ChemicalBook > CAS DataBase List > 4-(METHOXYCARBONYL)PHENYLBORONIC ACID

4-(METHOXYCARBONYL)PHENYLBORONIC ACID

Product Name
4-(METHOXYCARBONYL)PHENYLBORONIC ACID
CAS No.
99768-12-4
Chemical Name
4-(METHOXYCARBONYL)PHENYLBORONIC ACID
Synonyms
4-METHOXYCARBONYLPHENYLBORONIC ACID;METHYL 4-BORONOBENZOATE;Blueberry extract anthocyanin;AKOS BRN-0122;RARECHEM AH PB 0115;Methyl 4-boronobenzo;4-methoxybenzoborate;Methyl p-boronobenzoate;4-Methoxycarbonylphenylboronic;p-(Methoxycarbonyl)boronic acid
CBNumber
CB9216389
Molecular Formula
C8H9BO4
Formula Weight
179.97
MOL File
99768-12-4.mol
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4-(METHOXYCARBONYL)PHENYLBORONIC ACID Property

Melting point:
197-200 °C (lit.)
Boiling point:
345.8±44.0 °C(Predicted)
Density 
1.25±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in methanol.
form 
powder
pka
7.69±0.10(Predicted)
color 
white to off-white
InChI
InChI=1S/C8H9BO4/c1-13-8(10)6-2-4-7(5-3-6)9(11)12/h2-5,11-12H,1H3
InChIKey
PQCXFUXRTRESBD-UHFFFAOYSA-N
SMILES
C1=CC(C(OC)=O)=CC=C1B(O)O
CAS DataBase Reference
99768-12-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
594539
Product name
4-Methoxycarbonylphenylboronic acid
Purity
≥95%
Packaging
1g
Price
$18.36
Updated
2024/03/01
Sigma-Aldrich
Product number
594539
Product name
4-Methoxycarbonylphenylboronic acid
Purity
≥95%
Packaging
5g
Price
$131
Updated
2024/03/01
TCI Chemical
Product number
M1907
Product name
4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$21
Updated
2024/03/01
TCI Chemical
Product number
M1907
Product name
4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$36
Updated
2024/03/01
Alfa Aesar
Product number
H27627
Product name
4-(Methoxycarbonyl)benzeneboronic acid, 97%
Packaging
1g
Price
$61.65
Updated
2024/03/01
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4-(METHOXYCARBONYL)PHENYLBORONIC ACID Chemical Properties,Usage,Production

Chemical Properties

White to light yellow crystal powde

Uses

suzuki reaction

Uses

4-(Methoxycarbonyl)phenylboronic Acid is used in the synthesis and evaluation of several organic compounds including that of 4-Cyclohexylbutyl-N-[(S)-2-oxoazetidin-3-yl]carbamate which is a potent inhibitor of intracellular NAAA activity. Also used in the design and synthesis of BMS-955176 which is a potent, orally active second generation HIV-1 maturation inhibitor.

Uses

4-(Methoxycarbonyl)phenylboronic Acid is a reagent used for• ;Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence1 • ;Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2 • ;One-pot ipso-nitration of arylboronic acids3 • ;Copper-catalyzed nitration4 • ;Cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling5 • ;Reagent used in Preparation of• ;Biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6† • ;Chromenones and their

4-(METHOXYCARBONYL)PHENYLBORONIC ACID Preparation Products And Raw materials

Raw materials

Trimethyl borate Nitrogen 4-Bromotoluene Tetrahydrofuran Potassium permanganate Methanol Magnesium

Preparation Products

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4-(METHOXYCARBONYL)PHENYLBORONIC ACID Suppliers

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View Lastest Price from 4-(METHOXYCARBONYL)PHENYLBORONIC ACID manufacturers

Henan Fengda Chemical Co., Ltd
Product
4-(METHOXYCARBONYL)PHENYLBORONIC ACID 99768-12-4
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Changzhou waston chemical technology Co.,Ltd
Product
4-(METHOXYCARBONYL)PHENYLBORONIC ACID 99768-12-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
according to customer's requirements
Release date
2023-05-11
Hebei Maison Chemical Co.,Ltd.
Product
4-Methoxycarbonylphenylboronic acid 99768-12-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
≥99.0%
Supply Ability
1000kg
Release date
2023-03-28

99768-12-4, 4-(METHOXYCARBONYL)PHENYLBORONIC ACIDRelated Search:

Methyl benzenesulfonate Phenethylboronic acid Phenylboronic acid Basic Violet 1 4-Methoxyphenylboronic acid 4-Hydroxyphenylboronic acid 4-Tolylboronic acid Methyl acetate Acetonitrile Trimethyl borate Paraquat dichloride Methyl 2,2-dimethylphenylacetate Methyl acrylate Methyl benzoate Kresoxim-methyl Methyl anthranilate Methylparaben Isoquinoline-1-carboxylic acid

  • RARECHEM AH PB 0115
  • P-(METHOXYCARBONYL)PHENYLBORONIC ACID
  • METHYL 4-BORONOBENZOATE
  • AKOS BRN-0122
  • 4-METHOXYCARBONYLBENZENEBORONIC ACID
  • 4-METHOXYCARBONYLPHENYLBORONIC ACID
  • 4-CARBOMETHOXYPHENYLBORONIC ACID
  • Methyl 4-boronobenzoate 4-(Methoxycarbonyl)phenylboronic acid
  • 4-METHOXYCATBONYLPHENYLBORONICACID
  • 4-(Methoxycabonyl)phenylboronic acid
  • 4-METHOXYCARBONYLPHENYLBORONIC ACID 97%
  • 4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
  • 4-Methoxycarbonylphenylboronic acid,97%
  • 4-borono-benzoic acid 1-methyl ester
  • 4-Carbomethoxybenzeneboronic acid
  • Methyl p-boronobenzoate
  • p-(Methoxycarbonyl)boronic acid
  • p-borono-benzoic acid methyl ester
  • 4-Methoxycarbonylphenylboronic
  • Methyl 4-boronobenzoate，4-(Methoxycarbonyl)benzeneboronic Acid
  • Methyl 4-boronobenzo
  • 4-(Methoxycarbonyl)benzeneboronic acid 98%
  • 4-methoxycarboxyphenylboronic acid
  • 4-methoxybenzoborate
  • Benzoic acid, 4-borono-, 1-methyl ester
  • Blueberry extract anthocyanin
  • 4-Methoxycarbonylphenylboronic(contains varying amounts of Anhydride)
  • 99768-12-4
  • BORONIC ACID
  • Boronic Acids
  • Boronic Acids and Derivatives
  • Aryl
  • Organometallic Reagents
  • Aryl
  • Boronic acid
  • Organoborons
  • Acids and Derivatives
  • Boron, Nitrile, Thio,& TM-Cpds
  • blocks
  • BoronicAcids
  • Carboxes
  • Boronic Acid series
  • B (Classes of Boron Compounds)
  • CHIRAL CHEMICALS
  • Boronic acids
  • Aryl Boronic Acids
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Monosubstituted Aryl Boronic Acids
  • Organometallic Reagents
  • Boronate Ester
  • Potassium Trifluoroborate