2,4,6-Trimethyl-1,3-phenylenediamine
- Product Name
- 2,4,6-Trimethyl-1,3-phenylenediamine
- CAS No.
- 3102-70-3
- Chemical Name
- 2,4,6-Trimethyl-1,3-phenylenediamine
- Synonyms
- 3MPDA;MesDA;-m-phenyL;2,4-DIAMINOMESITYLENE;2,4-Mesitylenediamine;Mesitylene-2,4-diamine;2,4-Mesitylenediamine (7CI,8CI);2,4,6-Trimethyl-3-amino-aniline;2,4,6-trimethyl-3-benzenediamine;1,3-DIAMINO-2,4,6-TRIMETHYLBENZENE
- CBNumber
- CB9306097
- Molecular Formula
- C9H14N2
- Formula Weight
- 150.22
- MOL File
- 3102-70-3.mol
2,4,6-Trimethyl-1,3-phenylenediamine Property
- Melting point:
- 89-91 °C(lit.)
- Boiling point:
- 297.7±35.0 °C(Predicted)
- Density
- 1.051±0.06 g/cm3(Predicted)
- vapor pressure
- 0.009Pa at 20℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- pka
- 5.03±0.10(Predicted)
- form
- Solid
- color
- Brown
- Water Solubility
- 22.7g/L at 20℃
- BRN
- 2717221
- InChIKey
- ZVDSMYGTJDFNHN-UHFFFAOYSA-N
- LogP
- 0.41 at 24.2℃
- CAS DataBase Reference
- 3102-70-3(CAS DataBase Reference)
- NIST Chemistry Reference
- 2,4,6-Trimethyl-1,3-phenylenediamine(3102-70-3)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36
- RIDADR
- 2811
- WGK Germany
- 3
- RTECS
- CZ1607000
- F
- 8-9-23
- HazardClass
- 6.1(a)
- PackingGroup
- II
- HS Code
- 2921599090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 263885
- Product name
- 2,4,6-Trimethyl-m-phenylenediamine
- Purity
- 96%
- Packaging
- 25g
- Price
- $376
- Updated
- 2025/07/31
- Product number
- 263885
- Product name
- 2,4,6-Trimethyl-m-phenylenediamine
- Purity
- 96%
- Packaging
- 100g
- Price
- $476
- Updated
- 2025/07/31
- Product number
- T1275
- Product name
- 2,4,6-Trimethyl-1,3-phenylenediamine
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $81
- Updated
- 2025/07/31
- Product number
- T1275
- Product name
- 2,4,6-Trimethyl-1,3-phenylenediamine
- Purity
- >98.0%(GC)
- Packaging
- 100g
- Price
- $242
- Updated
- 2025/07/31
- Product number
- T796055
- Product name
- 2,4,6-Trimethyl-1,3-benzenediamine
- Packaging
- 100mg
- Price
- $110
- Updated
- 2021/12/16
2,4,6-Trimethyl-1,3-phenylenediamine Chemical Properties,Usage,Production
Chemical Properties
Light yellow powder
Uses
2,4,6-Trimethyl-1,3-benzenediamine is a compound used in the synthesis of various polymers.
Uses
2,4,6-Trimethyl-1,3-phenylenediamine is a compound used in the synthesis of various polymers.
Flammability and Explosibility
Non flammable
Synthesis
608-50-4
3102-70-3
The general procedure for the synthesis of 2,4,6-trimethyl-1,3-benzenediamine from 1,3-dinitro-2,4,6-trimethylbenzene is as follows: In a 1000 L coil-cooled nitrification kettle, 114 kg of homotrimethylbenzene was added and mixed with 700 kg of mixed acid (H2SO4 and HNO3 in the ratio of 75:25 by weight) under stirring. The reaction temperature was controlled to be 20°C with continuous titration for 35 minutes, followed by raising the temperature to 90°C and maintaining it for 35 minutes. The reaction was layered upon completion and the spent acid was used for the next batch of nitrification. To the organic layer, 500 kg of water and 2 kg of caustic soda were added, stirred for 1 hour and layered. A further 500kg of water was used to wash 2,4,6-trimethyl-m-dinitrobenzene. The washed 2,4,6-trimethyl-m-dinitrobenzene was added to a 1000L autoclave with 10kg Ni catalyst and 320kg methanol. After replacing the gas in the kettle with nitrogen and hydrogen, the temperature was raised to 65°C to start stirring and the hydrogenation reaction was carried out. The hydrogenation pressure was controlled to be 4MPa, the temperature was 80°C, and the hydrogenation reaction lasted for 1 hour. At the end of the reaction, hydrogen was discharged, methanol was evaporated, crystallized by cooling and filtered to obtain 2,4,6-trimethyl-m-phenylenediamine. The product was dried to obtain 135 kg with 99.7% purity and 94.7% yield.
References
[1] Bl.Soc.franc.Phot., vol. <3> 15, p. 92
[2] Chem. Zentralbl., 1928, vol. 99, # II, p. 1415
[3] Journal of the American Chemical Society, 1948, vol. 70, p. 4202
[4] Canadian Journal of Chemistry, 1988, vol. 66, p. 1867 - 1871
[5] Patent: CN105461567, 2016, A. Location in patent: Paragraph 0015; 0021
2,4,6-Trimethyl-1,3-phenylenediamine Preparation Products And Raw materials
Raw materials
Preparation Products
2,4,6-Trimethyl-1,3-phenylenediamine Suppliers
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- Europe
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View Lastest Price from 2,4,6-Trimethyl-1,3-phenylenediamine manufacturers
- Product
- 2,4,6-Trimethyl-1,3-phenylenediamine 3102-70-3
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-15
- Product
- 2,4,6-Trimethyl-1,3-phenylenediamine 3102-70-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-10-10
- Product
- 2,4,6-Trimethyl-1,3-phenylenediamine 3102-70-3
- Price
- US $50.60/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 5000kg
- Release date
- 2024-08-20