1,3,5-Trichlorobenzene

ChemicalBook > CAS DataBase List > 1,3,5-Trichlorobenzene

1,3,5-Trichlorobenzene

Product Name: 1,3,5-Trichlorobenzene
CAS No.: 108-70-3
Chemical Name: 1,3,5-Trichlorobenzene
Synonyms: TCB;Trichlorobenzene;1,3,5-TCB;ai3-22031;1.3.5-Tric;1,3,5-TrichL;s-Trichlorobenzene;1,3,5-Trichlorbenzol;SYM-TRICHLOROBENZENE;1,3,5-Trichlorobenze
CBNumber: CB8852759
Molecular Formula: C6H3Cl3
Formula Weight: 181.45
MOL File: 108-70-3.mol

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1,3,5-Trichlorobenzene Property

Melting point:: 63 °C
Boiling point:: 208 °C(lit.)
Density: 1.4528 (estimate)
vapor pressure: 0.58 at 25 °C (quoted, Mackay et al., 1982)
refractive index: 1.5693 (estimate)
Flash point:: 260 °F
storage temp.: 0-6°C
solubility: Soluble in benzene, ether, ligroin (Weast, 1986), glacial acetic acid, carbon disulfide, and petroleum ether (Windholz et al., 1983)
form: powder or crystals
color: Off-White
Water Solubility: Insoluble in water.
Merck: 14,9632
BRN: 1635233
Henry's Law Constant: 1.83, 2.04, 2.64, 4.49, and 5.24 at 2.0, 6.0, 10.0, 18.0, and 25.0 °C, respectively (EPICS-SPME, Dewulf et al., 1999)
Stability:: Stable. Incompatible with acids, strong oxidizing agents.
LogP: 4.190
CAS DataBase Reference: 108-70-3(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1,3,5-trichloro-(108-70-3)
EPA Substance Registry System: 1,3,5-Trichlorobenzene (108-70-3)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 20/21/22-36/37/38-38-22-52/53
Safety Statements: 26-36-36/37-61
RIDADR: 3077
WGK Germany: 3
RTECS: DC2100100
Hazard Note: Harmful/Irritant
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29039990
Hazardous Substances Data: 108-70-3(Hazardous Substances Data)
Toxicity: Drinking water standard: No MCLGs or MCLs have been proposed, however, a DWEL of 200 μg/L was recommended (U.S. EPA, 2000).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: T54607
Product name: 1,3,5-Trichlorobenzene
Purity: 99%
Packaging: 100g
Price: $80.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 03824
Product name: 1,3,5-Trichlorobenzene
Purity: certified reference material, TraceCERT
Packaging: 100mg
Price: $119
Updated: 2024/03/01

Alfa Aesar

Product number: L02132
Product name: 1,3,5-Trichlorobenzene, 98%
Packaging: 50g
Price: $42.1
Updated: 2023/06/20

Usbiological

Product number: 411208
Product name: 1,3,5-Trichlorobenzene
Packaging: 250mg
Price: $403
Updated: 2021/12/16

TRC

Product number: T773790
Product name: 1,3,5-Trichlorobenzene
Packaging: 1g
Price: $405
Updated: 2021/12/16

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1,3,5-Trichlorobenzene Chemical Properties,Usage,Production

Description

Trichlorobenzenes (TCBs) are synthetic chemicals that occur in three different isomeric forms. The three chlorinated cyclic aromatic isomers are 1,2,3-trichlorobenzene (1,2,3-TCB), 1,2,4-trichlorobenzene (1,2,4-TCB), and 1,3,5-trichlorobenzene (1,3,5-TCB). 1,2,4-TCB is one of the 188 chemicals designated as a hazardous air pollutant under the Clean Air Act.

Chemical Properties

white to beige crystalline powder

Uses

1,3,5-Trichlorobenzene is used for someof these applications plus as a termite preparation and insecticide. These compounds are found as unintended by-products of the manufacture of the mono- and dichlorobenzenes.

