Physical Properties Uses Preparation Reactions
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Aluminium chloride hexahydrate

Physical Properties Uses Preparation Reactions
Product Name
Aluminium chloride hexahydrate
CAS No.
7784-13-6
Chemical Name
Aluminium chloride hexahydrate
Synonyms
ALUMINUM CHLORIDE HEXAHYDRATE;trichloroalumane;ALUMINUM TRICHLORIDE HEXAHYDRATE;trichloroaluminumhexahydrate;Xerac AC;CS-T-54887;Aluminum chloride cr;Aluminumchloride6H2O;ALUMINIUM CHLORIDE 6H2O;hydrousaluminumchloride
CBNumber
CB9196728
Molecular Formula
AlCl3H2O
Formula Weight
151.35
MOL File
7784-13-6.mol
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Aluminium chloride hexahydrate Property

Melting point:
100°C (dec.)
Density 
2.39
vapor pressure 
1 mm Hg ( 100 °C)
storage temp. 
Store at +15°C to +25°C.
solubility 
water: soluble0.5g/10 mL, clear, colorless
form 
Solid
Specific Gravity
2.398
color 
White To Light Yellow
Odor
Odorless
PH Range
2.5 - 3.5
PH
2.5 (50g/l, H2O, 20℃)
Water Solubility 
477 g/L (20 ºC)
Sensitive 
Moisture Sensitive
Merck 
14,337
Exposure limits
NIOSH: TWA 2 mg/m3
Stability:
Stable, but may decompose upon exposure to moist air or water. Incompatible with acids.Note that decomposition of the anhydrous product, possibly caused by moisture leaking into the container or being trapped within it, may cause a pressure rise in a sealed container, potentially leading to explosive rupture.
LogP
-1.380 (est)
CAS DataBase Reference
7784-13-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,C
Risk Statements 
36/37/38-34-36/38-52
Safety Statements 
26-45-36/37/39
RIDADR 
UN 3260 8/PG 3
WGK Germany 
1
RTECS 
BD0530000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28273200
Toxicity
LD50 orally in Rabbit: 3311 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
237078
Product name
Aluminum chloride hexahydrate
Purity
ReagentPlus , 99%
Packaging
100g
Price
$48.1
Updated
2024/03/01
Sigma-Aldrich
Product number
237078
Product name
Aluminum chloride hexahydrate
Purity
ReagentPlus , 99%
Packaging
500g
Price
$86.3
Updated
2024/03/01
Alfa Aesar
Product number
010622
Product name
Aluminum chloride hexahydrate, Puratronic?, 99.9995% (metals basis)
Packaging
50g
Price
$193
Updated
2024/03/01
Alfa Aesar
Product number
010622
Product name
Aluminum chloride hexahydrate, Puratronic?, 99.9995% (metals basis)
Packaging
5g
Price
$61.4
Updated
2023/06/20
Strem Chemicals
Product number
13-1309
Product name
Aluminum chloride hexahydrate (99.999%-Al) PURATREM
Packaging
25g
Price
$71
Updated
2024/03/01
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Aluminium chloride hexahydrate Chemical Properties,Usage,Production

Physical Properties

White or yellowish deliquescent powder; faint odor of HCl; density 2.40 g/cm3; soluble in water and polar organic solvents such as alcohol; aqueous solution acidic.

Uses

The Aluminium chloride hexahydrate is used in the preparation of deodorant and antiperspirant. Also, it is applied in textile finishing to improve the antistatic characteristics and flammability ratings of various textile materials. Commercially, it is sold as crystalline powder or as a 28% solution in water.

Preparation

Aluminum chloride hexahydrate is prepared by dissolving Al(OH)3 in conc. HCl and passing gaseous HCl through the solution at 0°C. The precipitate is washed with diethyl ether and dried. Alternatively, it is prepared by hydrolyzing anhydrous AlCl3 in cold dilute HCl.

Reactions

Decomposes to alumina when heated at 300°C;
2AlCl3 •6H2O →2Al2O3 + 6HCl + 9H2O
Reacts with caustic soda solution forming gelatinous precipitate of aluminum hydroxide (hydrous aluminum oxide); yields aluminum monobasic stearate, Al(OH)2[OOC(CH2)16CH3] when its solution is mixed with a solution of sodium stearate.

Chemical Properties

white to pale yellow crystalline solid

Uses

The anhydrous form suitable as an acid catalyst, especially in Friedel-Crafts type reactions; in cracking of petroleum; in manufacture of rubbers, lubricants. The hexahydrate form used in preserving wood; disinfecting stables, slaughterhouses, etc.; in deodorants and antiperspirant preparations; refining crude oil; dyeing fabrics; manufacture of parchment paper.

