 853 1951, Beilstein 16 IV 1068.]

Phenylphosphonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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Phenylphosphonic acid Suppliers

CHEMICAL LAND21
Tel
--
Fax
--
Email
sales21@chemicalland21.com
Country
South Korea
ProdList
6303
Advantage
74
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View Lastest Price from Phenylphosphonic acid manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Phenylphosphonic acid 1571-33-1
Price
US $40.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-05-17
Hebei Weibang Biotechnology Co., Ltd
Product
Phenylphosphonic acid 1571-33-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Yanxi Chemical Co., Ltd.
Product
Phenylphosphonic acid 1571-33-1
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-13

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