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10-Undecenal

Product Name
10-Undecenal
CAS No.
112-45-8
Chemical Name
10-Undecenal
Synonyms
ALDEHYDE C-11 UNDECYLENIC;10-UNDECENYL ALDEHYDE;FEMA 2363;HENDECENAL;9-UNDECENAL;10-UNDECEN-1-AL;INTRELEVEN ALDEHYDE;UNDECYLENIC ALDEHYDE;intreleven aldehyde (IFF);ALDEHYDE C11 ENIC/UNDECYLENIC ALDEHYDE
CBNumber
CB9190322
Molecular Formula
C11H20O
Formula Weight
168.28
MOL File
112-45-8.mol
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10-Undecenal Property

Melting point:
7°C
Boiling point:
98-100 °C3 mm Hg(lit.)
Density 
0.84 g/mL at 25 °C(lit.)
vapor density 
>1 (vs air)
vapor pressure 
8.7Pa at 25℃
refractive index 
n20/D 1.4427(lit.)
FEMA 
3095 | 10-UNDECENAL
Flash point:
199 °F
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly)
pka
0[at 20 ℃]
form 
Crystals or Crystalline Powder
color 
White
Specific Gravity
0.84
Odor
at 1.00 % in dipropylene glycol. waxy aldehydic rose mandarin citrus soapy fatty
Odor Type
aldehydic
Water Solubility 
Insoluble
JECFA Number
330
LogP
4.672 at 25℃
CAS DataBase Reference
112-45-8(CAS DataBase Reference)
NIST Chemistry Reference
10-Undecenal(112-45-8)
EPA Substance Registry System
10-Undecenal (112-45-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
38-10
Safety Statements 
24/25-37/39-26
WGK Germany 
2
RTECS 
YQ2835000
HS Code 
29121900
Toxicity
rabbit,LD50,skin,> 5gm/kg (5000mg/kg),Food and Cosmetics Toxicology. Vol. 11, Pg. 479, 1973.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W309508
Product name
10-Undecenal
Purity
≥95%, FG, stabilized
Packaging
100g
Price
$68.9
Updated
2023/01/07
Sigma-Aldrich
Product number
132276
Product name
Undecylenic aldehyde
Purity
95%
Packaging
25g
Price
$61.3
Updated
2023/01/07
Sigma-Aldrich
Product number
132276
Product name
Undecylenic aldehyde
Purity
95%
Packaging
100g
Price
$134
Updated
2022/05/15
TCI Chemical
Product number
U0011
Product name
10-Undecenal
Purity
>95.0%(GC)
Packaging
25mL
Price
$45
Updated
2024/03/01
TRC
Product number
U788835
Product name
10-UndecylenicAldehyde
Packaging
25g
Price
$55
Updated
2021/12/16
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10-Undecenal Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Chemical Properties

10-Undecenal was identified, for example, in coriander leaf extract. It is a colorless liquid with a fatty, green, slightly metallic, heavy, floral odor. The aldehyde can be synthesized from undecylenic acid, for example, by hydrogenation of the acid chloride (Rosenmund reduction) or by reaction with formic acid in the vapor phase in the presence of titanium dioxide. In perfumery, 10-undecenal is one of the aldehydes essential for creating the “aldehydic note.”
Mixtures containing undecenals with the double bond in other positions (9-, 8-, 7-) are also marketed and used in fragrances, for example, Aldehyde C11 Iso (Givaudan), Intreleven aldehyde (IFF).

Chemical Properties

10-Undecenal has a characteristic fatty, rose odor on dilution. It has an unpleasant sweet, fatty taste. This compound tends to polymerize.

Occurrence

Reported found in coriander leaf (Coriandrum sativum L.).

Uses

10-Undecylenic Aldehyde is derived from the reduction of Undecylenic Acid (U788820) which is used for the manufacture of pharmaceuticals, cosmetics and perfumery, including antidandruff shampoos, antimicrobial powders and as a musk in perfumes and aromas.

Definition

ChEBI: 10-undecenal is an undecenal.

Preparation

By oxidation of the corresponding alcohol or reduction of the corresponding acid; by passing vapors of formic acid and undecylenic acid over TiO2 at 250°C under pressure; by passing vapors of undecylenic acid and methanol over a manganese dioxidebased catalyst; or by reduction of ethyl undecylenate with lithium hydride and sodium in tetrahydrofuran solution at very low temperature (–50°C).

Taste threshold values

Taste characteristics at 2.5 ppm: fatty, oily and aldehydic with a mandarin, citrus nuance.

Synthesis Reference(s)

The Journal of Organic Chemistry, 47, p. 4534, 1982 DOI: 10.1021/jo00144a026
Synthetic Communications, 12, p. 839, 1982 DOI: 10.1080/00397918208065961

Flammability and Explosibility

Non flammable

Safety Profile

LOW toxicity by ingestion and skin contact. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.

10-Undecenal Preparation Products And Raw materials

Raw materials

Preparation Products

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10-Undecenal Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
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View Lastest Price from 10-Undecenal manufacturers

JINING XINHE CHEMICAL CO., LTD
Product
10-Undecenal 112-45-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10ton
Release date
2024-07-22
Hebei Kingfiner Technology Development Co.Ltd
Product
10-Undecenal 112-45-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500000kg
Release date
2023-08-04
Baoji Guokang Healthchem co.,ltd
Product
10-Undecenal 112-45-8
Price
US $80.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10TONS
Release date
2021-06-04

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