ChemicalBook > CAS DataBase List > Iodoethane

Iodoethane

Product Name
Iodoethane
CAS No.
75-03-6
Chemical Name
Iodoethane
Synonyms
ETHYL IODIDE;Iodethan;C2H5I;Iodoethane (stabilized with Copper chip);ENCH;Jodethan;IODOETHANE;Ethyliodid;Ethyljodid;iodo-ethan
CBNumber
CB9139251
Molecular Formula
C2H5I
Formula Weight
155.97
MOL File
75-03-6.mol
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Iodoethane Property

Melting point:
-108 °C
Boiling point:
69-73 °C(lit.)
Density 
1.95 g/mL at 25 °C(lit.)
vapor density 
5.38 (vs air)
vapor pressure 
100 mm Hg ( 18 °C)
refractive index 
n20/D 1.513(lit.)
Flash point:
53 °C
storage temp. 
Store below +30°C.
solubility 
4g/l (slow decomposition)
form 
Liquid
color 
Clear colorless to faint yellow or pink
Specific Gravity
1.95
Odor
light delicate odor
Water Solubility 
4 g/L (20 ºC)
Sensitive 
Light Sensitive
Merck 
14,3813
BRN 
505934
Dielectric constant
7.4(20℃)
CAS DataBase Reference
75-03-6(CAS DataBase Reference)
NIST Chemistry Reference
Iodoethane(75-03-6)
EPA Substance Registry System
Ethane, iodo- (75-03-6)
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Safety

Hazard Codes 
Xn,T
Risk Statements 
20-36/37/38-42/43-10-23/24/25-22-20/22
Safety Statements 
23-26-36/37-45-37/39-16-36/37/39-27
RIDADR 
2922
WGK Germany 
3
RTECS 
KI4750000
1-8
TSCA 
Yes
HS Code 
2903 39 80
HazardClass 
6.1
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H341Suspected of causing genetic defects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
I7780
Product name
Iodoethane
Purity
contains copper as stabilizer, ReagentPlus , 99%
Packaging
5g
Price
$31.9
Updated
2024/03/01
Sigma-Aldrich
Product number
I7780
Product name
Iodoethane
Purity
contains copper as stabilizer, ReagentPlus , 99%
Packaging
100g
Price
$48.1
Updated
2024/03/01
Sigma-Aldrich
Product number
8.00896
Product name
Iodoethane
Purity
(stabilised with silver) for synthesis
Packaging
100mL
Price
$150
Updated
2024/03/01
Sigma-Aldrich
Product number
8.00896
Product name
Iodoethane
Purity
(stabilised with silver) for synthesis
Packaging
500mL
Price
$508
Updated
2024/03/01
TCI Chemical
Product number
I0058
Product name
Iodoethane (stabilized with Copper chip)
Purity
>99.0%(GC)
Packaging
25g
Price
$18
Updated
2024/03/01
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Iodoethane Chemical Properties,Usage,Production

Chemical Properties

Colorless to yellow liquid. Iodoethane is a stable chemical substance. It is incompatible with strong bases, magnesium, and strong oxidising agents and gets discoloured when exposed to light, moisture, and air.

Uses

A useful synthetic reagent for the introduction of ethyl groups

Uses

Iodoethane is an excellent ethylating agent used in organic synthesis to introduce an ethyl group into a compound. It reacts with magnesium to form the Grignard reagent, ethylmagnesium iodide which is used in organic synthesis. It is involved in the preparation of 1-ethyl-3-nitro-2-phenyl-indole and also serves as hydrogen radical promoter.

Definition

A colorless liquid alkyl halide made by reaction of ethanol with iodine in the presence of red phosphorus.

Definition

ChEBI: An iodoalkane that is ethane substituted by an iodo group.

Synthesis Reference(s)

The Journal of Organic Chemistry, 12, p. 133, 1947 DOI: 10.1021/jo01165a017

General Description

Iodoethane also known as ethyl iodide is an alkyl iodide. The interaction of iodoethane with Pt(111) surfaces has been analyzed by using thermal desorption and X-ray photoelectron spectroscopy. Its microwave spectrum has been recorded and studied. The dynamics of the gas phase photolysis of iodoethane have been studied using resonance Raman spectra. Its thermodynamic characteristics in the ideal state have been reported.

Hazard

Toxic by inhalation and skin absorption, narcotic in high concentration.

Purification Methods

Drying the iodide with P2O5 is unsatisfactory, and with CaCl2 it is incomplete. It is probably best to dry it with sodium wire and distil [Hammond et al. J Am Chem Soc 82 704 1960]. Exposure of ethyl iodide to light leads to rapid decomposition, with the liberation of iodine. Free iodine can be removed by shaking with several portions of dilute aqueous Na2S2O3 (until the colour is discharged), followed by washing with water, drying (with CaCl2, then sodium), and distilling. The distilled ethyl iodide is stored, over mercury, in a dark bottle away from direct sunlight. Other purification procedures include passage through a 60cm column of silica gel, followed by distillation, and treatment with elemental bromine, extraction of free halogen with Na2S2O3 solution, followed by washing with water, drying and distilling. Free iodine and HI have also been removed by direct distillation through a LeBel-Henninger column containing copper turnings. Purification by shaking with alkaline solutions, and storage over silver, are reported to be unsatisfactory. [Beilstein 1 IV 163.]

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View Lastest Price from Iodoethane manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
Iodoethane 75-03-6
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2024-09-24
Career Henan Chemical Co
Product
Iodoethane 1975-03-6
Price
US $1.00/KG
Min. Order
1KG
Purity
995
Supply Ability
25kg
Release date
2019-07-12

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