ChemicalBook > CAS DataBase List > 2-Chlorobutane

2-Chlorobutane

Product Name
2-Chlorobutane
CAS No.
78-86-4
Chemical Name
2-Chlorobutane
Synonyms
sec-C4H9Cl;2-Chlorbutan;2-CHLOROBUTANE;2-chloro-butan;2-Butylchloride;Butane,2-chloro-;chlorosec-butane;s-Butyl Chloride;SEC-BUTYL CHLORIDE;(2RS)-chlorobutane
CBNumber
CB8854384
Molecular Formula
C4H9Cl
Formula Weight
92.57
MOL File
78-86-4.mol
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2-Chlorobutane Property

Melting point:
-140 °C (lit.)
Boiling point:
68-70 °C (lit.)
Density 
0.873 g/mL at 25 °C (lit.)
vapor pressure 
160 hPa (20 °C)
refractive index 
n20/D 1.396(lit.)
Flash point:
5 °F
storage temp. 
Store below +30°C.
solubility 
1.0g/l
form 
Liquid
color 
Clear colorless to slightly yellow
PH
7 (H2O, 20℃)Aqueous solution
explosive limit
2.0-8.8%(V)
Water Solubility 
immiscible
Merck 
14,1561
BRN 
1718770
Dielectric constant
8.5600000000000005
Stability:
Stable. Flammable - note low flash point. May form explosive mixtures with air. Incompatible with strong oxidizing agents.
LogP
2.72 at 25℃
CAS DataBase Reference
78-86-4(CAS DataBase Reference)
NIST Chemistry Reference
Butane, 2-chloro-(78-86-4)
EPA Substance Registry System
2-Chlorobutane (78-86-4)
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Safety

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
16-29-7/9-9
RIDADR 
UN 1127 3/PG 2
WGK Germany 
2
RTECS 
EJ6475000
Autoignition Temperature
460 °C
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29031980
Toxicity
LD50 orally in Rabbit: 17400 mg/kg LD50 dermal Rabbit 17400 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C28898
Product name
2-Chlorobutane
Purity
≥99%
Packaging
100ml
Price
$32
Updated
2025/07/31
Sigma-Aldrich
Product number
C28898
Product name
2-Chlorobutane
Purity
≥99%
Packaging
250ml
Price
$67.3
Updated
2025/07/31
Sigma-Aldrich
Product number
8.20281
Product name
2-Chlorobutane
Purity
for synthesis
Packaging
100mL
Price
$38
Updated
2025/07/31
Sigma-Aldrich
Product number
8.20281
Product name
2-Chlorobutane
Purity
for synthesis
Packaging
1L
Price
$116
Updated
2025/07/31
TCI Chemical
Product number
C0143
Product name
2-Chlorobutane
Purity
>99.0%(GC)
Packaging
25mL
Price
$42
Updated
2025/07/31
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2-Chlorobutane Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Chemical Properties

Butyl chloride is a highly flammable, clear, colorless liquid.

Uses

2-Chlorobutane is used as a solvent and intermediate in organic synthesis. Further, it is involved in the preparation of active pharmaceutical ingredients, plasticizer, rubber, resin and surfactants.

Definition

ChEBI: 2-chlorobutane is a chloroalkane that is butane which carries a chloro group at position 2. It derives from a hydride of a butane.

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 2428, 1951 DOI: 10.1021/ja01150a006

Hazard

Flammable, dangerous fire risk.

Flammability and Explosibility

Highly flammable

Safety Profile

Wdly toxic by ingestion, inhalation, and skin contact. Questionable carcinogen with experimental neoplastigenic data. Dangerous fire hazard when exposed to heat, open flame (sparks), or oxidizers. To fight fEe, use water, water spray, fog, mist, dry chemical, alcohol foam. When heated to decomposition it emits toxic fumes of Cl-. See also E CHLORINATED HYDROCARBONS, ALIPHATIC .

Potential Exposure

Butyl chloride is used as a solvent; as a medicine to control worms, and to make other chemicals

Shipping

UN1127 Chlorobutanes require, Hazard Class: 3; Labels: 3—Flammable liquid

Purification Methods

Purify it in the same way as n-butyl chloride. [Beilstein 1 IV 248.]

Incompatibilities

Vapor may form explosive mixture with air. May accumulate static electrical charges, and may cause ignition of its vapors. Water contact slowly forms hydrochloric acid. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, alkaline earth, and alkali metals; finely divided metal. Attacks metals in presence of moisture. Attacks some plastics, rubber, or coatings

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

2-Chlorobutane Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Chlorobutane Suppliers

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View Lastest Price from 2-Chlorobutane manufacturers

Career Henan Chemical Co
Product
2-Chlorobutane 78-86-4
Price
US $1.00/KG
Min. Order
1KG
Purity
98%HPLC
Supply Ability
10 tons/month
Release date
2020-01-07

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