TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
- Product Name
- TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
- CAS No.
- 31011-57-1
- Chemical Name
- TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
- Synonyms
- Titanium(iv) chloride tet;Tetrachlorobis(THF)titanium;oxolane:tetrachlorotitanium;Titanium (IV) Chloride THF Complex;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM;Bis(tetrahydrofuran)tetrachlorotitanium;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV);Titanium tetrachloride bis(tetrahydrofuran);TITANIUM(IV) CHLORIDE-TETRAHYDOFURAN COMPLEX;Tetrachlorobis(tetrahydrofurane)titanium(IV)
- CBNumber
- CB9359422
- Molecular Formula
- C8H16Cl4O2Ti
- Formula Weight
- 333.89
- MOL File
- 31011-57-1.mol
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Property
- Melting point:
- 126-128 °C(lit.)
- Flash point:
- 1 °F
- storage temp.
- 2-8°C
- form
- crystal
- color
- yellow
- Water Solubility
- Reacts with water
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Sensitive
- Moisture Sensitive
- InChI
- InChI=1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4
- InChIKey
- LXWBMENBONGPSB-UHFFFAOYSA-J
- SMILES
- [Ti](Cl)(Cl)(Cl)Cl.C1COCC1.C1COCC1
- CAS DataBase Reference
- 31011-57-1(CAS DataBase Reference)
Safety
- Hazard Codes
- C
- Risk Statements
- 14-34-37
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 2925 4.1/PG 2
- WGK Germany
- 3
- F
- 3-10
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- II
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240Ground/bond container and receiving equipment.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 395404
- Product name
- Titanium(IV) chloride tetrahydrofuran complex
- Purity
- 97%
- Packaging
- 5g
- Price
- $90.1
- Updated
- 2025/07/31
- Product number
- 395404
- Product name
- Titanium(IV) chloride tetrahydrofuran complex
- Purity
- 97%
- Packaging
- 25g
- Price
- $276.45
- Updated
- 2025/07/31
- Product number
- 22-1080
- Product name
- Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
- Packaging
- 5g
- Price
- $63
- Updated
- 2024/03/01
- Product number
- 22-1080
- Product name
- Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
- Packaging
- 25g
- Price
- $244
- Updated
- 2024/03/01
- Product number
- 22-1080
- Product name
- Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
- Packaging
- 100g
- Price
- $732
- Updated
- 2024/03/01
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Chemical Properties,Usage,Production
Chemical Properties
The reaction of tetrachlorodi(tetrahydrofuran)titanium(IV) and magnesium in tetrahydrofuran under argon protection gives [Ti(MgCl)2(THF)]2. It reacts with magnesium directly in a nitrogen atmosphere to give TiN(MgCl)2(THF), which can then be reacted with iodine, via the ITiN(MgCl)2 intermediate, to produce Ti=N(MgCl). Stannous chloride can also reduce it to produce TiCl3(THF)3 and green [TiCl2(THF)4][SnCl5(THF)]: 2 TiCl4(THF)2 + SnCl2 → [trans-TiCl2(THF)4][SnCl5(THF)] + TiCl3(THF)3
Uses
Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.
reaction suitability
core: titanium
reagent type: Lewis acid
reagent type: catalyst
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Preparation Products And Raw materials
Raw materials
Preparation Products
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