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2-Methoxyethyl acetate

Product Name
2-Methoxyethyl acetate
CAS No.
110-49-6
Chemical Name
2-Methoxyethyl acetate
Synonyms
ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE;egmea;2-Methoxyacetate;METHYL GLYCOL ACETATE;MeCsAc;EM ACETATE;2-methoxyethyl;3-OXABUTYL ACETATE;CH3C(O)O(CH2)2OCH3;Methylglykolacetat
CBNumber
CB8852810
Molecular Formula
C5H10O3
Formula Weight
118.13
MOL File
110-49-6.mol
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2-Methoxyethyl acetate Property

Melting point:
−65 °C(lit.)
Boiling point:
145 °C(lit.)
Density 
1.009 g/mL at 25 °C(lit.)
vapor pressure 
4.7 hPa (20 °C)
refractive index 
n20/D 1.402(lit.)
Flash point:
111 °F
storage temp. 
Store below +30°C.
solubility 
Soluble in alcohol and ether (Weast, 1986).
form 
Solid
color 
White
explosive limit
1.7-8.8%(V)
Water Solubility 
Miscible (Lyman et al., 1982)
λmax
λ: 254 nm Amax: 1.00
λ: 275 nm Amax: 0.15
λ: 300 nm Amax: 0.05
λ: 350-400 nm Amax: 0.01
Merck 
14,6039
BRN 
1700761
Henry's Law Constant
(x 10-6 atm?m3/mol): 3.28 at 30.00 °C (headspace-GC, Hovorka et al., 2002)
Exposure limits
NIOSH REL: TWA 0.1 ppm (0.5 mg/m3), IDLH 200 ppm; OSHA PEL: TWA 25 ppm (120 mg/m3); ACGIH TLV: TWA 5 ppm (24 mg/m3).
CAS DataBase Reference
110-49-6(CAS DataBase Reference)
EPA Substance Registry System
Ethylene glycol monomethyl ether acetate (110-49-6)
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Safety

Hazard Codes 
T
Risk Statements 
60-61-20/21/22
Safety Statements 
53-45
RIDADR 
UN 1189 3/PG 3
WGK Germany 
1
RTECS 
KL5950000
Autoignition Temperature
380 °C DIN 51794
HS Code 
2915 39 00
HazardClass 
3
PackingGroup 
III
Hazardous Substances Data
110-49-6(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 3.4 g/kg (Smyth)
IDLA
200 ppm
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.06061
Product name
2-Methoxyethyl acetate
Purity
for synthesis
Packaging
1L
Price
$79.9
Updated
2024/03/01
Sigma-Aldrich
Product number
8.06061
Product name
2-Methoxyethyl acetate
Purity
for synthesis
Packaging
2.5L
Price
$214
Updated
2024/03/01
Sigma-Aldrich
Product number
109886
Product name
2-Methoxyethyl acetate
Purity
reagent grade, 98%
Packaging
1l
Price
$141
Updated
2024/03/01
Sigma-Aldrich
Product number
109886
Product name
2-Methoxyethyl acetate
Purity
reagent grade, 98%
Packaging
4l
Price
$413
Updated
2024/03/01
Sigma-Aldrich
Product number
8.06061
Product name
2-Methoxyethyl acetate
Purity
for synthesis
Packaging
100mL
Price
$37.1
Updated
2023/06/20
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2-Methoxyethyl acetate Chemical Properties,Usage,Production

Description

Methoxyethyl acetate is a colorless liquid with a mild, ether-like odor. Odor threshold= 0.33 ppm. Molecular weight= 118.15; Specific gravity (H2O:1)= 1.01;Boiling point=145℃; Freezing/Melting point=65℃; Vapor pressure= 2 mmHg at 20℃; Flash point=48.9℃ (cc); Autoignition temperature=380℃. Explosive limits: LEL= 1.7%; UEL= 8.2%. Hazard Identification (based on NFPA-704 M Rating System): Health 1, Flammability 2, Reactivity 0. Soluble in water.

Chemical Properties

CLEAR LIQUID

Chemical Properties

Methoxyethyl acetate is a colorless liquid. Mild, ethereal odor.

Physical properties

Colorless liquid with a mild, ether-like odor. Experimentally determined detection and recognition odor threshold concentrations were 1.6 mg/m3 (330 ppbv) and 3.1 mg/m3 (640 ppbv), respectively (Hellman and Small, 1974).

