Thioanisole

ChemicalBook > CAS DataBase List > Thioanisole

Uses Use Restriction

Product Name: Thioanisole
CAS No.: 100-68-5
Chemical Name: Thioanisole
Synonyms: MPS;Methyl(phenyl)sulfane;PHSME;METHYL PHENYL SULFIDE;THIOANISOL;Thioanisole (L);Benzene, (methylthio)-;Thioanisole Vetec(TM) reagent grade, 98%;FEMA 3873;THIOANISOLE
CBNumber: CB9233364
Molecular Formula: C7H8S
Formula Weight: 124.2
MOL File: 100-68-5.mol

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Thioanisole Property

Melting point:: −15 °C(lit.)
Boiling point:: 188 °C(lit.)
Density: 1.057 g/mL at 20 °C(lit.)
vapor pressure: 38.5 Pa (20 °C)
refractive index: n20/D 1.587(lit.)
FEMA: 3873 | METHYL PHENYL SULFIDE
Flash point:: 135 °F
storage temp.: Store below +30°C.
solubility: <1mg/l
form: Liquid
Specific Gravity: 1.058
color: Clear light yellow to brown-yellow
Odor: at 0.10 % in propylene glycol. toluene solvent spicy woody sawdust
Odor Type: solvent
Water Solubility: INSOLUBLE
Sensitive: Stench
JECFA Number: 459
BRN: 1904179
Dielectric constant: 4.7599999999999998
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
LogP: 2.9 at 25℃
CAS DataBase Reference: 100-68-5(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, (methylthio)-(100-68-5)
EPA Substance Registry System: Benzene, (methylthio)- (100-68-5)

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Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38
Safety Statements: 26-36/39-36/37
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
RTECS: DA6200000
F: 13
Hazard Note: Harmful/Stench
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29309070
Toxicity: LD50 orally in Rabbit: 891 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: T28002
Product name: Thioanisole
Purity: ReagentPlus , ≥99%
Packaging: 25g
Price: $39.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20825
Product name: Methyl phenyl sulfide
Purity: for synthesis
Packaging: 100mL
Price: $69.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20825
Product name: Methyl phenyl sulfide
Purity: for synthesis
Packaging: 500mL
Price: $249
Updated: 2024/03/01

TCI Chemical

Product number: T0191
Product name: Thioanisole
Purity: >99.0%(GC)
Packaging: 25mL
Price: $21
Updated: 2024/03/01

TCI Chemical

Product number: T0191
Product name: Thioanisole
Purity: >99.0%(GC)
Packaging: 100mL
Price: $42
Updated: 2024/03/01

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Thioanisole Chemical Properties,Usage,Production

Uses

Thioanisole is an important raw material of light curing initiator UV-907.
High efficiency startup agent, used for acid catalytic cracking of N-Z and protective groups of O-benzyl and O-methyl.
Thioanisole is used as pesticide, medicine, dye intermediate.

Use Restriction

FEMA(mg/kg)：Baked products 0.06 ~ 1; non-alcoholic beverages 0.2～2.0 ; grease0.01～0.04 ; gelatin, pudding, sauce, 0.1～1.0 ; meat products 0.4～4.0; seasoning spices0.5～1.0.

Description

Thioanisole is a chiral organosulfide with a wide range of uses in the chemical, pharmaceutical, flavour and fragrance and food industries. Its use in combination with biocatalysts in immobilised cells eliminates the 2-day preparation phase and results in complete bioconversion of thioanisole within 24 hours. Degradative halogenation of thioanisoles by iodine at temperatures between 100 and 150°C produces diphenyl sulfide, diphenyl disulfide, thianthrene and trimethylsulfonium iodide, as well as small amounts of hydrogen sulfide, hydrogen iodide, iodomethane and dimethyl sulfide.

Chemical Properties

Colorless to yellow liquid

Chemical Properties

Methyl phenyl sulfide has an unpleasant odor.

Occurrence

Reported found in coffee.

Uses

Thioanisole is used in oxidative biotransformations.

Uses

Intermediate, solvent for polymeric systems.

