ChemicalBook > CAS DataBase List > 3-(Trifluoromethoxy)bromobenzene

3-(Trifluoromethoxy)bromobenzene

Product Name
3-(Trifluoromethoxy)bromobenzene
CAS No.
2252-44-0
Chemical Name
3-(Trifluoromethoxy)bromobenzene
Synonyms
1-BROMO-3-(TRIFLUOROMETHOXY)BENZENE;1-Bromo-3-(trifL;BUTTPARK 91\57-27;uoromethoxy)benzene;3-(trifluoromrthoxy)bromobenzene;3-(TRIFLUOROMETHOXY)BROMOBENZENE;M-BROMO(TRIFLUOROMETHOXY)BENZENE;3-BROMO(TRIFLUOROMETHOXY)BENZENE;3-Bromo-1-(trifluoromethoxy)benzene;3-(Trifluoromethoxy)bromobenzene99%
CBNumber
CB9266667
Molecular Formula
C7H4BrF3O
Formula Weight
241.01
MOL File
2252-44-0.mol
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3-(Trifluoromethoxy)bromobenzene Property

Boiling point:
156-158 °C
Density 
1.62 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.462(lit.)
Flash point:
145 °F
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
1.64
BRN 
1945938
CAS DataBase Reference
2252-44-0(CAS DataBase Reference)
NIST Chemistry Reference
3-(Trifluoromethoxy)bromobenzene(2252-44-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-24/25
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29049090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
343870
Product name
1-Bromo-3-(trifluoromethoxy)benzene
Purity
99%
Packaging
5g
Price
$11.08
Updated
2024/03/01
TCI Chemical
Product number
B2007
Product name
1-Bromo-3-(trifluoromethoxy)benzene
Purity
>98.0%(GC)
Packaging
5g
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
B2007
Product name
1-Bromo-3-(trifluoromethoxy)benzene
Purity
>98.0%(GC)
Packaging
25g
Price
$60
Updated
2024/03/01
Alfa Aesar
Product number
A16561
Product name
1-Bromo-3-(trifluoromethoxy)benzene, 98+%
Packaging
1g
Price
$24.8
Updated
2021/12/16
Alfa Aesar
Product number
A16561
Product name
1-Bromo-3-(trifluoromethoxy)benzene, 98+%
Packaging
5g
Price
$87.6
Updated
2021/12/16
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3-(Trifluoromethoxy)bromobenzene Chemical Properties,Usage,Production

Chemical Properties

Clear very faintly yellow liquid

Uses

1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl].

General Description

1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes.

3-(Trifluoromethoxy)bromobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-(Trifluoromethoxy)bromobenzene manufacturers

Speranza Chemical Co., Ltd.
Product
1-bromo-3-(trifluoromethoxy)benzene 2252-44-0
Price
US $160.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
300MT/year
Release date
2019-12-24
Henan Fengda Chemical Co., Ltd
Product
3-(Trifluoromethoxy)bromobenzene 2252-44-0
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Henan Aochuang Chemical Co.,Ltd.
Product
3-(Trifluoromethoxy)bromobenzene 2252-44-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-08

2252-44-0, 3-(Trifluoromethoxy)bromobenzeneRelated Search:


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  • Benzene, 1-bromo-3-(trifluoromethoxy)-
  • 3-(Trifluoromethoxy)bromobenzene ISO 9001:2015 REACH
  • 2252-44-0
  • C7H4BrF3O
  • ARYL HALIDE
  • Building Blocks
  • Organic Building Blocks
  • Ethers
  • Oxygen Compounds
  • Fluorobenzene
  • Trifluoroanisole series
  • Aromatic Ethers
  • Halides
  • Phenyls & Phenyl-Het
  • Miscellaneous
  • Phenyls & Phenyl-Het
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • alkyl bromide