ChemicalBook > CAS DataBase List > 3-(4-METHYLBENZYLIDENE)CAMPHOR

3-(4-METHYLBENZYLIDENE)CAMPHOR

Product Name
3-(4-METHYLBENZYLIDENE)CAMPHOR
CAS No.
36861-47-9
Chemical Name
3-(4-METHYLBENZYLIDENE)CAMPHOR
Synonyms
4-METHYLBENZYLIDENE CAMPHOR;Enzacamene;PARSOL 5000;3-(4-METHYLBENZYLIDINE)CAMPHOR;MBC 95;UV 4MBC;MEXORYLSD;NEO-HELIOPAN;Zinc01481820;EUSOLEX 6300
CBNumber
CB9366893
Molecular Formula
C18H22O
Formula Weight
254.37
MOL File
36861-47-9.mol
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3-(4-METHYLBENZYLIDENE)CAMPHOR Property

Melting point:
66-68°C
Boiling point:
198-200 °C
Density 
1.064±0.06 g/cm3(Predicted)
RTECS 
DT5099565
storage temp. 
Inert atmosphere,Room Temperature
solubility 
insoluble in H2O; ≥10 mg/mL in DMSO; ≥111.2 mg/mL in EtOH
BRN 
9213949
LogP
3.385 (est)
CAS DataBase Reference
36861-47-9(CAS DataBase Reference)
EPA Substance Registry System
Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-[(4-methylphenyl)methylene]- (36861-47-9)
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Safety

Hazard Codes 
Xn
Risk Statements 
63
Safety Statements 
22-24/25-36/37
WGK Germany 
2
TSCA 
Yes
HS Code 
2914399000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
PHR2805
Product name
Methyl Benzylidene Camphor
Purity
Pharmaceutical Secondary Standard; Certified Reference Material
Packaging
400MG
Price
$182
Updated
2024/03/01
Sigma-Aldrich
Product number
61547
Product name
3-(4-Methylbenzylidene)camphor
Purity
certified reference material, TraceCERT
Packaging
50mg
Price
$116
Updated
2024/03/01
Sigma-Aldrich
Product number
1424222
Product name
Methyl benzylidene camphor
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
200mg
Price
$436
Updated
2024/03/01
Cayman Chemical
Product number
13840
Product name
4-Methylbenzylidene camphor
Purity
≥98%
Packaging
1g
Price
$120
Updated
2024/03/01
Cayman Chemical
Product number
13840
Product name
4-Methylbenzylidene camphor
Purity
≥98%
Packaging
5g
Price
$537
Updated
2024/03/01
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3-(4-METHYLBENZYLIDENE)CAMPHOR Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

3-(4-Methylbenzyliden)camphor is an UV-B absorbing agent in sunscreen cosmetics of the type creams, lotions, lipsticks, sun oils, etc.

Uses

3-(4-Methylbenzylidene)camphor is an organic camphor derivative that is used in the cosmetic industry for its ability to protect the skin against UV, specifically UV B radiation. 4-Methylbenzylidene camphor(4-MBC) a UV-B ray filter, is an endocrine disruptors (ED).

Uses

4-(Methylbenzylidene)camphor (4-MBC), a UV-B ray filter, is an endocrine disruptors (ED).

Biological Activity

4-methylbenzylidene camphor (4-mbc) is an ultraviolet light blocker used in cosmetics and sunscreen preparations that also has estrogenic activities.since the estrogen receptor (er) ligand type can influence transactivation, it is important to obtain information on molecular actions of nonclassical er agonists.

in vitro

previous results of competitive binding assays using cytosolic protein preparations from xenopus hepatocytes demonstrated that 4-mbc could weakly bind to the er. in addition, 4-mbc at a 100 micromol/l was not able to replace estradiol from the receptor completely [1].

in vivo

the estrogen target gene expression in uterus of long evans rats after exposure to 4-mbc was studied. results showed that 4-mbc could altere steady-state levels of mrnas encoding for er, progesterone receptor (pr), and androgen recepto in uterus of 12-wk-old offspring. to evaluate sensitivity to estradiol (e2), offspring were injected with e2, and killed 6 h later. acute up-regulation of pr and igf-i and down-regulation of er and androgen receptor by e2 were reduced in 4-mbc treated rats dose-dependently [2].

References

[1] klann a, levy g, lutz i, müller c, kloas w, hildebrandt jp. estrogen-like effects of ultraviolet screen 3-(4-methylbenzylidene)-camphor (eusolex 6300) on cell proliferation and gene induction in mammalian and amphibian cells. environ res. 2005 mar;97(3):274-81.
[2] s. durrer, k. maerkel, m. schlumpf, et al. estrogen target gene regulation and coactivator expression in rat uterus after developmental exposure to the ultraviolet filter 4-methylbenzylidene camphor. endocrinology 146(5), 2130-2139 (2005).
[3] n. r. janjua, b. mogensen, a. m. andersson, et al. systemic absorption of the sunscreens benzophenone-3, octyl-methoxycinnamate, and 3-(4-methyl-benzylidene) camphor after whole-body topical application and reproductive hormone levels in humans. journal of investigative dermatology 123, 57-61(2004).