Uses

Trichlorobenzenes are primarily used as solvents in chemical manufacturing industries. 1,2,4-Trichlorobenzene is economically the most important isomer. 1,2,4-Trichlorobenzene is used as a solvent in chemical reactions to dissolve oils, waxes, and resins. Furthermore, it is also used as a dye carrier. 1,2,3- Trichlorobenzene is used as an intermediate for pesticides production, pigments, and dyes. 1,3,5-Trichlorobenzene is not marketed commercially and has very limited use as a chemical intermediate. Besides, trichlorobenzenes can also be used as degreasing agents, as septic tanks and drain cleaners, and as an ingredient in wood preservatives and abrasive formulations. Other minor uses include metal work, anticorrosive paint, and corrosion inhibitor in sprays. In the past, mixed isomers of trichlorobenzenes were used to control termites; however, their use has been discontinued.

Uses

1,3,5-Trichlorobenzene is an isomer of 1,2,4-Trichlorobenzene (T774220) which is a solvent in various organic chemical reactions.

Definition

ChEBI: 1,3,5-trichlorobenzene is a trichlorobenzene carrying chloro substituents at positions 1, 3 and 5.

General Description

White to off-white crystals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Can react vigorously with oxidizing materials. .

Fire Hazard

1,3,5-Trichlorobenzene is combustible.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic vapors of Cl-.

Environmental Fate

Biological. Under aerobic conditions, soil microbes degraded 1,3,5-trichlorobenzene to 1,3- and 1,4-dichlorobenzene and carbon dioxide (Kobayashi and Rittman, 1982). A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,3,5-trichlorobenzene to 2,4,6-trichlorophenol (Ballschiter and Scholz, 1980).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,3,5- trichlorobenzene underwent reductive dechlorination yielding 1,3-dichlorobenzene. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 9.5 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. The sunlight irradiation of 1,3,5-trichlorobenzene (20 g) in a 100-mL borosilicate glass-stoppered Erlenmeyer flask for 56 d yielded 160 ppm pentachlorobiphenyl (Uyeta et al., 1976). A photooxidation half-life of 6.17 months was reported for the vapor-phase reaction of 1,3,5-trichlorobenzene with OH radicals (Atkinson, 1985).

Purification Methods

Recrystallise it from dry *benzene or toluene. [Beilstein 5 IV 666.]

Toxicity evaluation

The liver is themain target of trichlorobenzenes irrespective of the route of exposure. The mechanisms of liver toxicity induced by these chemicals have not been illustrated. It might involve intermediate arene oxides formed during initial transformation to trichlorophenols. In addition, exposure to 1,2,4-TCB induced porphyria in rats by inducing daminolevulinic acid (ALA) synthetase, a rate-limiting enzyme in the biosynthesis of heme, and also heme oxygenase, a ratelimiting enzyme in the degradation of heme synthetase, and therefore increasing heme production.

1,3,5-Trichlorobenzene Preparation Products And Raw materials

Raw materials

2,4,6-Trichloroaniline 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene

Preparation Products

2,4,6-Trichlorobenzoic acid 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 3,5-Dichloroaniline

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View Lastest Price from 1,3,5-Trichlorobenzene manufacturers

Yancheng Green Chemicals Co.,Ltd

Product: 1,3,5-Trichlorobenzene 108-70-3
Price: US $0.00/KG
Min. Order: 25KG
Purity: 99
Supply Ability: 1mt
Release date: 2020-10-21

Changde Changlian Chemical Co., Ltd.

Product: 1,3,5-Trichlorobenzene 108-70-3
Price: US $0.00/Kg/Drum
Min. Order: 25Kg/Drum
Purity: 99
Supply Ability: 1mt
Release date: 2020-10-21

Ningxia Jinhua Chemical Co.,Ltd

Product: 1,3,5-Trichlorobenzene 108-70-3
Price: US $0.00/Kg/Drum
Min. Order: 25Kg/Drum
Purity: 99
Supply Ability: 1mt
Release date: 2020-10-21

108-70-3, 1,3,5-TrichlorobenzeneRelated Search:

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1,3,5-Trichlorobenzene ISO 9001：2015 REACH

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1,3,5-Trichlorobenzene (1,3,5-TCB) pure, 99%

Anagrelide Impurity 9

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1,3,5-Trichlorobenzene 10 μg/ml Acetonitrile

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108-70-3

C6Cl3H3

C6H3CI3

108703

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