Uses
ChemicalBook > CAS DataBase List > 4-Bromo-2,2''-bipyridine

4-Bromo-2,2''-bipyridine

Uses
Product Name
4-Bromo-2,2''-bipyridine
CAS No.
14162-95-9
Chemical Name
4-Bromo-2,2''-bipyridine
Synonyms
4-Bromo-2,2'-bipyridyl;4-Bromo-2,2'-bipyridine;2,2'-Bipyridine,4-bromo-;4-Bromo-2,2''-bipyridine;4-BroMo-2,2'-bipyridine 97%;4-broMo-2-(pyridin-2-yl)pyridine;2,2′-Bipyridine, 4-bromo- (8CI, 9CI, ACI);4-Bromo-2,2''-bipyridine ISO 9001：2015 REACH
CBNumber
CB91501479
Molecular Formula
C10H7BrN2
Formula Weight
235.08
MOL File
14162-95-9.mol
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4-Bromo-2,2''-bipyridine Property

Melting point:
52 °C
Boiling point:
325.2±27.0 °C(Predicted)
Density 
1.493
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
powder to crystal
pka
3.70±0.22(Predicted)
color 
White to Almost white
InChI
InChI=1S/C10H7BrN2/c11-8-4-6-13-10(7-8)9-3-1-2-5-12-9/h1-7H
InChIKey
SCOXFIBXWCCICG-UHFFFAOYSA-N
SMILES
C1(C2=NC=CC=C2)=NC=CC(Br)=C1
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Safety

RIDADR 
UN2811
HazardClass 
6.1
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5088
Product name
4-Bromo-2,2'-bipyridyl
Packaging
200MG
Price
$115
Updated
2025/07/31
TRC
Product number
B659180
Product name
4-bromo-2,2''-bipyridine
Packaging
50mg
Price
$90
Updated
2021/12/16
Oakwood
Product number
323769
Product name
4-Bromo-2,2'-bipyridine
Packaging
250mg
Price
$95
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB35081
Product name
4-Bromo-2,2'-bipyridine
Packaging
1g
Price
$320
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB35081
Product name
4-Bromo-2,2'-bipyridine
Packaging
250mg
Price
$125
Updated
2021/12/16
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4-Bromo-2,2''-bipyridine Chemical Properties,Usage,Production

Uses

4-bromo-2,2'-bipyridine is a useful research chemical.

Uses

4-Bromo-2,2'-bipyridine can be used as electro-active compounds in flow batteries.

Synthesis

14163-03-2

14162-95-9

Under nitrogen protection, 4-bromo-[2,2'-bipyridine] 1-oxide (786 mg, 3.13 mmol) was dissolved in dry chloroform (10 mL) and the solution was cooled to 0 °C. Subsequently, phosphorus tribromide (PBr3, 1.0 mL, 10 mmol) was slowly added to the solution. The reaction mixture was heated to reflux for 5 hours. After completion of the reaction, the mixture was poured into ice water, the pH was adjusted to alkaline with 6N aqueous sodium hydroxide and extracted with chloroform (CHCl3). The organic layers were combined, dried with anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure to give the white solid product 4-bromo-2,2'-bipyridine (728 mg, 3.09 mmol, 98.7% yield). The structure of the product was confirmed by 1H NMR, IR spectroscopy, melting point and ESI-MS.1H NMR (CDCl3): δ = 8.69 (d, J = 5.0 Hz, 1H), 8.63 (d, J = 1.8 Hz, 1H), 8.49 (d, J = 5.1 Hz, 1H), 8.39 (d, J = 8.0 Hz, 1H), 7.83 ( dt, J1 = 8.0 Hz, J2 = 1.6 Hz, 1H), 7.48 (dd, J1 = 5.1 Hz, J2 = 1.8 Hz, 1H), 7.34 (ddd, J1 = 7.5 Hz, J2 = 4.8 Hz, J3 = 1.6 Hz, 1H). ir (kbr): ν = 1565, 1545, 1452, 1386, 1280, 1066, 994, 833 1066, 994, 833, 787, 687 cm-1. Melting point: 51.5-53 °C. ESI-MS: m/z = 256.9, 258.9 [M + Na]+ (calculated values C10H7N2Br + Na = 256.9, 258.9).

References

[1] Patent: US2012/247546, 2012, A1. Location in patent: Page/Page column 29
[2] Tetrahedron Letters, 2013, vol. 54, # 40, p. 5514 - 5517
[3] European Journal of Organic Chemistry, 2014, vol. 2014, # 28, p. 6295 - 6302
[4] Journal of the Chemical Society. Perkin Transactions 2, 1998, # 10, p. 2281 - 2288
[5] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984, # 8, p. 1293 - 1302

4-Bromo-2,2''-bipyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromo-2,2''-bipyridine Suppliers

Americas 1 China 124 China Hong Kong 1 Europe 1 India 2 Japan 1 Switzerland 1 United Kingdom 1 United States 7 Global 139
Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
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View Lastest Price from 4-Bromo-2,2''-bipyridine manufacturers

Shanghai UCHEM Inc.
Product
4-Bromo-2,2'-bipyridine 14162-95-9
Price
US $422.00-1259.00/g
Min. Order
1g
Purity
0.98
Supply Ability
10kg
Release date
2023-10-18
Dideu Industries Group Limited
Product
4-Bromo-2,2''-bipyridine 14162-95-9
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-10-27
Career Henan Chemical Co
Product
4-Bromo-2,2''-bipyridine 14162-95-9
Price
US $1.00/KG
Min. Order
1G
Purity
99%
Supply Ability
100kg
Release date
2018-08-12

14162-95-9, 4-Bromo-2,2''-bipyridineRelated Search:

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  • 4-BroMo-2,2'-bipyridine 97%
  • 4-broMo-2-(pyridin-2-yl)pyridine
  • 2,2'-Bipyridine,4-bromo-
  • 4-Bromo-2,2'-bipyridyl
  • 4-Bromo-2,2''-bipyridine ISO 9001：2015 REACH
  • 2,2′-Bipyridine, 4-bromo- (8CI, 9CI, ACI)
  • 4-Bromo-2,2'-bipyridine
  • 14162-95-9
  • pharmacetical