Uses

Lacquer industry; textile printing; manufacture of photographic film, coatings, and adhesives

Uses

Industrial solvent.

General Description

A clear colorless liquid with a pleasant odor. Flash point of 135°F. Denser than water and soluble in water. Vapors are heavier than air.

Air & Water Reactions

Flammable. Water soluble. Reacts slowly in water to form acetic acid and methyl alcohol; the reaction is not violent.

Reactivity Profile

Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Toxic by ingestion, inhalation, and skin absorption. Moderate fire risk. Toxic by skin absorption.

Health Hazard

May cause irritation if splashed into eyes. Can be absorbed through the skin. Swallowing a large single dose or absorbing larged amount through skin could result in death. It is unlikely that air levels of the compound would be dangerous unless it is heated.

Fire Hazard

Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon monoxide, may be formed when involved in fire.

Safety Profile

Moderately toxic by ingestion, intraperitoneal, and subcutaneous routes. hfddly toxic by inhalation and skin contact. Human systemic effects by inhalation: eye lachrymation, cough, and pulmonary changes. Experimental reproductive effects. Mutation data reported. An inhalation irritant in humans. An eye irritant. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. A moderate explosion hazard. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

Potential Exposure

Methoxyethyl acetate is used as a solvent for resins, oils, greases and inks. It is also an ingredient of lacquers, paints and adhesives.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 2448 h after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a corticosteroid spray.

Environmental Fate

Chemical/Physical. Hydrolyzes in water forming methyl cellosolve and acetic acid. At an influent concentration of 1,024 mg/L, treatment with GAC resulted in an effluent concentration of 886 mg/L. The adsorbability of the carbon used was 28 mg/g carbon (Guisti et al., 1974).

storage

Color Code—Red: Flammability Hazard: Store in a flammable liquid storage area or approved cabinet away from ignition sources and corrosive and reactive materials. Prior to working with this chemical you should be trained on its proper handling and storage. Before entering confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. 2-Methoxyethyl acetate must be stored to avoid contact with oxidizers (such as perchlorates, peroxides, permanganates, chlorates, and nitrates) and strong caustics, since violent reactions occur. Sources of ignition, such as smoking and open flames are prohibited where 2-methoxyethyl acetate is used, handled, or stored in a manner that could create a potential fire or explosion hazard. Wherever 2-methoxyethyl acetate is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.

Shipping

UN1189 Ethylene glycol monomethyl ether acetate, Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Shake the methoxy-ethane with anhydrous Na2CO3, filter and distil it in a vacuum. Redistillation can be then be carried out at atmospheric pressure. [Dunbar & Bolstad J Org Chem 21 1041 1956, Beilstein 2 IV 214.]

Incompatibilities

Forms explosive mixture with air. Strong oxidants, strong bases, strong acids, and nitrates. May be able to form explosive peroxides.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. Beware of possible presence of peroxides in which case open burning may be used

2-Methoxyethyl acetate Preparation Products And Raw materials

Raw materials

tert-Butyl methyl ether 2-Methoxyethanol Potassium carbonate Diethyl ether Acetic acid Sulfuric acid

Preparation Products

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2-Methoxyethyl acetate Suppliers

Americas 1 China 102 Cyprus 1 Europe 4 France 2 Germany 9 India 10 Japan 8 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 9 United States 40 Global 191
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
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81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
Shandong Xiya Chemical Co., Ltd
Tel
13355009207 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18739
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12990
Advantage
57
BEST-REAGENT
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11726
Advantage
57
Wuhan Kemi-Works Chemical Co., Ltd
Tel
027-85736489
Fax
86-27-85736485
Email
info@kemiworks.net
Country
China
ProdList
542
Advantage
57
Nanjing Vital Chemical Co., Ltd.
Tel
Please Send Email 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
4388
Advantage
65
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11714
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
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View Lastest Price from 2-Methoxyethyl acetate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
2-Methoxyethyl acetate 110-49-6
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-14
Hebei Mojin Biotechnology Co., Ltd
Product
2-Methoxyethyl acetate 110-49-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-11-22
Hebei Guanlang Biotechnology Co., Ltd.
Product
2-Methoxyethyl acetate 110-49-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-09-27

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