Isobornyl acrylate

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Isobornyl acrylate

Description Sources

Product Name: Isobornyl acrylate
CAS No.: 5888-33-5
Chemical Name: Isobornyl acrylate
Synonyms: iboa;IBXA;exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate;sr506;ebecryliboa;(1R,2R,4R)-rel-1,7,7-TriMethylbicyclo[2.2.1]heptan-2-yl acrylate;qm589;EM70DN;sartomer506;al-co-cureiba
CBNumber: CB9327469
Molecular Formula: C13H20O2
Formula Weight: 208.3
MOL File: 5888-33-5.mol

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Isobornyl acrylate Property

Melting point:: <-35°C
Boiling point:: 119-121 °C15 mm Hg(lit.)
Density: 0.986 g/mL at 25 °C(lit.)
vapor pressure: 1.3Pa at 20℃
refractive index: n20/D 1.476(lit.)
Flash point:: 207 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: clear liquid
color: Colorless to Almost colorless
Water Solubility: Difficult to mix in water.
FreezingPoint: 5
Sensitive: Light Sensitive
BRN: 2254825
Stability:: Light sensitive
InChIKey: PSGCQDPCAWOCSH-BREBYQMCSA-N
LogP: 4.52 at 20℃
CAS DataBase Reference: 5888-33-5(CAS DataBase Reference)
EPA Substance Registry System: Isobornyl acrylate (5888-33-5)

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Safety

Hazard Codes: Xn,N,Xi
Risk Statements: 20/22-36/37/38-51/53
Safety Statements: 26-36-61-28
RIDADR: UN 3082 9 / PGIII
WGK Germany: 2
RTECS: UD3940000
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29161290
Toxicity: LD50 oral in rat: 4890mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 392103
Product name: Isobornyl acrylate
Purity: technical grade, contains 200 ppm monomethyl ether hydroquinone as inhibitor
Packaging: 100ml
Price: $52.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 392103
Product name: Isobornyl acrylate
Purity: technical grade, contains 200 ppm monomethyl ether hydroquinone as inhibitor
Packaging: 1l
Price: $225
Updated: 2024/03/01

TCI Chemical

Product number: I0638
Product name: Isobornyl Acrylate (stabilized with MEHQ)
Purity: >90.0%(GC)
Packaging: 25g
Price: $27
Updated: 2024/03/01

TCI Chemical

Product number: I0638
Product name: Isobornyl Acrylate (stabilized with MEHQ)
Purity: >90.0%(GC)
Packaging: 500g
Price: $104
Updated: 2024/03/01

Alfa Aesar

Product number: L09977
Product name: Isobornyl acrylate, tech. 85%, stab. with 100ppm 4-methoxyphenol
Packaging: 250g
Price: $69.3
Updated: 2024/03/01

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Isobornyl acrylate Chemical Properties,Usage,Production

Description

Isobornyl acrylate can be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP)¹. It is a photo-polymerizable monomer that is employed in micro-fluidic devices because of desirable properties, such as inertness, transparency, and resolution².

Sources

https://www.sigmaaldrich.com/catalog/product/aldrich/392103?lang=en&region=US
López-García, M. D. C., D. J. Beebe, and W. C. Crone. Characterization of poly(isobornyl acrylate) as a construction material for microfluidic applications. Journal of Applied Polymer Science. 2007:1894–1902.

Uses

Isobornyl acrylate (IBA) is used as UVcuring EBcuring adhesive, it can also be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP).

Application

Isobornyl acrylate can be used as a co-monomer with other acrylic monomers in the preparation of pressure-sensitive adhesives (PSAs) for optical applications. It is also used in the development of high-performance and stable polymer gate dielectrics for organic thin-film transistors (OTFTs). Furthermore, it can also used in the preparation of UV-curable waterborne polyurethane (WPU) by copolymerization.

Hazard

Moderately toxic by ingestion. Low toxicity by skin contact. A moderate skin and mild eye irritant.

