Lithium dihydrogen phosphate

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Lithium dihydrogen phosphate

Product Name: Lithium dihydrogen phosphate
CAS No.: 13453-80-0
Chemical Name: Lithium dihydrogen phosphate
Synonyms: monolithiumphosphate;LITHIUM DIHYDROGEN P;lithiumdihydrophosphate;lithiumphosphate(lih2po4);Lithium hydrogen phosphate;LITHIUM PHOSPHATE MONOBASIC;LITHIUM DIHYDROGEN PHOSPHATE;LithiuM Dihydroxide Phosphate;Lithiumdihydrogenphosphate,97%;lithiumdihydrogenorthophosphate
CBNumber: CB9150683
Molecular Formula: H4LiO4P
Formula Weight: 105.94
MOL File: 13453-80-0.mol

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Lithium dihydrogen phosphate Property

Melting point:: >100°C
Density: 2.5 g/mL at 25 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
form: Powder
Specific Gravity: 2.461
color: white
Water Solubility: Slightly soluble in water.
Stability:: Stable. Incompatible with strong oxidizing agents.
InChI: InChI=1S/Li.H3O4P.H/c;1-5(2,3)4;/h;(H3,1,2,3,4);
InChIKey: AZOORWHXDYIBGH-UHFFFAOYSA-N
SMILES: P(O)(O)(O)=O.[LiH]
CAS DataBase Reference: 13453-80-0(CAS DataBase Reference)
EPA Substance Registry System: Phosphoric acid, monolithium salt (13453-80-0)

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Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38
Safety Statements: 26-36
WGK Germany: 3
RTECS: TC6593950
TSCA: Yes
HS Code: 28352990
Toxicity: mouse,LD50,oral,910mg/kg (910mg/kg),"Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 28, 1978.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 563161
Product name: Lithium phosphate monobasic
Purity: ≥99.99%
Packaging: 25g
Price: $107
Updated: 2024/03/01

Sigma-Aldrich

Product number: 442682
Product name: Lithium phosphate monobasic
Purity: 99%
Packaging: 500g
Price: $148
Updated: 2024/03/01

Alfa Aesar

Product number: A16987
Product name: Lithium dihydrogen phosphate, 97%
Packaging: 250g
Price: $91.7
Updated: 2024/03/01

Strem Chemicals

Product number: 93-0383
Product name: Lithium dihydrogen phosphate, 97%
Packaging: 100g
Price: $69
Updated: 2024/03/01

Strem Chemicals

Product number: 93-0383
Product name: Lithium dihydrogen phosphate, 97%
Packaging: 500g
Price: $274
Updated: 2024/03/01

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Lithium dihydrogen phosphate Chemical Properties,Usage,Production

Description

Lithium dihydrogen phosphate, also known as LDP, is a White crystalline powder with the formula LiH₂PO₄. It is soluble in water. LiH₂PO₄ is usually prepared by a stoichiometric reaction of Li₂СO₃ and 85% orthophosphoric acid^[1]. It is often used as a raw material for the preparation of cathode materials for lithium batteries or as phosphate in chemical reactions.

Chemical Properties

White crystalline powder

Uses

Precursor for LiMX2O7 (M = Fe, V; x =P, As) cathode materials.1

Uses

Lithium Dihydrogen Phosphate is used in preparation method of lithium hydroxide from lithium-containing low-magnesium brine in lithium phosphate manner.

General Description

This product has been enhanced for energy efficiency.

Solubility in water

At 0°C， the solubility of lithium dihydrogen phosphate in water is about 55.8wt % (126.2 g of LiH₂PO₄ /100 g of water)^[1]. At 22°C, the solubility of lithium dihydrogen phosphate corresponds to ~ 153.8 g of LiH₂PO₄/100 g of water. At 25°C, it doesn't dissolve in water^[2].

References

[1] A.P. Voronov, G.N. Babenko, V.M. Puzikov, A.N. Iurchenko, Growth of LiH2PO4 single crystals from phosphate solutions, Journal of Crystal Growth, 2013, 374, 49–52. [2] R. W. Berg, A. V. Nikiforov, N. J. Bjerrum, Vapor pressure and specific electrical conductivity in the H2O–LiH2PO4–LiPO3 system—a novel electrolyte for water electrolysis at elevated temperature.Ionics, 2021, 27, 703–719.

Lithium dihydrogen phosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Lithium dihydrogen phosphate manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: Lithium dihydrogen phosphate 13453-80-0
Price: US $20.00-2.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20 tons
Release date: 2023-09-22

Hebei Guanlang Biotechnology Co., Ltd.

Product: Lithium dihydrogen phosphate 13453-80-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-10-10

Career Henan Chemical Co

Product: Lithium dihydrogen phosphate 13453-80-0
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2020-01-02

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13483-80-0

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