4-Bromobenzylamine Property

Melting point:

25 °C(lit.)

Boiling point:

110-112 °C30 mm Hg(lit.)

Density 

1.473 g/mL at 25 °C(lit.)

refractive index 

1.5855-1.5875

Flash point:

>230 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2–8 °C

form 

Liquid

pka

8.85±0.10(Predicted)

color 

Clear colorless

CAS DataBase Reference

3959-07-7(CAS DataBase Reference)

NIST Chemistry Reference

p-Bromobenzylamine(3959-07-7)

Safety

Hazard Codes 

C

Risk Statements 

34-21/22

Safety Statements 

26-28-36/37/39-45

RIDADR 

UN 3259 8/PG 2

WGK Germany 

3

HazardClass 

8

PackingGroup 

Ⅱ

HS Code 

29214990

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

4-Bromobenzylamine Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

4-Bromobenzylamine (p-Bromobenzylamine) may be used to synthesize 7-[(p-bromobenzyl)ureido]-7,8-dihydro-α-bisabolene.
It may be used to synthesize the following 4-biphenylmethylamine derivatives:

• (4′-fluoro-4-biphenyl)methylamine
• (4′-methoxy-4-biphenyl)methylamine
• (2′-methoxy-4-biphenyl)methylamine
• (3′-cyano-4-biphenyl)methylamine

General Description

4-Bromobenzylamine (BBA), also known as p-bromobenzylamine, is an aryl bromide. The selective formation of nitrile or imine from BBA in the presence of red copper has been reported. The formal [4+4] reaction of BBA to form 2,6,9-triazabicyclo[3.3.1]nonane derivatives has been investigated.