ChemicalBook > CAS DataBase List > N-Formylpiperidine

N-Formylpiperidine

Product Name
N-Formylpiperidine
CAS No.
2591-86-8
Chemical Name
N-Formylpiperidine
Synonyms
PIPERIDINE-1-CARBALDEHYDE;1-FORMYLPIPERIDINE;nfp;1-PIPERIDINECARBOXALDEHYDE;FORMYLPIPERIDINE;N-Formylpiperidin;1-FormyL;N-Formylpiperdine;1-formyl-piperidin;N-FORMYLPIPERIDINE
CBNumber
CB9149092
Molecular Formula
C6H11NO
Formula Weight
113.16
MOL File
2591-86-8.mol
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N-Formylpiperidine Property

Melting point:
-31 °C
Boiling point:
222 °C(lit.)
Density 
1.019 g/mL at 25 °C(lit.)
vapor pressure 
0.1 mm Hg ( 25 °C)
refractive index 
n20/D 1.484(lit.)
Flash point:
197 °F
storage temp. 
Store below +30°C.
form 
Liquid
pka
-0.44±0.20(Predicted)
Specific Gravity
1.02
color 
Clear colorless to slightly yellow
Water Solubility 
freely soluble
BRN 
107697
Dielectric constant
26.149999999999999
CAS DataBase Reference
2591-86-8(CAS DataBase Reference)
NIST Chemistry Reference
1-Piperidinecarboxaldehyde(2591-86-8)
EPA Substance Registry System
N-Formylpiperidine (2591-86-8)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
21/22-36/37/38
Safety Statements 
26-36/37-36
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
3
RTECS 
TN0380000
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29333999
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
F17407
Product name
1-Formylpiperidine
Purity
99%
Packaging
100g
Price
$70.8
Updated
2024/03/01
Sigma-Aldrich
Product number
F17407
Product name
1-Formylpiperidine
Purity
99%
Packaging
500g
Price
$167.4
Updated
2024/03/01
TCI Chemical
Product number
F0234
Product name
1-Formylpiperidine
Purity
>98.0%(GC)
Packaging
25mL
Price
$26
Updated
2024/03/01
TCI Chemical
Product number
F0234
Product name
1-Formylpiperidine
Purity
>98.0%(GC)
Packaging
100mL
Price
$45
Updated
2024/03/01
Alfa Aesar
Product number
B23452
Product name
1-Formylpiperidine, 99%
Packaging
50g
Price
$42.65
Updated
2024/03/01
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N-Formylpiperidine Chemical Properties,Usage,Production

Description

This simple piperidine base has recently been discovered in the oxygenated fraction from Piper nigrum. The structure has been elucidated from chemical and spectroscopic data.

Chemical Properties

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID

Uses

Solvent for polar and nonpolar compounds, as well as many high polymers; gas absorption; plastics modifiers.

Uses

Reactant for:

  • Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate
  • Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride
  • CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides
  • Synthesis of alternating copolymers for organic photovoltaic applications
  • One-pot double functionalization of π-deficient heterocyclic lithium reagents
  • Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds

Definition

ChEBI: 1-Piperidinecarboxaldehyde is a member of piperidines.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 42, p. 1655, 1994 DOI: 10.1248/cpb.42.1655
Synthetic Communications, 20, p. 447, 1990 DOI: 10.1080/00397919008052787

References

Debrauwere, Verzale, Bull. Soc. Chim. Belg., 84, 167 (1975)

N-Formylpiperidine Preparation Products And Raw materials

Raw materials

Preparation Products

TERT-BUTYL 4-FORMYLPYRIDIN-3-YLCARBAMATE 5-BROMO-2-FLUOROPYRIDINE-3-CARBALDEHYDE
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N-Formylpiperidine Suppliers

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View Lastest Price from N-Formylpiperidine manufacturers

Henan Fengda Chemical Co., Ltd
Product
Formylpiperidine 2591-86-8
Price
US $122.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-11
Shanghai CRM New Material Technology Co., LTD
Product
Formylpiperidine 2591-86-8
Price
US $10.00-15.00/g
Min. Order
10g
Purity
99%
Supply Ability
10t
Release date
2022-09-22
Qiuxian Baitai New Material Co., LTD
Product
n-formylpiperidine 2591-86-8
Price
US $73.00/g
Min. Order
100g
Purity
99%
Supply Ability
500ton/Month
Release date
2021-11-05

2591-86-8, N-FormylpiperidineRelated Search:

Triacetonediamine Haloperidol Formaldehyde N-Formylmorpholine DROPERIDOL TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN 4-Benzyloxycarbonylaminopiperidine Hydrochloride Hexahydroisonicotinamide DL-Pipecolinic acid Piperazine-2-carboxylic acid dihydrochloride 3-CBZ-AMINOPIPERIDINE HCL tert-Butyl 1-piperazinecarboxylate PIPERIDIN-3-ONE HYDROCHLORIDE Piperidine Diphenoxylate N-Carbethoxy-4-piperidone ETHYL 1-PIPERIDINEGLYOXYLATE 2-METHOXY-1-FORMYLPIPERIDINE,N-Methoxy-1-formylpiperidine

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