ChemicalBook > CAS DataBase List > TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)

Product Name: TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
CAS No.: 31011-57-1
Chemical Name: TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
Synonyms: Titanium(iv) chloride tet;Tetrachlorobis(THF)titanium;oxolane:tetrachlorotitanium;Titanium (IV) Chloride THF Complex;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM;Bis(tetrahydrofuran)tetrachlorotitanium;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV);Titanium tetrachloride bis(tetrahydrofuran);TITANIUM(IV) CHLORIDE-TETRAHYDOFURAN COMPLEX;Tetrachlorobis(tetrahydrofurane)titanium(IV)
CBNumber: CB9359422
Molecular Formula: C8H16Cl4O2Ti
Formula Weight: 333.89
MOL File: 31011-57-1.mol

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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Property

Melting point:: 126-128 °C(lit.)
Flash point:: 1 °F
storage temp.: 2-8°C
form: crystal
color: yellow
Water Solubility: Reacts with water
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Sensitive: Moisture Sensitive
InChI: InChI=1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4
InChIKey: LXWBMENBONGPSB-UHFFFAOYSA-J
SMILES: [Ti](Cl)(Cl)(Cl)Cl.C1COCC1.C1COCC1
CAS DataBase Reference: 31011-57-1(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 14-34-37
Safety Statements: 26-36/37/39-45
RIDADR: UN 2925 4.1/PG 2
WGK Germany: 3
F: 3-10
TSCA: No
HazardClass: 8
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 395404
Product name: Titanium(IV) chloride tetrahydrofuran complex
Purity: 97%
Packaging: 5g
Price: $90.1
Updated: 2025/07/31

Sigma-Aldrich

Product number: 395404
Product name: Titanium(IV) chloride tetrahydrofuran complex
Purity: 97%
Packaging: 25g
Price: $276.45
Updated: 2025/07/31

Strem Chemicals

Product number: 22-1080
Product name: Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
Packaging: 5g
Price: $63
Updated: 2024/03/01

Strem Chemicals

Product number: 22-1080
Product name: Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
Packaging: 25g
Price: $244
Updated: 2024/03/01

Strem Chemicals

Product number: 22-1080
Product name: Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
Packaging: 100g
Price: $732
Updated: 2024/03/01

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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Chemical Properties,Usage,Production

Chemical Properties

The reaction of tetrachlorodi(tetrahydrofuran)titanium(IV) and magnesium in tetrahydrofuran under argon protection gives [Ti(MgCl)2(THF)]2. It reacts with magnesium directly in a nitrogen atmosphere to give TiN(MgCl)2(THF), which can then be reacted with iodine, via the ITiN(MgCl)2 intermediate, to produce Ti=N(MgCl). Stannous chloride can also reduce it to produce TiCl3(THF)3 and green [TiCl2(THF)4][SnCl5(THF)]: 2 TiCl4(THF)2 + SnCl2 → [trans-TiCl2(THF)4][SnCl5(THF)] + TiCl3(THF)3

Uses

Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.

reaction suitability

core: titanium
reagent type: Lewis acid
reagent type: catalyst

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Suppliers

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31011-57-1, TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)Related Search:

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Titanium tetrachloride bis(tetrahydrofuran)

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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) ISO 9001：2015 REACH

Titanium (IV) Chloride THF Complex

31011-57-1

C8H16Cl4O2Ti

TiCl42C4H8O

TiCl42THF

2C4H8OCl4Ti

TiCl4C4H8O2

Lewis Acids

Synthetic Reagents

Titanium

metal halide