Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Reaction- Product Name
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- CAS No.
- 887919-35-9
- Chemical Name
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- Synonyms
- Pd132;Pd(amphos)Cl2;Pd(Amphos)2Cl2;PdCl2(Amphos)2;(A-taPhos)2PdCl2;PdAMPHOS;BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II);pall;Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…;Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II)
- CBNumber
- CB8972714
- Molecular Formula
- C32H58Cl2N2P2Pd
- Formula Weight
- 710.1
- MOL File
- 887919-35-9.mol
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Property
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- Powder
- color
- yellow
- Water Solubility
- Insoluble in water.
- InChI
- InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;
- InChIKey
- AWOFSUFKCXRJMV-UHFFFAOYSA-N
- SMILES
- P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 678740
- Product name
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- Purity
- 95%
- Packaging
- 1g
- Price
- $163
- Updated
- 2024/03/01
- Product number
- 678740
- Product name
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- Purity
- 95%
- Packaging
- 5g
- Price
- $776
- Updated
- 2024/03/01
- Product number
- 045511
- Product name
- Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II), Pd 15%
- Packaging
- 1g
- Price
- $236.65
- Updated
- 2024/03/01
- Product number
- 46-0825
- Product name
- Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos
- Packaging
- 250mg
- Price
- $55
- Updated
- 2024/03/01
- Product number
- 46-0825
- Product name
- Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos
- Packaging
- 1g
- Price
- $162
- Updated
- 2024/03/01
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Chemical Properties,Usage,Production
Reaction
- Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
- Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate.
Chemical Properties
Yellow powder
Uses
Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.
Uses
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
Synthesis
To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) manufacturers
- Product
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II) 887919-35-9
- Price
- US $8.00-0.80/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-22
- Product
- Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II) 887919-35-9
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG /month
- Release date
- 2021-11-12
- Product
- BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) 887919-35-9
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27