ChemicalBook > CAS DataBase List > 2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine

2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine

Product Name
2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine
CAS No.
13223-43-3
Chemical Name
2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine
Synonyms
5,7-DIMETHOXY-[1,2,4]TRIAZOLO[1,5-A]PYRIMIDIN-2-AMINE;Pyroxsulam Metabolite ADTP;2-Amino-5,7-Dimethoxy-1,2,4-Tr;5,7-Dimethoxy-[1,2,4]triazolo[1,5-α]pyrimidin-2-amine;2-amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine;[1,2,4]Triazolo[1,5-a]pyrimidin-2-amine,5,7-dimethoxy-;2-Amino-5,7-Dimethoxy-1,2,4-Triazole-[1,5-A]-Pyrimidine;ADTP/2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine;2-Amino-5,7-Dimethoxy-1,2,4-Triazolo[1,5-A]Pyrimidine(Adtp);2- amino -5,7- dimethoxy -1,2,4- triazino [1,5-a] pyrimidine
CBNumber
CB8843526
Molecular Formula
C7H9N5O2
Formula Weight
195.18
MOL File
13223-43-3.mol
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2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine Property

Density 
1.61±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
3.85±0.30(Predicted)
CAS DataBase Reference
13223-43-3(CAS DataBase Reference)
EPA Substance Registry System
[1,2,4]Triazolo[1,5-a]pyrimidin-2-amine, 5,7-dimethoxy- (13223-43-3)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

Biosynth Carbosynth
Product number
FD143997
Product name
5,7-Dimethoxy-[1,2,4]triazolo[1,5-a]pyrimidin-2-amine
Packaging
100mg
Price
$300
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD143997
Product name
5,7-Dimethoxy-[1,2,4]triazolo[1,5-a]pyrimidin-2-amine
Packaging
250mg
Price
$400
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD143997
Product name
5,7-Dimethoxy-[1,2,4]triazolo[1,5-a]pyrimidin-2-amine
Packaging
2g
Price
$469
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD143997
Product name
5,7-Dimethoxy-[1,2,4]triazolo[1,5-a]pyrimidin-2-amine
Packaging
500mg
Price
$500
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
35213
Product name
5,7-Dimethoxy-[1,2,4]triazolo[1,5-α]pyrimidin-2-amine
Purity
95+%
Packaging
100mg
Price
$548
Updated
2021/12/16
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2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine Chemical Properties,Usage,Production

Chemical Properties

White solid

Uses

5,7-Dimethoxy-[1,2,4]triazolo[1,5-a]pyrimidin-2-amine is a useful research chemical compound used in the preparation of N-(5,7-dimethoxy[1,2,4]triazolo[1,5-a]pyrimidin-2-yl) arylsulfonamides as herbicides.

Synthesis

102739-44-6

13223-43-3

The general procedure for the synthesis of 2-amino-5,7-dimethoxy-1,2,4-triazino[1,5-a]pyrimidine from the compound (CAS:102739-44-6) was as follows: 3a (114.5 g, 0.4 mol) and hydroxylamine hydrochloride (40.3 g, 0.58 mol) were dissolved in ethanol (600 mL) and stirred vigorously at 60 °C for 0.5 hours. Subsequently, triethylamine (58.7 g, 0.58 mol) was slowly added dropwise to the reaction mixture. The resulting mixture was refluxed for 5 h. After completion of the reaction, it was cooled to room temperature. The white solid of product 4a was collected by filtration and washed with 200 mL of water to give 71.4 g of product in 91.5% yield.

References

[1] Heterocycles, 2016, vol. 92, # 5, p. 829 - 843
[2] Patent: CN105399746, 2016, A. Location in patent: Paragraph 0077-0078
[3] Patent: US2002/111361, 2002, A1

2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine Suppliers

Capot Chemical Co., Ltd
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Amadis Chemical Company Limited
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View Lastest Price from 2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine manufacturers

Career Henan Chemical Co
Product
2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidine 13223-43-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
G/KG/T
Release date
2019-12-24

13223-43-3, 2-Amino-5,7-dimethoxy-1,2,4-triazolo[1,5-a]pyrimidineRelated Search:


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  • 2-Amino-5,7-Dimethoxy-1,2,4-Triazole-[1,5-A]-Pyrimidine
  • 2-Amino-5,7-Dimethoxy-1,2,4-Tr
  • [1,2,4]Triazolo[1,5-a]pyrimidin-2-amine,5,7-dimethoxy-
  • 5,7-DIMETHOXY-[1,2,4]TRIAZOLO[1,5-A]PYRIMIDIN-2-AMINE
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  • 2- amino -5,7- dimethoxy -1,2,4- triazino [1,5-a] pyrimidine
  • Pyroxsulam Metabolite ADTP
  • 2-Amino-5,7-Dimethoxy-1,2,4-Triazolo[1,5-A]Pyrimidine(Adtp)
  • 5,7-Dimethoxy-[1,2,4]triazolo[1,5-α]pyrimidin-2-amine
  • 13223-43-3
  • Heterocycle-Pyrimidine series