5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester
- Product Name
- 5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester
- CAS No.
- 213771-32-5
- Chemical Name
- 5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester
- Synonyms
- Methyl 5-Bromo-3-methylpicolinate;METHYL-5-BROMO-3-METHYLPICOLINATE (TAX I;5-Bromo-3-methylpicolinic acid methyl ester;methyl 3-methyl-5-bromo-2-pyridinecarboxylate;Methyl 5-bromo-3-methyl-pyridine-2-carboxylate;5-BroMo-3-Methylpyridine-2-Carboxylic Acid Methyl;5-Bromo-3-methyl-2-pyridinecarboxylic acid methyl ester;2-Pyridinecarboxylic acid, 5-bromo-3-methyl-, methyl ester;5-bromo-3-methyl-2-Pyridinecarboxylic acid methyl ester (9CI ACI);2-Pyridinecarboxylic acid, 5-bromo-3-methyl-, methyl ester (9CI, ACI)
- CBNumber
- CB91563729
- Molecular Formula
- C8H8BrNO2
- Formula Weight
- 230.06
- MOL File
- 213771-32-5.mol
5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester Property
- Boiling point:
- 302.2±37.0 °C(Predicted)
- Density
- 1.503
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- -0.17±0.10(Predicted)
- Appearance
- White to yellow Solid
- InChI
- InChI=1S/C8H8BrNO2/c1-5-3-6(9)4-10-7(5)8(11)12-2/h3-4H,1-2H3
- InChIKey
- KZPOANNAYCXMSH-UHFFFAOYSA-N
- SMILES
- C1(C(OC)=O)=NC=C(Br)C=C1C
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- M296493
- Product name
- Methyl5-Bromo-3-methylpicolinate
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- B13142
- Product name
- Methyl5-bromo-3-methylpicolinate
- Purity
- 95%
- Packaging
- 5g
- Price
- $80
- Updated
- 2021/12/16
- Product number
- 4H23-9-X5
- Product name
- Methyl 5-bromo-3-methylpyridine-2-carboxylate
- Purity
- 98%
- Packaging
- 10g
- Price
- $424
- Updated
- 2021/12/16
- Product number
- B13142
- Product name
- Methyl5-bromo-3-methylpicolinate
- Purity
- 95%
- Packaging
- 1g
- Price
- $25
- Updated
- 2021/12/16
- Product number
- 072770
- Product name
- 5-Bromo-3-methylpyridine-2-carboxylicacid methyl ester
- Purity
- 95+%
- Packaging
- 5g
- Price
- $639
- Updated
- 2021/12/16
5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester Chemical Properties,Usage,Production
Synthesis
886365-43-1
74-88-4
213771-32-5
Step C: Synthesis of methyl 5-bromo-3-methylpyridine-2-carboxylate 5-Bromo-3-methylpyridine-2-carboxylic acid (2.6 g, 12 mmol) was dissolved in N,N-dimethylformamide (20.0 mL) followed by addition of potassium carbonate (4.99 g, 36.1 mmol) and iodomethane (1.50 mL, 24.1 mmol). The reaction mixture was stirred at 80 °C for 40 min. After completion of the reaction, the mixture was extracted with ethyl acetate and water by partitioning. The organic layer was separated, washed with saturated brine, dried over anhydrous sodium sulfate, filtered and concentrated to give methyl 5-bromo-3-methylpyridine-2-carboxylate 2.3 g in yellow solid form in 83% yield.
References
[1] Patent: US2013/96144, 2013, A1. Location in patent: Paragraph 0392; 0393
[2] Patent: WO2008/100715, 2008, A1. Location in patent: Page/Page column 34
5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester Suppliers
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View Lastest Price from 5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester manufacturers
- Product
- 5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester 213771-32-5
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons Min
- Release date
- 2021-10-26
- Product
- 5-Bromo-3-methylpyridine-2-carboxylic acid methyl ester 213771-32-5
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kGS
- Release date
- 2018-12-14