Definition

ChEBI: Thioanisole is an aryl sulfide that is thiophenol in which the hydrogen of the thiol group has been replaced by a methyl group. It is an aryl sulfide and a member of benzenes. It is functionally related to a thiophenol.

Aroma threshold values

Aroma characteristics at 0.1% EtoH: toluene solvent, spicy, pungent, woody sawdust.

Taste threshold values

Taste characteristics at .02 to 0.5 ppm: solventy, woody, roasted coffee.

Synthesis Reference(s)

Journal of the American Chemical Society, 112, p. 186, 1990 DOI: 10.1021/ja00157a030
The Journal of Organic Chemistry, 33, p. 4290, 1968 DOI: 10.1021/jo01275a070

Flammability and Explosibility

Non flammable

Thioanisole Preparation Products And Raw materials

Raw materials

Preparation Products

Octreotide acetate 3-METHYLBENZO[B]THIOPHENE 2-Bromo-1-[4-(methylsulfonyl)phenyl]-1-ethanone 2-ACETYL-3-METHYLBENZO[B]THIOPHENE 6-Acetyl-4,4-dimethylthio-chroman 3-METHYLBENZO[B]THIOPHENE-2-CARBOXALDEHYDE 2-Methyl-4-(phenylthio)-2-butanol

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View Lastest Price from Thioanisole manufacturers

Hebei Duling International Trade Co. LTD

Product: Thioanisole 100-68-5
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 300MT/month
Release date: 2022-11-23

Hebei Guanlang Biotechnology Co,.LTD

Product: Methyl phenyl sulfide 100-68-5
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2023-06-06

Hebei Guanlang Biotechnology Co., Ltd.

Product: 2-Chloropyrazine 100-68-5
Price: US $10.00/PCS
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2021-03-15

100-68-5, ThioanisoleRelated Search:

Anise oil Tri(o-tolyl)phosphine Borane-methyl sulfide complex Methyl salicylate Dimethyl sulfide Hydrogen Sulfide CARBONYL SULFIDE Butylated hydroxyanisole tert-Butyl methyl ether Chlorodimethylphenylsilane Triton X-100 Glycidyl phenyl ether Diphenyl sulfide Sodium sulfide POLY(1,4-PHENYLENE SULFIDE) Thiophanate-methyl Silicone oil (high temperature) Methyl

Thioanisole ReagentPlus(R), >=99%

Thioanisole Vetec(TM) reagent grade, 98%

(1-Thiaethyl)benzene

(Methylsulfanyl)benzene

(methylthio)-benzen

1-Phenyl-1-thiaethane

Anisole, thio-

Methyl phenyl sulphide

methylphdenylsulfide

Methyl phenyl sulfide MPS

Benzene, (methylthio)-

THIOMETHYLBENZENE

Thioanisole99%

THIOANISOLE / METHYL PHENYL SULPHIDE

MPS

Methyl phenyl sulfide, Thioanisole

Methylmercaptobenzene

Thioanisole,Methyl phenyl sulfide

Methyl phenyl sulfide,Methyl phenyl sulfide, Thioanisole

Thioanisole, 99% 25GR

Thioanisole, 99% 500GR

Thioanisole (L)

Methyl Phenyl Sulfide Methylthiobenzene

Methyl phenyl sulphide, (Methylsulphanyl)benzene, (Methylthio)benzene

Methyl(phenyl)sulfane

PHENYL METHYL SULFIDE

PHSME

Methylphenylsulfid

METHYLTHIOBENZENE

METHYL PHENYL SULFIDE

FEMA 3873

THIOANISOL

THIOANISOLE

THIOANISOLE, REAGENTPLUS, 99%

METHYL PHENYL SULFIDE 99+%

methylphenylthioether

Phenylthiomethane

Sulfide, methyl phenyl

sulfide,methylphenyl

Thioanisole &gt

Thioanisole, 99%, for synthesis

Thioanisole USP/EP/BP

Thioanisole 100-68-5

THIOANISOLE Extra pure

Methylparaben Impurity 10

100-68-5

100-86-5

C6H5SCH3

CH3SC6H5

Building Blocks

Sulfur Compounds

Sulfides/Disulfides

Organic Building Blocks

Drug Discovery

Other Reagents

sulfide Flavor

Intermediates

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