Uses

in preserving wood, disinfecting stables, etc.; in deodorants and antiperspirant preparations; in refining crude oil, and dyeing fabrics; in dental ceramics; in topical astringents

Uses

Pharmaceutical preparations of aluminum chloride hexahydrate are used to treat hyperhidrosis, a condition involving excessive sweating. It is also employed in deodorants, antiperspirant preparations, dyeing fabrics, refining crude oil, textile finishing, manufacturing parchment paper, preserving the wood and disinfecting stables. It also finds use as a reagent in organic synthesis. Aluminum chloride hexahydrate is also useful in water treatment process, medicine and cosmetic products.

Definition

ChEBI: Aluminium trichloride hexahydrate is a hydrate. It contains an aluminium trichloride.

Indications

Aluminum chloride hexahydrate (6.25% Xerac A-C) is an effective antiperspirant that has also an antibacterial effect. It may be useful in cases of acne in which sweating is prominent or appears to be aggravating the disease, but its effects have not been well studied.

Aluminium chloride hexahydrate Preparation Products And Raw materials

Raw materials

Hydrochloric acid Aluminium trichloride,solution Polyacrylamide flocculant Aluminum hydroxide ALUMINUM INGOTS

Preparation Products

1,4,5,8-Naphthalenetetracarboxylic acid 2-(4-Chlorobenzoyl)benzoic acid 4-BROMO-2,2-DIPHENYLBUTYRONITRILE Vat Yellow 4 4-chloro-4'-methoxybenzophenone 3-(o-chlorophenyl)-3-hydroxy-3-phenylpropiononitrile 4-[2-(diethylamino)ethoxy]benzophenone 3-(4-ACETYLAMINOBENZOYL)PROPANOIC ACID 2-BENZOYLBENZOYL CHLORIDE 1-(2,5-Dimethoxyphenyl)-2-oximino-1-propanone TRANS-1,2-DIBENZOYLETHYLENE ETHYL 3-(4-ISOBUTYLPHENYL)-3-METHYL GLYCIDATE Musk xylene 5-(2-Carboxybenzoyl)-2-chlorobenzenesulfonyl chloride (2-Chlorophenyl)phenyl-methanone 1-(2,3-DICHLORO-4-HYDROXYPHENYL)BUTAN-1-ONE Aluminum Chlorohydrate 4-tert-Amylphenol 3-BENZOYLPROPIONIC ACID 2-(4-isobutylphenyl)propionaldehyde oxime SODIUM 3-4-ISOBUTYLPHENYL)-2,3-EPOXYBUTYURATE 3,4-Dichlorobenzophenone 3,3-Diphenylpropionic acid 4-Bromo-2,2-diphenylbutyric acid 3-BENZOYLPHENYLACETIC ACID METHYL 4-(4-(BIS(2-HYDROXYETHYL)AMINO)PHENYL)BUTYRATE ETHYL 3-(6-METHOXY-2-NAPHTHYL)-3-METHYL GLYCIDATE METHYL 3-(6-METHOXY-2-NAPHTHYL)-3-METHYL GLYCIDATE 4-Chlorobenzhydrol water-proofing agnet AC KETAMINE RELATED COMPOUND A (50 MG) (1 -[(2-CHLOROPHENYL)(METHYLIMINO)METHYL]CYLCOPENTA-NOL) Ethyl(4-butyry-2,3-dichloro)phenoxyacetate ALPHA,ALPHA-DIPHENYL-GAMMA-BUTYROLACTONE 8-ACETYL-7-HYDROXY-4-METHYLCOUMARIN 2',5'-Dihydroxyacetophenone BUCLIZINE 1,5-DIHYDROXYANTHRAQUINONE 4-(4-Aminophenyl)butyric acid 1,4-Dibenzoylbutane METHYL 4-(4-(BIS(2-CHLOROETHYL)AMINO)PHENYL)BUTYRATE
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View Lastest Price from Aluminium chloride hexahydrate manufacturers

Hebei Kingfiner Technology Development Co.Ltd
Product
Aluminium chloride hexahydrate 7784-13-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000kg
Release date
2024-06-20
Shaanxi TNJONE Pharmaceutical Co., Ltd
Product
Aluminium Chloride Hexahydrate 7784-13-6
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2024-04-07
Henan Fengda Chemical Co., Ltd
Product
Aluminium chloride hexahydrate 7784-13-6
Price
US $32.00-1.30/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-28

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