2-BROMO-5-NITROANISOLE

Product Name: 2-BROMO-5-NITROANISOLE
CAS No.: 77337-82-7
Chemical Name: 2-BROMO-5-NITROANISOLE
Synonyms: 2-Bromo-5-nitroanisoL;2-BROMO-5-NITROANISOLE;2-Bromo-5-nitroanisole >2-Bromo-5-nitroanisole,98%;2-bromo-5-nitrobenzyl ether;2-BroMo-5-nitroanisole, 97+%;4-BROMO-3-METHOXYNITROBENZENE;2-Methoxy-4-nitrobromobenzene;2-BroMo-5-nitroanisole, 98% 10GR;1-BROMO-2-METHOXY-4-NITROBENZENE
CBNumber: CB8719656
Molecular Formula: C7H6BrNO3
Formula Weight: 232.03
MOL File: 77337-82-7.mol

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2-BROMO-5-NITROANISOLE Property

Melting point:: 99-103 °C
Boiling point:: 302.1±22.0 °C(Predicted)
Density: 1.640±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Water Solubility: Insoluble in water
form: Crystalline Powder
color: Light brown
λmax: 324nm(EtOH)(lit.)
BRN: 2520496
CAS DataBase Reference: 77337-82-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 24/25-26
Hazard Note: Irritant
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B3418
Product name: 2-Bromo-5-nitroanisole
Purity: >98.0%(GC)
Packaging: 5g
Price: $77
Updated: 2025/07/31

TCI Chemical

Product number: B3418
Product name: 2-Bromo-5-nitroanisole
Purity: >98.0%(GC)
Packaging: 25g
Price: $306
Updated: 2025/07/31

TRC

Product number: B688118
Product name: 2-Bromo-5-nitroanisole
Packaging: 5g
Price: $75
Updated: 2021/12/16

ChemScene

Product number: CS-W014685
Product name: 2-Bromo-5-nitroanisole
Packaging: 100g
Price: $89
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0018783
Product name: 2-BROMO-5-NITROANISOLE
Purity: 95.00%
Packaging: 1G
Price: $127.05
Updated: 2021/12/16

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2-BROMO-5-NITROANISOLE Chemical Properties,Usage,Production

Chemical Properties

light brown crystalline powder

Synthesis

97-52-9

77337-82-7

General procedure for the synthesis of 2-bromo-5-nitroanisole from 2-methoxy-4-nitroaniline: a catalytic amount of copper bromide (1 mol%) was added to a solution of 2-methoxy-4-nitroaniline (2.5 mmol) in acetonitrile (30 ml), followed by camphorsulfonic acid (3.0 mmol), sodium nitrite or tert-butyl nitrite (3.0 mmol), and tetrabutylammonium bromide (5.0 mmol). The reaction mixture was stirred at 60°C for 24 h (Tables 1 and 2). Nitrogen release was observed immediately during the reaction. After completion of the reaction (confirmed by β-naphthol test and thin layer chromatography), the solvent was removed using a rotary evaporator. The residue was washed with water and extracted with dichloromethane. The organic phases were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure. Finally, purification by column chromatography using a hexane/dichloromethane solvent mixture as eluent gave the pure product 2-bromo-5-nitroanisole. The physical properties and 1H NMR data of the product were consistent with the commercially available analytically pure sample.

References

[1] Tetrahedron, 2013, vol. 69, # 16, p. 3511 - 3517
[2] Tetrahedron, 2010, vol. 66, # 37, p. 7418 - 7422
[3] Tetrahedron Letters, 2010, vol. 51, # 51, p. 6769 - 6771
[4] Chemical and Pharmaceutical Bulletin, 2014, vol. 62, # 10, p. 979 - 988
[5] Journal of the American Chemical Society, 1935, vol. 57, p. 1592,1594

2-BROMO-5-NITROANISOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-5-NITROANISOLE Suppliers

Americas 1 Belgium 1 China 156 Europe 2 Germany 4 India 10 Japan 2 The Netherlands 2 United Kingdom 13 United States 25 Global 216

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View Lastest Price from 2-BROMO-5-NITROANISOLE manufacturers

Henan Fengda Chemical Co., Ltd

Product: 2-BROMO-5-NITROANISOLE 77337-82-7
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-25

Honest Joy Holdings Limited

Product: 2-BROMO-5-NITROANISOLE 77337-82-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.8%
Supply Ability: 100 tons
Release date: 2022-01-14

Shaanxi Dideu Medichem Co. Ltd

Product: 2-Bromo-5-nitroanisole 77337-82-7
Price: US $0.00-0.00/Kg
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100 tons
Release date: 2020-01-10

77337-82-7, 2-BROMO-5-NITROANISOLERelated Search:

2-bromo-5-nitrobenzaldehyde 1-CYANO-2-BROMO-5-NITROBENZENE 4-BROMO-3-NITROANISOLE 2-BROMO-5-NITROETHOXYBENZENE 1-Bromo-4-nitrobenzene 2-Bromoanisole 4-BROMO-3-METHOXYANILINE 2-BROMO-5-NITROANISOLE 3-BROMO-5-NITROANISOLE 2-BROMO-4-NITROANISOLE 95%,2-BROMO-4-NITROANISOLE 2-Bromo-3-nitroanisole 99%,2-BROMO-3-NITROANISOLE 4-BROMO-2-NITROANISOLE 3-BROMO-4-NITROANISOLE 3-Bromo-2-nitroanisole 5-amino-2-bromophenol 1-bromo-2,5-dimethoxy-4-nitrobenzene 2-Bromo-4-nitrophenol 3-BROMO-4-NITROANISOLE 95%

4-BROMO-3-METHOXYNITROBENZENE

1-BROMO-2-METHOXY-4-NITROBENZENE

2-BroMo-5-nitroanisole, 98% 10GR

2-BroMo-5-nitroanisole, 97+%

2-BROMO-5-NITROANISOLE

2-Bromo-5-nitroanisole,98%

2-Methoxy-4-nitrobroMobenzene[2-BroMo-5-nitroanisole]

2-Bromo-5-nitroanisoL

2-Bromo-5-nitroanisole &gt

Benzene, 1-bromo-2-methoxy-4-nitro-

2-BROMO-5-NITROANISOLE ISO 9001：2015 REACH

2-Bromo-5-nitroanisole[2-Methoxy-4-nitrobromobenzene

2-bromo-5-nitrobenzyl ether

2-Methoxy-4-nitrobromobenzene

77337-82-7

Alcohols

Building Blocks

C7 to C8

Chemical Synthesis

New Products for Chemical Synthesis

Nitrogen Compounds

Organic Building Blocks

Oxygen Compounds

Aromatic Halides (substituted)

Phenyls & Phenyl-Het

Anisole

Miscellaneous

Anisoles, Alkyloxy Compounds & Phenylacetates

Bromine Compounds

Nitro Compounds

Phenyls & Phenyl-Het