(R)-(-)-2-Aminobutane

Product Name: (R)-(-)-2-Aminobutane
CAS No.: 13250-12-9
Chemical Name: (R)-(-)-2-Aminobutane
Synonyms: (R)-2-Butanamine;(2R)-butan-2-amine;(R)-N-sec-Butylamine;(R)-(-)-2-Aminobutane;(2R)-(-)-2-Aminobutane;(R)-(-)-sec-Butylamine;(R)-1-Methylpropylamine;R(-)-SEC-BUTYLAMINE 99+%;(R)-(-)-2-Aminobutane,98%;2-Butanamine, (2R)- (9CI)
CBNumber: CB8853044
Molecular Formula: C4H11N
Formula Weight: 73.14
MOL File: 13250-12-9.mol

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(R)-(-)-2-Aminobutane Property

Melting point:: -105°C
alpha: -7.5 º (c=neat 19 ºC)
Boiling point:: 63 °C(lit.)
Density: 0.72 g/mL at 25 °C(lit.)
refractive index: n20/D 1.393(lit.)
Flash point:: -19°C
storage temp.: Flammables area
pka: 10.74±0.10(Predicted)
form: clear liquid
color: Colorless to Almost colorless
optical activity: [α]19/D 7.5°, neat
Water Solubility: > 10 mg/L
Sensitive: Air Sensitive
Merck: 14,1544
BRN: 1718760
CAS DataBase Reference: 13250-12-9(CAS DataBase Reference)

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Safety

Hazard Codes: F,C,N,F+
Risk Statements: 11-34-50-35-20/22
Safety Statements: 16-26-36/37/39-45-9-61-28A-28
RIDADR: UN 2733 3/PG 2
WGK Germany: 3
F: 10-23
HazardClass: 3
PackingGroup: II
HS Code: 29211999

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 296643
Product name: (R)-(?)-sec-Butylamine
Purity: 99%
Packaging: 250mg
Price: $55.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 296643
Product name: (R)-(?)-sec-Butylamine
Purity: 99%
Packaging: 1g
Price: $201
Updated: 2024/03/01

TCI Chemical

Product number: B2917
Product name: (R)-(-)-sec-Butylamine
Packaging: 100MG
Price: $37
Updated: 2024/03/01

TCI Chemical

Product number: B2917
Product name: (R)-(-)-sec-Butylamine
Packaging: 1G
Price: $173
Updated: 2024/03/01

Alfa Aesar

Product number: L03889
Product name: (R)-(-)-2-Aminobutane, 99%
Packaging: 1g
Price: $218
Updated: 2023/06/20

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(R)-(-)-2-Aminobutane Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(-)-2-Aminobutane is a chiral amine plays an important role in pharmaceutical chemistry and in organic synthesis as chiral auxiliary, which is used to determine the enantiomeric excess (ee).

Uses

(R)-(?)-sec-Butylamine can be used:

To prepare (R)-(?)-sec-butylbis(2-hydroxyethyl)amine, an intermediate for the synthesis of aminodiphosphine ligands.
As a substrate to demonstrate the stereochemistry of Mitsunobu reaction in the synthesis of secondary amines.
As a model compound in the study of singlet-triplet transitions in circular dichroism.

Purification Methods

Dry it over solid NaOH overnight and fractionate it through a short helices packed column. The L-hydrogen tartrate salt has m 139-140o (from H2O), the 1H2O has m 96o []D +18.1o (c 11, H2O), the hydrochloride has m 152o [ ] 21 -1.1o (c 13, H2O) and the benzoyl derivative crystallises from EtOH as needles with m 97o, [] 21 -34.9o (c 11, H2O). [Bruck et al. J Chem Soc 921 1956,Kjaer & Hansen Acta Chem Scand 11 898 1957.] [Beilstein 4 H 161, 4 I 372, 4 III 308, 4 IV 617.] The S -(+)-enantiomer has has same properties except for the optical rotation which has the opposite sign.

(R)-(-)-2-Aminobutane Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-2-Aminobutane Suppliers

Americas 1 Belgium 3 China 56 Europe 1 Germany 8 India 8 Japan 2 Switzerland 2 United Kingdom 7 United States 19 Global 107

J & K SCIENTIFIC LTD.

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View Lastest Price from (R)-(-)-2-Aminobutane manufacturers

Career Henan Chemical Co

Product: (R)-(-)-2-Aminobutane 13250-12-9
Price: US $10.00/KG/Tin
Min. Order: 1KG/Tin
Purity: 99%
Supply Ability: 100
Release date: 2019-06-27

13250-12-9, (R)-(-)-2-AminobutaneRelated Search:

1,2,3,4-Butanetetracarboxylic acid ISOBUTANE 1-Chlorobutane n-Butane 1-Chloro-2-methylpropane 1-Bromo-2-methylpropane 1-Bromobutane 2,2-DICHLOROBUTANE NITROCYCLOPENTANE TPCK 1,8-DIAMINO-P-MENTHANE Cyclobutylamine N-ALPHA-BENZOYL-L-ARGININE 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE 1-ETHYNYLCYCLOHEXYLAMINE sec-Butylamine Aminobutane,1-Aminobutane, n-Butylamine,1-AMINOBUTANE Nalpha-Cbz-L-Arginine

(R)-(-)-sec-Butylamine

(R)-1-Methylpropylamine

(R)-2-Butanamine

(R)-N-sec-Butylamine

(2R)-(-)-2-Aminobutane

(1R)-(-)-1-Methylpropylamine

(2R)-(-)-2-Aminobutane, R-(-)-sec-Butylamine

(R)-(-)-2-Aminobutane,98%

(R)-(-)-sec-Butylamine 99%

(2R)-butan-2-amine

R(-)-SEC-BUTYLAMINE 99+%

(R)-(-)-2-Aminobutane

(R)-(-)-2-BUTYLAMINE HYDROCHLORIDE

2-Butanamine, (2R)- (9CI)

(R)-(-)-2-Aminobutane ISO 9001：2015 REACH

13250-12-9

C2H5CHNH2CH3

Asymmetric Synthesis

Chiral Building Blocks

Amines

Organic Building Blocks

chiral

Amines (Chiral)

Chiral Building Blocks

Synthetic Organic Chemistry