5-Bromopyrimidine

Product Name: 5-Bromopyrimidine
CAS No.: 4595-59-9
Chemical Name: 5-Bromopyrimidine
Synonyms: 5-bromo-pyrimidin;5-pyriMidine;5-BROMOPYRIMIDINE;5-Bromo-1,3-diazine;PYRIMIDINE, 5-BROMO-;PYRIMIDINE, 2-BROMO-;5-Bromopyrimidine,98%;5-Bromopyrimidine >5-BROMOPYRIMIDINE 0.98;5 - broMine pyriMidine
CBNumber: CB8853640
Molecular Formula: C4H3BrN2
Formula Weight: 158.98
MOL File: 4595-59-9.mol

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5-Bromopyrimidine Property

Melting point:: 67-73 °C (lit.)
Boiling point:: 168°C(lit.)
Density: 1.6448 (rough estimate)
refractive index: 1.5260 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: Soluble in chloroform.
form: Crystalline Powder or Chunks
pka: 1.40±0.10(Predicted)
color: Yellow to beige-brown
BRN: 107326
CAS DataBase Reference: 4595-59-9(CAS DataBase Reference)
NIST Chemistry Reference: Pyrimidine, 5-bromo-(4595-59-9)
EPA Substance Registry System: Pyrimidine, 5-bromo- (4595-59-9)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-36/38
Safety Statements: 26-36-37/39
WGK Germany: 3
Hazard Note: Irritant
TSCA: T
HazardClass: IRRITANT, KEEP COLD
HS Code: 29335990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 219142
Product name: 5-Bromopyrimidine
Purity: 97%
Packaging: 5g
Price: $49.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 219142
Product name: 5-Bromopyrimidine
Purity: 97%
Packaging: 25g
Price: $85.3
Updated: 2024/03/01

TCI Chemical

Product number: B2229
Product name: 5-Bromopyrimidine
Purity: >98.0%(GC)
Packaging: 5g
Price: $62
Updated: 2024/03/01

TCI Chemical

Product number: B2229
Product name: 5-Bromopyrimidine
Purity: >98.0%(GC)
Packaging: 25g
Price: $247
Updated: 2024/03/01

Alfa Aesar

Product number: L14172
Product name: 5-Bromopyrimidine, 98%
Packaging: 5g
Price: $22.65
Updated: 2024/03/01

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5-Bromopyrimidine Chemical Properties,Usage,Production

Chemical Properties

yellow solid crystalline, insoluble in water, soluble in organic solvents such as benzene and toluene.

Uses

5-Bromopyrimidine was used in the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction, (5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol.

Uses

5-Bromopyrimidine was used in the synthesis of:
N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction
(5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol
Intermediate for the synthesis of plant growth regulator flurprimidol

Application

5-Bromopyrimidine is a compound useful in organic synthesis.

Preparation

5-Bromopyrimidine is prepared by reacting dibromodifuranone with formamide in the presence of B2O2 catalyst at 180-185°C to obtain the product.

General Description

Rapid nucleophilic displacement reactions of 5-bromopyrimidine with nucleophiles under microwave irradiation has been studied. 5-Bromopyrimidine undergoes direct metallation with lithuium diisopropylamide to yield 4-lithio-5-bromopyrimidine.

5-Bromopyrimidine Preparation Products And Raw materials

Raw materials

2,3-Dihydrofuran 4-Hydroxy-2,5-dimethyl-3(2H)furanone

Preparation Products

5-HYDROXYPYRIMIDINE 5-Pyrimidinecarboxylic acid 5-Pyrimidinylboronic acid Pyrimidine-5-carboxaldehyde 5-Hydroxypyrimidine

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5-Bromopyrimidine Suppliers

Americas 1 Belgium 3 Canada 3 China 394 Europe 5 Germany 6 India 23 Japan 6 Slovakia 1 South Korea 1 Switzerland 5 The Netherlands 2 Ukraine 1 United Kingdom 19 United States 69 Global 539

Clearsynth Labs Limited

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GLR Innovations

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SUVEN LIFE SCIENCES LTD

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Avra Synthesis Pvt Ltd

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CHEMSWORTH

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View Lastest Price from 5-Bromopyrimidine manufacturers

Zhengzhou Alfa Chemical Co.,Ltd

Product: 5-Bromopyrimidine 4595-59-9
Price: US $238.00/g
Min. Order: 1g
Purity: 97% min.
Supply Ability: 300kg
Release date: 2021-03-26

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 5-Bromopyrimidine 4595-59-9
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%min
Supply Ability: 100kg
Release date: 2023-01-13

Hebei Weibang Biotechnology Co., Ltd

Product: 5-Bromopyrimidine 4595-59-9
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-04

4595-59-9, 5-BromopyrimidineRelated Search:

5-Bromo-2,4-dichloropyrimidine Fluorocytosine Alloxan Pyrimethamine Cytosine Silver sulfadiazine Sulfadiazine Pyrimidine Uracil 5-Bromophthalide 5-Bromonicotinic acid 5-Bromoindole 2-AMINO-5-BROMOPYRIMIDINE,2-Amino-5-bromopyrimidine ,98% 2-AMINO-5-BROMO-4-HYDROXY-6-METHYLPYRIMIDINE 5-Bromo-4,6-dichloropyrimidine 2-Amino-5-bromo-4,6-dimethylpyrimidine 5-Bromo-4,6-dihydroxypyrimidine 5-BROMO-2,4-DIMETHOXYPYRIMIDINE

5-bromo-pyrimidin

PYRIMIDINE, 2-BROMO-

PYRIMIDINE, 5-BROMO-

5-BROMOPYRIMIDINE

5-Bromopyrimidine,98%

Pyrimidine,5-bromo-(6CI,7CI,8CI,9CI)

5-BROMOISATINIC ANHYDRIDE

5-BROMOPYRIMIDINE, 99% MIN

5-BROMOPYRIMIDINE 0.98

5-BroMopyriMidine, 98% 25GR

5-pyriMidine

5-Bromo-1,3-diazine

5-BroMopyriMidine, 97+%

5 - broMine pyriMidine

5-Bromopyrimidine Vetec(TM) reagent grade, 97%

5-Bromopyrimidine &gt

27540 5-Bromopyrimidine

5-BROMOPYRIMIDINE 4595-59-9

5-Bromopyrimidine ISO 9001：2015 REACH

4595-59-9

4595-59-5

C4H3BrN2

Building Blocks

Halogenated Heterocycles

Heterocyclic Building Blocks

Pyrimidines

Halides

Pyrazines, Pyrimidines & Pyridazines

Aromatics Compounds

Aromatics

Heterocycles

Pyrazines, Pyrimidines & Pyridazines

Building Blocks

Halogenated Heterocycles

Heterocyclic Building Blocks

Pyrimidines

PyrimidinesHeterocyclic Building Blocks

Pyrimidine

Heterocycle-Pyrimidine series

HALIDE

Pyridines, Pyrimidines, Purines and Pteredines

bc0001

4595-59-9