Bis(triphenylphosphine)palladium(II) chloride

Structure

Product Name: Bis(triphenylphosphine)palladium(II) chloride
CAS No.: 13965-03-2
Chemical Name: Bis(triphenylphosphine)palladium(II) chloride
Synonyms: DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;(PPh3)2PdCl2;DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDE;Bis(triphenylphosphine)dichloropalladium;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);TRIPHENYLPHOSPHINE PALLADIUM CHLORIDE;Bis(triphenylphosphine)palladium(ll) chloride;PALLADIUM BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
CBNumber: CB9364066
Molecular Formula: C36H30Cl2P2Pd
Formula Weight: 701.9
MOL File: 13965-03-2.mol

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Bis(triphenylphosphine)palladium(II) chloride Property

Melting point:: 260°C
vapor pressure: 0Pa at 25℃
RTECS: RT3578000
storage temp.: Store below +30°C.
solubility: Chloroform (Slightly), Dichloromethane (Slightly, Heated), Methanol (Slightly,
form: Powder
color: Yellow
Water Solubility: Insoluble in water. Soluble in benzene, and toluene.
Sensitive: Hygroscopic
BRN: 4935975
InChI: InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChIKey: ILBDOZRDKNIJBS-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl
LogP: 5.69 at 20℃
CAS DataBase Reference: 13965-03-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-22-40-19
Safety Statements: 37/39-26-36/37
WGK Germany: 3
F: 3-10-21
TSCA: No
HS Code: 28439090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.04174
Product name: Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd)
Purity: for synthesis
Packaging: 1g
Price: $148
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.04174
Product name: Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd)
Purity: for synthesis
Packaging: 5G
Price: $550
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208671
Product name: Bis(triphenylphosphine)palladium(II) dichloride
Purity: 98%
Packaging: 1g
Price: $68.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208671
Product name: Bis(triphenylphosphine)palladium(II) dichloride
Purity: 98%
Packaging: 5g
Price: $214
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.04174
Product name: Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd)
Purity: for synthesis
Packaging: 500mg
Price: $111
Updated: 2023/01/07

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Bis(triphenylphosphine)palladium(II) chloride Chemical Properties,Usage,Production

Structure

Several crystal structures containing PdCl2(PPh3)2 have been reported. In all of the structures,Bis(triphenylphosphine)palladium(II) chloride adopts a square planar coordination geometry and the trans isomeric form.

Chemical Properties

Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. This yellow solid is insoluble in water but can dissolve in some organic solvents, such as toluene and benzene, and is slightly soluble in acetone and chloroform. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex adopts a square planar geometry and numerous similar complexes are known, with different phosphine ligands.

Uses

Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.

Synthesis

The synthesis of Bis(triphenylphosphine)palladium(II) chloride can be achieved by the reaction of palladium(II) chloride with triphenylphosphine, resulting in the formation of Bis(triphenylphosphine)palladium(II) chloride. This chemical process is represented by the balanced equation: PdCl2 + 2 PPh3 → PdCl2(PPh3)2.

Reactions

Precatalyst for the carbonylative cyclization of malonate derivatives.
Catalyst used in the double allylation of activated olefins.
Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans.
Precatalyst for the homocoupling of terminal alkynes.
Precatalyst in the cross-coupling of alkynylsilanols and aryl halides.
Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles.
Catalyst for a tandem Heck reaction/C-H functionalization.
Catalyst for direct arylation of tautomerizable heterocycles.

General Description

Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.

Flammability and Explosibility

Non flammable

Bis(triphenylphosphine)palladium(II) chloride Preparation Products And Raw materials

Raw materials

Acetonitrile Ethanol Toluene Hydrazine hydrate Palladium chloride Ethyl acetate Triphenylphosphine

Preparation Products

5-(2-PHENYLETH-1-YNYL)THIOPHENE-2-CARBALDEHYDE 4-ETHYNYLANILINE 4-Azaindole 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE 2-CHLORO-7H-PYRROLO[2,3-D]PYRIMIDINE

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Bis(triphenylphosphine)palladium(II) chloride Suppliers

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View Lastest Price from Bis(triphenylphosphine)palladium(II) chloride manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: Bis(triphenylphosphine)palladium(II) chloride 13965-03-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG /month
Release date: 2021-11-05

Hebei Weibang Biotechnology Co., Ltd

Product: Bis(triphenylphosphine)palladium(II) chloride 13965-03-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-28

Hebei Yanxi Chemical Co., Ltd.

Product: Bis(triphenylphosphine)palladium(II) chloride 13965-03-2
Price: US $60.00-20.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 30 tons
Release date: 2023-09-25

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