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Lithium dihydrogen phosphate

Product Name
Lithium dihydrogen phosphate
CAS No.
13453-80-0
Chemical Name
Lithium dihydrogen phosphate
Synonyms
monolithiumphosphate;LITHIUM DIHYDROGEN P;lithiumdihydrophosphate;lithiumphosphate(lih2po4);Lithium hydrogen phosphate;LITHIUM PHOSPHATE MONOBASIC;LITHIUM DIHYDROGEN PHOSPHATE;LithiuM Dihydroxide Phosphate;Lithiumdihydrogenphosphate,97%;lithiumdihydrogenorthophosphate
CBNumber
CB9150683
Molecular Formula
H4LiO4P
Formula Weight
105.94
MOL File
13453-80-0.mol
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Lithium dihydrogen phosphate Property

Melting point:
>100°C
Density 
2.5 g/mL at 25 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
Specific Gravity
2.461
color 
white
Water Solubility 
Slightly soluble in water.
Stability:
Stable. Incompatible with strong oxidizing agents.
InChI
InChI=1S/Li.H3O4P.H/c;1-5(2,3)4;/h;(H3,1,2,3,4);
InChIKey
AZOORWHXDYIBGH-UHFFFAOYSA-N
SMILES
P(O)(O)(O)=O.[LiH]
CAS DataBase Reference
13453-80-0(CAS DataBase Reference)
EPA Substance Registry System
Phosphoric acid, monolithium salt (13453-80-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
TC6593950
TSCA 
Yes
HS Code 
28352990
Toxicity
mouse,LD50,oral,910mg/kg (910mg/kg),"Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 28, 1978.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
563161
Product name
Lithium phosphate monobasic
Purity
≥99.99%
Packaging
25g
Price
$107
Updated
2024/03/01
Sigma-Aldrich
Product number
442682
Product name
Lithium phosphate monobasic
Purity
99%
Packaging
500g
Price
$148
Updated
2024/03/01
Alfa Aesar
Product number
A16987
Product name
Lithium dihydrogen phosphate, 97%
Packaging
250g
Price
$91.7
Updated
2024/03/01
Strem Chemicals
Product number
93-0383
Product name
Lithium dihydrogen phosphate, 97%
Packaging
100g
Price
$69
Updated
2024/03/01
Strem Chemicals
Product number
93-0383
Product name
Lithium dihydrogen phosphate, 97%
Packaging
500g
Price
$274
Updated
2024/03/01
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Lithium dihydrogen phosphate Chemical Properties,Usage,Production

Description

Lithium dihydrogen phosphate, also known as LDP, is a White crystalline powder with the formula LiH2PO4. It is soluble in water. LiH2PO4 is usually prepared by a stoichiometric reaction of Li2СO3 and 85% orthophosphoric acid[1]. It is often used as a raw material for the preparation of cathode materials for lithium batteries or as phosphate in chemical reactions.

Chemical Properties

White crystalline powder

Uses

Precursor for LiMX2O7 (M = Fe, V; x =P, As) cathode materials.1

Uses

Lithium Dihydrogen Phosphate is used in preparation method of lithium hydroxide from lithium-containing low-magnesium brine in lithium phosphate manner.

General Description

This product has been enhanced for energy efficiency.

Solubility in water

At 0°C, the solubility of lithium dihydrogen phosphate in water is about 55.8wt % (126.2 g of LiH2PO4 /100 g of water)[1]. At 22°C, the solubility of lithium dihydrogen phosphate corresponds to ~ 153.8 g of LiH2PO4/100 g of water. At 25°C, it doesn't dissolve in water[2].

References

[1] A.P. Voronov, G.N. Babenko, V.M. Puzikov, A.N. Iurchenko, Growth of LiH2PO4 single crystals from phosphate solutions, Journal of Crystal Growth, 2013, 374, 49–52. [2] R. W. Berg, A. V. Nikiforov, N. J. Bjerrum, Vapor pressure and specific electrical conductivity in the H2O–LiH2PO4–LiPO3 system—a novel electrolyte for water electrolysis at elevated temperature.Ionics, 2021, 27, 703–719.

Lithium dihydrogen phosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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Lithium dihydrogen phosphate Suppliers

Hubei Ruishengxiang Technology Co. , Ltd.
Tel
027-85881289; 15207170057
Email
3605285405@qq.com
Country
China
ProdList
394
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58
Shanghai Yihua Science and technology Co.,Ltd
Tel
18017215653
Email
1602230568@qq.com
Country
China
ProdList
38
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58
Wuhan Chujiang Haoyu Chemical Technology Development Co., Ltd.
Tel
15871235046
Email
371903194@qq.com
Country
China
ProdList
364
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58
Hubei Ruishengxiang Technology Co. , Ltd.
Tel
15207119892
Email
1558829227@qq.com
Country
China
ProdList
177
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58
Hubei Taihechang Biotechnology Co., Ltd
Tel
18607169902 18607169902
Email
18607169902@163.com
Country
China
ProdList
2715
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58
Hebei Dj Yan Chemical Co., Ltd.
Tel
17531190177
Fax
QQ:672648158
Email
peter@yan-xi.com
Country
China
ProdList
1002
Advantage
58
Shijiazhuang Jianxin Biotechnology Co., LTD
Tel
0311-17692708569 17692708569
Email
17692708569@163.com
Country
China
ProdList
320
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58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
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View Lastest Price from Lithium dihydrogen phosphate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Lithium dihydrogen phosphate 13453-80-0
Price
US $20.00-2.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-09-22
Hebei Guanlang Biotechnology Co., Ltd.
Product
Lithium dihydrogen phosphate 13453-80-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-10-10
Career Henan Chemical Co
Product
Lithium dihydrogen phosphate 13453-80-0
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2020-01-02

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