ChemicalBook > CAS DataBase List > Diethyl 1,1-cyclopropanedicarboxylate

Diethyl 1,1-cyclopropanedicarboxylate

Product Name
Diethyl 1,1-cyclopropanedicarboxylate
CAS No.
1559-02-0
Chemical Name
Diethyl 1,1-cyclopropanedicarboxylate
Synonyms
DIETHYL CYCLOPROPANE-1,1-DICARBOXYLATE;1,1-CYCLOPROPANEDICARBOXYLIC ACID DIETHYL ESTER;Diethyl 1;NSC 21376;RARECHEM AL BO 0836;opropane-1,1-dicarboxyL;DiethyldifluoroMalonate96%;1-Cyclopropanedicarboxylate;1,1-Dicarbethoxycyclopropane;Ethyl 1,1-cyclopropanedicarboxylate
CBNumber
CB8853145
Molecular Formula
C9H14O4
Formula Weight
186.21
MOL File
1559-02-0.mol
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Diethyl 1,1-cyclopropanedicarboxylate Property

Melting point:
134-136 °C(lit.)
Boiling point:
94-96 °C/10 mmHg (lit.)
Density 
1.055 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.433(lit.)
Flash point:
188 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Acetone (Slightly), Chlorform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear colorless
BRN 
2049509
CAS DataBase Reference
1559-02-0(CAS DataBase Reference)
NIST Chemistry Reference
Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25-23
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29172090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
147710
Product name
Diethyl cyclopropane-1,1-dicarboxylate
Purity
97%
Packaging
5g
Price
$103
Updated
2023/06/20
Sigma-Aldrich
Product number
147710
Product name
Diethyl cyclopropane-1,1-dicarboxylate
Purity
97%
Packaging
25g
Price
$381
Updated
2023/06/20
TCI Chemical
Product number
C1341
Product name
Diethyl 1,1-Cyclopropanedicarboxylate
Purity
>96.0%(GC)
Packaging
5g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
C1341
Product name
Diethyl 1,1-Cyclopropanedicarboxylate
Purity
>96.0%(GC)
Packaging
25g
Price
$37
Updated
2024/03/01
Alfa Aesar
Product number
H56568
Product name
Diethyl cyclopropane-1,1-dicarboxylate
Packaging
1g
Price
$27.65
Updated
2024/03/01
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Diethyl 1,1-cyclopropanedicarboxylate Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Diethyl 1,1-Cyclopropanedicarboxylate (cas# 1559-02-0) is a compound useful in organic synthesis.

Synthesis Reference(s)

Synthesis, p. 690, 1980 DOI: 10.1055/s-1980-29171

General Description

Diethyl cyclopropane-1,1-dicarboxylate participates in ring-opening addition reactions with various nucleophilic reagents.

Purification Methods

If it is free from OH bands in the IR, then fractionally distil the ester and redistil the middle fraction. Otherwise shake it with aqueous NaHCO3, dry it (MgSO4), filter and distil as before or re-esterify it. [As synthon see Danishefsky Acc Chem Res 12 66 1979, Beilstein 9 I 314, 9 II 512, 9 III 3595, 9 IV 2786.]

Diethyl 1,1-cyclopropanedicarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

(1-Aminocyclopropyl)methanol
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Diethyl 1,1-cyclopropanedicarboxylate Suppliers

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View Lastest Price from Diethyl 1,1-cyclopropanedicarboxylate manufacturers

Hebei Mujin Biotechnology Co.,Ltd
Product
Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16
Hebei Chuanghai Biotechnology Co., Ltd
Product
Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Henan Aochuang Chemical Co.,Ltd.
Product
Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-29

1559-02-0, Diethyl 1,1-cyclopropanedicarboxylateRelated Search:

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  • C9H14O4
  • C3H4CO2C2H52
  • C1 to C5
  • C8 to C9
  • Carboxylic Acids
  • Carbonyl Compounds
  • Building Blocks
  • Esters
  • Organic Building Blocks
  • Simple 3-Membered Ring Compounds
  • Cyclopropanes
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks
  • Aliphatics
  • Cyclopropanes
  • Simple 3-Membered Ring Compounds
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