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2-IODOBENZALDEHYDE

Product Name
2-IODOBENZALDEHYDE
CAS No.
26260-02-6
Chemical Name
2-IODOBENZALDEHYDE
Synonyms
o-Iodobenzaldehyde;2-IODOBENZALDEHYDE;Benzaldehyde, 2-iodo-;2-Iodobenzaldehyde 97%;2-Iodobenzaldehyde,98%;2-Iodobenzaldehyde o-Iodobenzaldehyde
CBNumber
CB9193914
Molecular Formula
C7H5IO
Formula Weight
232.02
MOL File
26260-02-6.mol
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2-IODOBENZALDEHYDE Property

Melting point:
36-39 °C (lit.)
Boiling point:
129 °C (14 mmHg)
Density 
1.8576 (estimate)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
soluble in Methanol
form 
Low Melting Crystalline Mass or Powder
color 
White to light beige
Sensitive 
Light Sensitive
BRN 
1927296
InChI
InChI=1S/C7H5IO/c8-7-4-2-1-3-6(7)5-9/h1-5H
InChIKey
WWKKTHALZAYYAI-UHFFFAOYSA-N
SMILES
C(=O)C1=CC=CC=C1I
CAS DataBase Reference
26260-02-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
HazardClass 
IRRITANT, AIR SENSITIVE, KEEP COLD
HS Code 
29130000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
550779
Product name
2-Iodobenzaldehyde
Purity
97%
Packaging
1g
Price
$121.8
Updated
2025/07/31
TCI Chemical
Product number
I0610
Product name
2-Iodobenzaldehyde
Purity
>98.0%(GC)
Packaging
1g
Price
$95
Updated
2025/07/31
TCI Chemical
Product number
I0610
Product name
2-Iodobenzaldehyde
Purity
>98.0%(GC)
Packaging
5g
Price
$282
Updated
2025/07/31
TRC
Product number
I689000
Product name
2-Iodo-benzaldehyde
Packaging
2.5g
Price
$120
Updated
2021/12/16
Matrix Scientific
Product number
007490
Product name
2-Iodobenzaldehyde
Purity
98%
Packaging
1g
Price
$28
Updated
2021/12/16
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2-IODOBENZALDEHYDE Chemical Properties,Usage,Production

Chemical Properties

white to light beige low melting crystalline

Uses

2-Iodo-benzaldehyde is a very useful synthetic intermediate. It is halogenated Benzaldehyde (B119740) which is mainly used as a precursor to other organic compounds, such as pharmaceuticals, and plastic additives.

Uses

2-Iodobenzaldehyde may be used as a reactant in the synthesis of the following heterocycles:

  • 2,3-diaryl-1-indenones
  • indolo[1,2-a]quinazolines
  • Baylis-Hillman (BH) adducts
It may also be used in preparing:
  • 5-phenylindazolo[3,2-b]quinazolin-7(5H)-one
  • 4-(3-iodophenyl)-2,2:6,2-terpyridine
  • fluoren-9-one
  • 2-formyl-3′-methoxybiphenyl

General Description

2-Iodobenzaldehyde (o-iodobenzaldehyde) is a 2-halobenzaldehyde derivative. Its crystals belong to the orthorhombic crystal system and P212121 space group.

Synthesis

40138-16-7

26260-02-6

General procedure for the synthesis of 2-iodobenzaldehyde from 2-formylphenylboronic acid: 2-formylphenylboronic acid (0.067 g, 0.4 mmol), copper powder (0.0052 g, 0.08 mmol), (CF3)2CFI (0.178 g, 0.6 mmol) and DMF (2 mL) were added to a closed tube with a rubber stopper. The reaction mixture was stirred at room temperature for 24 hours. Upon completion of the reaction, the resulting suspension was poured into water and extracted with ethyl acetate. The organic layers were combined, dried with anhydrous Na2SO4 and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography using petroleum ether/ethyl acetate (20:1, v/v) as eluent to give 0.086 g of 2-iodobenzaldehyde as a light yellow solid (0.35 mmol, 87% yield).

References

[1] Journal of Fluorine Chemistry, 2016, vol. 189, p. 59 - 67

2-IODOBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-IODOBENZALDEHYDE Suppliers

CMS Chemicals Limited
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View Lastest Price from 2-IODOBENZALDEHYDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2-Iodobenzaldehyde 26260-02-6
Price
US $0.00-0.00/g
Min. Order
10mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-15
Career Henan Chemical Co
Product
2-IODOBENZALDEHYDE 26260-02-6
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02

26260-02-6, 2-IODOBENZALDEHYDERelated Search:


  • 2-IODOBENZALDEHYDE
  • 2-Iodobenzaldehyde o-Iodobenzaldehyde
  • 2-Iodobenzaldehyde,98%
  • o-Iodobenzaldehyde
  • Benzaldehyde, 2-iodo-
  • 2-Iodobenzaldehyde 97%
  • 26260-02-6
  • 6260-02-6
  • 2620-02-6
  • C7H5OI
  • C8H8I2O
  • ALDEHYDE
  • Aldehydes
  • Building Blocks
  • Carbonyl Compounds
  • C7
  • Organic Building Blocks
  • Aromatic Aldehydes & Derivatives (substituted)
  • Aldehydes
  • Phenyls & Phenyl-Het
  • Benzaldehyde
  • Adehydes, Acetals & Ketones
  • Iodine Compounds
  • Phenyls & Phenyl-Het
  • C7
  • Carbonyl Compounds