cyclamen aldehyde

Product Name: cyclamen aldehyde
CAS No.: 103-95-7
Chemical Name: cyclamen aldehyde
Synonyms: 3-(4-Isopropylphenyl)-2-methylpropanal;Cyclamal;2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE;3-p-cumenyl-2-methylpropionaldehyde;3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE;3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE;(R,S)-p-Isopropyl-α-methylhydro-cinnamaldehyde;3-p-;FEMA 2743;aldehydeb
CBNumber: CB9246702
Molecular Formula: C13H18O
Formula Weight: 190.28
MOL File: 103-95-7.mol

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cyclamen aldehyde Property

Boiling point:: 270 °C(lit.)
Density: 0.95 g/mL at 25 °C(lit.)
vapor pressure: 0.3Pa at 20℃
refractive index: n20/D 1.505(lit.)
FEMA: 2743 | 2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE
Flash point:: 228 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Slightly), Ethyl Acetate, Methanol (Slightly)
form: Oil
color: Colourless liquid.
Odor: Powerful floral-green with a characteristic cucumber-melon note used in floral types.
Odor Type: floral
Water Solubility: 66mg/L at 20℃
JECFA Number: 1465
Stability:: Hygroscopic
LogP: 3.4 at 35℃
CAS DataBase Reference: 103-95-7(CAS DataBase Reference)
EPA Substance Registry System: Benzenepropanal, .alpha.-methyl-4-(1-methylethyl)- (103-95-7)

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Safety

Hazard Codes: Xi
Risk Statements: 38
Safety Statements: 26-36
WGK Germany: 2
RTECS: MW4900000
HS Code: 29122990
Toxicity: The acute oral LD₅₀ value in rats was reported as 3*81 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W274305
Product name: 2-Methyl-3-(p-isopropylphenyl)propionaldehyde
Purity: ≥95%, FCC, FG
Packaging: sample-k
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W274305
Product name: 2-Methyl-3-(p-isopropylphenyl)propionaldehyde
Purity: ≥95%, FCC, FG
Packaging: 1kg
Price: $139
Updated: 2024/03/01

Sigma-Aldrich

Product number: W274305
Product name: 2-Methyl-3-(p-isopropylphenyl)propionaldehyde
Purity: ≥95%, FCC, FG
Packaging: 5kg
Price: $511
Updated: 2024/03/01

Sigma-Aldrich

Product number: S405361
Product name: 3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE
Purity: Aldrich
Packaging: 1g
Price: $179
Updated: 2024/03/01

TCI Chemical

Product number: I0377
Product name: 3-(4-Isopropylphenyl)isobutyraldehyde
Purity: >92.0%(GC)
Packaging: 25mL
Price: $78
Updated: 2024/03/01

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cyclamen aldehyde Chemical Properties,Usage,Production

Description

2-Methyl-3-(p-isopropylphenyl) propionaldehyde has a strong, flowery odor. May be prepared by condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst.

Chemical Properties

The commercially available racemate is a colorless to yellowish liquid with an intense floral odor reminiscent of Cyclamen europaeum (cyclamen, sowbread).
Production. Two main processes are used for the industrial synthesis of cyclamen aldehyde:
1) Alkaline condensation of 4-isopropylbenzaldehyde and propanal results, via the aldol, in the formation of 2-methyl-3-(4-isopropylphenyl)-2-propenal. The unsaturated aldehyde is hydrogenated selectively to the saturated aldehyde in the presence of potassium acetate and a suitable catalyst, such as palladium–alumina:
2) Friedel–Crafts reaction of isopropylbenzene and 2-methylpropenal diacetate (methacrolein diacetate) in the presence of titanium tetrachloride/boron trifluoride etherate gives cyclamen aldehyde enolacetate, which is hydrolyzed to aldehyde:
Uses. Cyclamen aldehyde is an important component for obtaining special blossomnotes in perfume compositions, particularly the cyclamen type. Because of its fresh, floral aspect, it is also used as the top note in many other blossomfragrances.

Chemical Properties

2-Methyl-3-(p-isopropylphenyl)-propionaldehyde has a strong, flowery odor

Occurrence

Reported found in nutmeg and starfruit.

Uses

Cyclamal, is an ingredient in perfume. It can also be used in the synthesis of Cyclamen Alcohol (C987655).

Uses

Cyclamen Aldehyde is a very powerful, floral, green note used in many perfumery applications to blend into fresh, floral, green or ozonic/marine accords. It is an ingredient with growing use and importance in helping to build replacement accords for materials disappearing from the Perfumers’ palette. Cyclamen has good overall stability except in extremes of pH. It has good tenacity and substantivity and represents very good value for money in new creations.In addition to its use in numerous perfume compositions, cyclamen aldehyde is an intermediate for the preparation of fungicides and fungistatic substances.

