ChemicalBook > CAS DataBase List > Ruthenium(III) chloride hydrate

Ruthenium(III) chloride hydrate

Product Name
Ruthenium(III) chloride hydrate
CAS No.
14898-67-0
Chemical Name
Ruthenium(III) chloride hydrate
Synonyms
RUTHENIUM TRICHLORIDE HYDRATE;RUTHENIUM(III) CHLORIDE HYDRATE;RUTHENIUM CHLORIDE HYDRATE;Ruthenium(III) chloride xhydrate;RUTHENIUM(III) CHLORIDE HYDRATE14898-67-0;Aluminium oxide,active;RuodiuM Chloride Hydrate;Active oxidative aluminum;Ruthenium(3+) trichloride;Trichlororuthenium hydrate
CBNumber
CB9142235
Molecular Formula
Cl3H2ORu
Formula Weight
225.44
MOL File
14898-67-0.mol
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Ruthenium(III) chloride hydrate Property

Melting point:
>300°C
Density 
3.11 g/cm3
storage temp. 
Store at +5°C to +30°C.
solubility 
Water (Slightly)
form 
Powder
color 
Dark brown to black
PH
<2 (H2O, 20℃)Aqueous solution
Water Solubility 
soluble
Sensitive 
Hygroscopic
Merck 
14,8302
Stability:
hygroscopic
InChI
InChI=1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
InChIKey
BIXNGBXQRRXPLM-UHFFFAOYSA-K
SMILES
[Ru](Cl)(Cl)Cl.O
CAS DataBase Reference
14898-67-0(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34-52/53-22
Safety Statements 
26-36/37/39-45-61
RIDADR 
UN 3260 8/PG 2
WGK Germany 
2
RTECS 
VM2650000
TSCA 
Yes
HS Code 
2843 90 90
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
84050
Product name
Ruthenium(III) chloride hydrate
Purity
38.0-42.0% Ru basis
Packaging
1g
Price
$72.8
Updated
2024/03/01
Sigma-Aldrich
Product number
84050
Product name
Ruthenium(III) chloride hydrate
Purity
38.0-42.0% Ru basis
Packaging
5G
Price
$149
Updated
2024/03/01
Sigma-Aldrich
Product number
206229
Product name
Ruthenium(III) chloride hydrate
Purity
ReagentPlus
Packaging
1g
Price
$62.4
Updated
2024/03/01
Sigma-Aldrich
Product number
206229
Product name
Ruthenium(III) chloride hydrate
Purity
ReagentPlus
Packaging
5g
Price
$200
Updated
2024/03/01
TCI Chemical
Product number
R0074
Product name
Ruthenium(III) Chloride Hydrate
Packaging
1G
Price
$94
Updated
2024/03/01
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Ruthenium(III) chloride hydrate Chemical Properties,Usage,Production

Chemical Properties

Ruthenium(III) chloride hydrate appears as dark brown to black powder. It cannot dissolve in cold water or carbon disulfide, but it can decompose in hot water. It is also insoluble in ethanol, but it can dissolve in hydrochloric acid. When combined with potassium iodide solution, it forms a precipitate of iodide. When reacted with hydrogen sulfide, it forms a precipitate of ruthenium trisulfide. It can react with ammonia, potassium cyanide, and potassium nitrite to form corresponding ammonia, cyanide, and nitroso complexes. It can also be reduced to blue divalent ruthenium ions by sodium amalgam or titanium trichloride.

Uses

Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs? catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

Application

Ruthenium hydrated oxide, prepared from RhCl3 when deposited on titania nanotubes can  be used as a catalyt system for selective oxidation of alcohols by oxygen.

Preparation

Ruthenium(III) chloride hydrate can be synthesized by directly combining ruthenium metal and chlorine at high temperature. Alternatively, adding hydrochloric acid to ruthenium hydroxide and subsequently evaporating, concentrating, and crystallizing the mixture can also produce the desired compound.

General Description

Ruthenium(III) chloride hydrate, also called Ruthenium(III) trichloride hydrate, is widely used as a starting material in Ruthenium chemistry. It is used in the determination of sulfites, the manufacture of chlororuthenates, and as an electrode coating material.

Purification Methods

Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].

Ruthenium(III) chloride hydrate Preparation Products And Raw materials

Raw materials

Preparation Products

Tris(triphenylphosphine)ruthenium(II) chloride Dichloro(cycloocta-1,5-diene)ruthenium(II) TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE 3-BROMO-6-METHYL-2-OXO-1(2H)-PYRAZINEACETIC ACID ETHYL ESTER ethyl 2-(3,4-dihydro-6-methyl-2,3-dioxopyrazin-1(2H)-yl)acetate
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View Lastest Price from Ruthenium(III) chloride hydrate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
ruthenium chloride 14898-67-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Yanxi Chemical Co., Ltd.
Product
ruthenium chloride 14898-67-0
Price
US $30.00-9.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-16
Hebei Mojin Biotechnology Co.,Ltd
Product
Ruthenium(III) chloride 14898-67-0
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-08-22

14898-67-0, Ruthenium(III) chloride hydrateRelated Search:

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