Flammability and Explosibility

Non flammable

Synthesis

Isobornyl acrylate is prepared by reacting (-)- borneol,triethylamine with acryloyl chloride in anhydrous THF.Dissolve (-)- borneol (1.00 g, 6.48 mmol, 1 equiv) and triethylamine (0.98 g, 9.72 mmol, 1.5 equiv) in anhydrous THF (20 mL) in a 100 mL round-bottom flask. Add acryloyl chloride (0.88 g, 9.72 mmol, 1.5 equiv) dropwise to the reaction mixture at 0 °C. Allow the reaction to stir at room temperature overnight. Filter the reaction solution. Concentrate the reaction solution on the rotary evaporator. Wash the mixture with water (20 mL). Extract the mixture with dichloromethane (3x20 mL). Dry the combined organic phases over anhydrous sodium sulfate. Filter and concentrate the residue. Purify the crude product further by silica gel column chromatography (petroleum ether/ethyl acetate = 4:1) to obtain isobornyl acrylate.
Fig Synthetic method of Isobornyl acrylate

Isobornyl acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Isobornyl acrylate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Bornylacrylate 5888-33-5
Price: US $70.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-22

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Acrylic acid isobornyl ester 5888-33-5
Price: US $70.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-23

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Isobornyl acrylate 5888-33-5
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-15

5888-33-5, Isobornyl acrylateRelated Search:

Tris(trimethylsilyl)phosphate 6-Benzylaminopurine Ethyl acrylate BUTYL OLEATE Methyl propiolate Hydroxypropyl acrylate Acrylic acid Methyl acrylate Ethyl(ethoxymethylene)cyanoacetate Diethyl ethoxymethylenemalonate 2-Ethylhexyl acrylate Dodecyl acrylate DIHYDRODICYCLOPENTADIENYL ACRYLATE 4-Acryloylmorpholine Sodium allylsulfonate Allylboronic acid pinacol ester Isobornyl methacrylate ETHOXYLATED BISPHENOL A DIACRYLATE

1,7,7-trimethylbicyclo(2.2.1)hept-2-ylester,exo-2-propenoicaci

1,7,7-trimethylbicyclo[2.2.1]hept-2-ylester,exo-2-propenoicaci

1,7,7-trimethylbicyclo[2.2.1]hept-2-ylester,exo-2-Propenoicacid

al-co-cureiba

ebecryliboa

exo-isobornylacrylate

IBXA

Isobornyl acrylate, stabilized with 100ppm 4-methoxyphenol

EM70DN

Isobornyl acrylate, 93%, stabilized with 200 - 400 ppm MEHQ

Isobornyl acrylate 5888-33-5

5888-33-5 Isobornyl acrylate IBOA

sr506(acrylate)

ISOBORNYL ACRYLATE

(1,7,7-trimethyltricyclo[2.2.1]hepten-2-yl)-2-propenoate

ACRYLIC ACID ISOBORNYL ESTER

ISOBORNYL ACRYLATE, TECH.

Isobornylacrylate,tech.85%

2-Propenoic acid, (1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-yl ester, rel-

exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacrylat

ISOBOOMYL ACRYLATE

Isobornyl acrylate, tech. 85%, stab. with 100ppm 4-methoxyphenol

Isobornyl Acrylate (stabilized with MEHQ)

[(1S,4S)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] prop-2-enoate

acrylic acid [(1S,4S)-1,7,7-trimethylnorbornan-2-yl] ester

Isobornyl acrylate,Acrylic acid isobornyl ester

iboa

lightacrylateib-xa

qm589

sartomer506

sr506

Bornylacrylate

exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

IBOA Isobornyl acrylate

Isobornyl Acrylate, Technical

(1R,2R,4R)-rel-1,7,7-TriMethylbicyclo[2.2.1]heptan-2-yl acrylate

Isobornyl acrylate technical grade, contains 200 ppm monomethyl ether hydroquinone as inhibitor

Isobornyl acrylate, technical, 85%, stabilized

Photomer 4012

IsobornylAcrylate(stabilizedwithMEHQ)&gt

Isobornyl acrylate, tech. 85%, stab. stab. with 100ppm 4-met

lsobornyl acrylate

(1S,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl prop-2-enoate

1,7,7-trimethylbicyclo[2.2.1]hept-2-yl prop-2-enoate

Lsobornyl acrylate IBOA

Sinomer? IBOA Monomer / Isobornyl acrylate

(1R,2R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acrylate

5888-33-5

5888-35-5

5888-55-3

Esters

Organic Building Blocks

C12 to C63

Carbonyl Compounds

Building Blocks