Definition

ChEBI: Xi-3-(4-Isopropylphenyl)-2-methylpropanal is a monoterpenoid.

Preparation

By condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst

Safety Profile

Moderately toxic by ingestion. A human skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.

Synthesis

Cyclamen aldehyde is synthesized from Cuminaldehyde plus Ropionaldehyde by condensation followed by selective hydrogenation and finally dehydrogenation of the Cyclamen alcohol to aldehyde.

cyclamen aldehyde Preparation Products And Raw materials

Raw materials

Tropine Lily aldehyde Potassium hydroxide 2-Methylpropanedioic acid Sodium ethoxide tert-Butylbenzene PUMICE STONE trans-Cinnamic acid Titanium tetrachloride Isobutyraldehyde Diethyl malonate Cuminaldehyde trans-Cinnamaldehyde

Preparation Products

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View Lastest Price from cyclamen aldehyde manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: cyclamen aldehyde 103-95-7
Price: US $60.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-11-25

Hebei Weibang Biotechnology Co., Ltd

Product: cyclamen aldehyde 103-95-7
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-05

Hebei Chuanghai Biotechnology Co,.LTD

Product: cyclamen aldehyde 103-95-7
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-13

103-95-7, cyclamen aldehydeRelated Search:

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(R,S)-p-Isopropyl-α-methylhydro-cinnamaldehyde

P-ISOPROPYL-A-METHYLHYDROCINNAMALDEHYDE

CYCLAMEN ALDEHYDE

FEMA 2743

2-METHYL-3-(P-ISOPROPYLPHENYL)PROPION- &

3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE

4-ISOPROPYL-ALPHA-METHYLHYDROCINNAMALDEHYDE

A-METHYL-P-ISOPROPYLHYDROCINNAMIC ALDEHYDE

ALPHA-METHYL-P-ISOPROPYLHYDROCINNAMIC ALDEHYDE

1-(4-ISOPROPYLPHENYL)-2-PROPANAL

2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE

2-Methyl-3-(para-isopropyl phenyl)propionaldehyde

Alpha-methyl-p-isopropylphenylpropanaldehyde

Benzenepropanal, a-methyl-4-(1-methylethyl)-

.alpha.-methyl-4-(1-methylethyl)-Benzenepropanal

3-(4-iso-Propylphenyl)-2-methylpropanal

3-(4-Isopropylphenyl)-2-methylpropanal

3-(p-Isopropylphenyl)isobutyraldehyde

3-p-

3-p-cumenyl-2

3-p-cumenyl-2-

3-p-cumenyl-2-methylpropionaldehyde

Aldehyde B

aldehydeb

alpha-methyl-4-(1-methylethyl)-benzenepropana

alpha-methyl-4-(1-methylethyl)benzenepropanal

alpha-Methyl-p-isopropylhydrocinnamaldehyde

Benzenepropanal, alpha-methyl-4-(1-methylethyl)-

Benzenepropanal,.alpha.-methyl-4-(1-methylethyl)-

beta-Methyl-p-iso-propyl phenyl propionaldehyde

Cyclamal

Hydrocinnamaldehyde, p-isopropyl-alpha-methyl-

-Methyl-4-(1-methylethyl)benzenepropanal

p-isopropyl-alpha-methyl-hydrocinnamaldehyd

p-Isopropyl-alpha-methylhydrocinnamaldehyde

p-Isopropyl-alpha-methylhydrocinnamic aldehyde

p-isopropyl-alpha-methylhydrocinnamicaldehyde

p-Isopropyl-alpha-methylphenylpropyl aldehyde

p-isopropyl-alpha-methylphenylpropylaldehyde

p-isopropyl-alpha-methylpropiophenaldehyde

p-iso-Propyl-methylhyrocinnamaldehyde

CYCLAMON ALDEHYDE EXTRA

Rabbit ears grass aldehyde

PARA-ISOPROPYL-ALPHA-METHYL-HYDROCINNAMALDEHYDE

4-PROPYL-ALPHA-METHYLHYDROCINNAMALDEHYDE

3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE 90+%

p-Isopropyl-α-methylpropiophenaldehyde

p-Isopropyl-α-methylhydrocinnamaldehyde

p-Isopropyl-α-methylphenylpropyl aldehyde

4-Isopropyl-α-methylbenzenepropanal

4-Isopropyl-α-methylhydrocinnamaldehyde

p-Isopropyl-α-methylbenzenepropionaldehyde

2-methvl-3-(P-isopropylphenyl)-propionaldehyde

3-(4-isopropylphenyl)butyraldehyde

3-(4-propan-2-ylphenyl)butanal

3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE

Benzenepropanal, α-methyl-4-(1-methylethyl)-

3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE USP/EP/BP