3-(4-METHYLBENZYLIDENE)CAMPHOR Preparation Products And Raw materials

Raw materials

Preparation Products

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3-(4-METHYLBENZYLIDENE)CAMPHOR Suppliers

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View Lastest Price from 3-(4-METHYLBENZYLIDENE)CAMPHOR manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
3-(4-METHYLBENZYLIDENE)CAMPHOR 36861-47-9
Price
US $10.00/kg
Min. Order
1kg
Purity
99.8%
Supply Ability
10000ton
Release date
2024-04-23
Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
3-(4-METHYLBENZYLIDENE)CAMPHOR 36861-47-9
Price
US $2.00/kg
Min. Order
1kg
Purity
99.8%
Supply Ability
10000ton
Release date
2024-04-17
WUHAN FORTUNA CHEMICAL CO., LTD
Product
3-(4'-Methylbenzylidene)camphor 36861-47-9
Price
US $0.00-0.00/Kg/Drum
Min. Order
1KG
Purity
99%min
Supply Ability
500kg
Release date
2021-11-05

36861-47-9, 3-(4-METHYLBENZYLIDENE)CAMPHORRelated Search:

Trimethyl borate Heptane Dibenzylideneacetone Sodium 1-heptanesulfonate p-Toluic acid Benzyl bromide BENZYL GLYCIDYL ETHER N,N-Dimethylbenzylamine Camphor Benzyltriethylammonium chloride Benzyl chloride Benzyltrimethylammonium chloride Chalcone Toluene 2-BENZYLIDENECYCLOHEXANONE alpha-Hexylcinnamaldehyde [(3E)-3-[[4-[(Z)-[7,7-dimethyl-3-oxo-4-(sulfomethyl)norbornan-2-yliden e]methyl]phenyl]methylidene]-7,7-dimethyl-2-oxo-norbornan-1-yl]methane sulfonic acid Phenylacetone

  • 4''-METHYLBENZYLIDENE CAMPHOR(MBC 95)
  • NEO-HELIOPAN
  • METHYLBENZYLIDENECAMPHOR
  • MEXORYLSD
  • 3-(4-METHYLBENZYLIDINE)CAMPHOR
  • (+-)-1,7,7-Trimethyl-3-[(4-methylphenyl)methylen]bicyclo[2.2.1]heptan-2-on
  • (1S,2Z,4R)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]-3-bicyclo[2.2.1]heptanone
  • (2Z)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one
  • 3-(4-Methylbenzylidene)-camphor, 99+%
  • Bicyclo2.2.1heptan-2-one, 1,7,7-trimethyl-3-(4-methylphenyl)methylene-
  • MBC 95
  • 4-Methylbenzylidencamphor
  • (Z)-1,7,7-triMethyl-3-(4-Methylbenzylidene)bicyclo[2.2.1]heptan-2-one
  • 1,7,7-Trimethyl-3-(4-methylbenzylidene)-norbornan-2-one
  • 1,7,7-trimethyl-3-[(4-methylphenyl)methylene]-Bicyclo[2.2.1]heptan-2-one
  • 4-METHYLBENZYLIDENE CAMPHOR
  • Contralum 6300
  • Zinc01481820
  • Methyl Benzylidene Camphor (200 mg)
  • 3-(4-METHYLBENZYLIDEN)CAMPHOR
  • 3-(4'-METHYL)BENZYLIDENE-BORNAN-2-ONE
  • 3-(4-METHYLZYLIDENE)-BRONAN-2-ONE
  • 3-(4-METHYLZYLIDENE)CAMPHOR
  • (3e)-1,7,7-trimethyl-3-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-2-one
  • EUSOLEX(R) 6300
  • EUSOLEX 6300
  • NEO HELIOPAN MBC
  • PARSOL 5000
  • 4-Methyl-benzylidene camphor (4-MBC) @100 μg/mL in MeOH
  • Enzacamene
  • 3-(4-Methylbenzylidene)camphor Solution in Methanol/THF/Water, 100μg/mL
  • JADEWIN 4-MBC
  • 36861-47-9 3-(4'-Methylbenzylidene)camphor
  • The chemical name is 3-(4-methylbenzene) -camphor
  • UV 4MBC
  • UV ABSORBER TRUELICHT UV 5000
  • 1,7,7-Trimethyl-3-(4-methylbenzylidene)bicyclo[2.2.1]heptan-2-one
  • Azilsartan Impurity 86
  • 36861-47-9
  • 36861-47-1
  • 861-47-9
  • Aromatics
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • cosmetic raw material
  • UV-Absorber