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2-Bromotoluene

Product Name
2-Bromotoluene
CAS No.
95-46-5
Chemical Name
2-Bromotoluene
Synonyms
1-BROMO-2-METHYLBENZENE;a13-26648;2-Bromtoluol;o-bromo-toluen;2-BROMOTOLUENE;2-bromo-toluen;2-tolylbromide;O-BROMOTOLUENE;2-Tolyl bromide;O-TOLYL BROMIDE
CBNumber
CB8854692
Molecular Formula
C7H7Br
Formula Weight
171.03
MOL File
95-46-5.mol
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2-Bromotoluene Property

Melting point:
-27 °C (lit.)
Boiling point:
58-60 °C/10 mmHg (lit.)
Density 
1.422 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.555(lit.)
Flash point:
174 °F
storage temp. 
2-8°C
form 
Liquid
Specific Gravity
1.422
color 
Clear colorless to light yellow
Water Solubility 
<0.1 g/100 mL at 15 ºC
Merck 
14,1439
BRN 
1904176
Dielectric constant
4.2800000000000002
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
95-46-5(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-2-methyl-(95-46-5)
EPA Substance Registry System
o-Bromotoluene (95-46-5)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
36/37/39-37/39-26
WGK Germany 
3
RTECS 
XS7965500
Hazard Note 
Harmful/Irritant
TSCA 
Yes
PackingGroup 
III
HS Code 
29036990
Hazardous Substances Data
95-46-5(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B82006
Product name
2-Bromotoluene
Purity
99%
Packaging
25g
Price
$52.1
Updated
2024/03/01
Sigma-Aldrich
Product number
B82006
Product name
2-Bromotoluene
Purity
99%
Packaging
100g
Price
$90
Updated
2024/03/01
TCI Chemical
Product number
B0659
Product name
2-Bromotoluene
Packaging
25G
Price
$24
Updated
2024/03/01
TCI Chemical
Product number
B0659
Product name
2-Bromotoluene
Packaging
500G
Price
$211
Updated
2024/03/01
Alfa Aesar
Product number
A12315
Product name
2-Bromotoluene, 99%
Packaging
25g
Price
$43.65
Updated
2024/03/01
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2-Bromotoluene Chemical Properties,Usage,Production

Chemical Properties

liquid

Uses

2-Bromotoluene was used in the synthesis of (±)-isocomene. Suzuki coupling of 2-bromotoluene with phenylboronic acid using palladium nanoparticles supported on alumina-based oxides as catalyst has been reported. 2-Bromotoluene is used in manufacturing pharmaceuticals (especially for nonsteroidal antiinflammatory drugs; Meclofenamic acid, Mefenamic acid) and other organic compounds

General Description

Clear colorless to pale beige liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Bromotoluene reacts with strong oxidizing agents.

Fire Hazard

2-Bromotoluene is combustible.

Purification Methods

Fractionally distil it through an efficient column. It can be separated from its isomers by gas chromatography on a column of “Sil-o-cel” firebrick (30-40mesh, 80 parts) coated with 5% (20 parts) of ICI E301 con rubber with N2 carrier gas at 170o/atm and 100mL/minute and using a conductivity cell detector. [Cowley et al. J Chem Soc 1801 1959, Beilstein 5 H 304, 5 I 153, 5 II 234 5 III 704, 5 IV 825.]

2-Bromotoluene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromotoluene Suppliers

Matrix Fine Chemicals GmbH
Tel
--
Fax
--
Email
nfo@matrix-fine-chemicals.com
Country
Switzerland
ProdList
6968
Advantage
58
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 2-Bromotoluene manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-Bromotoluene 95-46-5
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Career Henan Chemical Co
Product
2-Bromotoluene 95-46-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

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