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2,4-Dichlorobenzyl chloride

Product Name
2,4-Dichlorobenzyl chloride
CAS No.
94-99-5
Chemical Name
2,4-Dichlorobenzyl chloride
Synonyms
2,4-Dichloro-1-(chloromethyl)benzene;2,4-DCBC;NSC 406892;AKOS BBS-00004051;2,4-dichlorobenzyl;2,4-Dichlorobenzyl c;Oxiconazole USP RC E;-2,4-Trichlorotoluene;A 2,4-TRICHLOROTOLUENE;α,2,4-trichlorotoluene
CBNumber
CB9379105
Molecular Formula
C7H5Cl3
Formula Weight
195.47
MOL File
94-99-5.mol
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2,4-Dichlorobenzyl chloride Property

Melting point:
-2.6 °C (lit.)
Boiling point:
248 °C (lit.)
Density 
1.407 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.576(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Oily Liquid
color 
Clear colorless to very light yellow
BRN 
387220
InChI
InChI=1S/C7H5Cl3/c8-4-5-1-2-6(9)3-7(5)10/h1-3H,4H2
InChIKey
IRSVDHPYXFLLDS-UHFFFAOYSA-N
SMILES
C1(CCl)=CC=C(Cl)C=C1Cl
LogP
4.08
CAS DataBase Reference
94-99-5(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 2,4-dichloro-1-(chloromethyl)-(94-99-5)
EPA Substance Registry System
Benzene, 2,4-dichloro-1-(chloromethyl)- (94-99-5)
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Safety

Hazard Codes 
C,N
Risk Statements 
34-37-50/53-22
Safety Statements 
26-36/37/39-45-61-60
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
F 
19
Hazard Note 
Corrosive
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29036990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
139254
Product name
2,4-Dichlorobenzyl chloride
Purity
99%
Packaging
100ml
Price
$333
Updated
2025/07/31
TCI Chemical
Product number
T0400
Product name
2,4-Dichlorobenzyl Chloride
Packaging
25G
Price
$21
Updated
2025/07/31
TCI Chemical
Product number
T0400
Product name
2,4-Dichlorobenzyl Chloride
Packaging
500G
Price
$128
Updated
2025/07/31
TRC
Product number
D432320
Product name
2,4-Dichlorobenzyl chloride
Packaging
1g
Price
$55
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD21662
Product name
2,4-Dichlorobenzyl chloride
Packaging
50g
Price
$65
Updated
2021/12/16
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2,4-Dichlorobenzyl chloride Chemical Properties,Usage,Production

Chemical Properties

clear colorless to very light yellow oily liquid

Uses

2,4-Dichlorobenzyl chloride was used as starting reagent for the synthesis of series of novel 1,2,4-triazolium derivatives.

Uses

2,4-Dichlorobenzyl chloride is a reagent used in the addition of dichlorobenzene.

Synthesis

1777-82-8

94-99-5

GENERAL STEPS: 2,4-dichlorobenzyl alcohol (17.7 g, 0.1 mol), dichloromethane (30 mL), and N,N-dimethylformamide (DMF, 1 mL) were added to a 100 mL round-bottomed flask, followed by the slow dropwise addition of phosphorus trichloride (4.68 g, 0.034 mol). The reaction mixture was heated to reflux temperature (60-80°C) and the reaction lasted for 2-3 hours. The progress of the reaction was monitored by thin layer chromatography (TLC) until the complete disappearance of the raw material. After completion of the reaction, 2,4-dichlorobenzyl chloride (17.99 g, 92% yield) was purified by distillation.

References

[1] Patent: CN106117028, 2016, A. Location in patent: Paragraph 0053; 0054; 0055; 0056

2,4-Dichlorobenzyl chloride Preparation Products And Raw materials

Raw materials

ALPHA,ALPHA,2,4-TETRACHLOROTOLUENE 2,2'-Azobis(2-methylpropionitrile) 2,4-Dichlorotoluene Chlorine

Preparation Products

ALPHA,ALPHA,2,4-TETRACHLOROTOLUENE 2,4-Dichlorobenzaldehyde
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2,4-Dichlorobenzyl chloride Suppliers

Belgium 1 Canada 3 China 352 Europe 2 France 1 Germany 7 India 16 Japan 5 Slovakia 1 Switzerland 2 The Netherlands 1 Ukraine 2 United Kingdom 11 United States 43 Global 447
UkrOrgSynthesis Ltd.
Tel
--
Fax
--
Email
y.barysheva@ukrorgsynth.com
Country
Ukraine
ProdList
6230
Advantage
38
CAS Organic Company
Tel
--
Fax
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Email
Sales@casorganic.com
Country
Ukraine
ProdList
5026
Advantage
34
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View Lastest Price from 2,4-Dichlorobenzyl chloride manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2,4-Dichlorobenzyl chloride 94-99-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-28
Shaanxi Dideu Medichem Co. Ltd
Product
2,4-Dichlorobenzyl chloride 94-99-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-08-14
Henan Fengda Chemical Co., Ltd
Product
2,4-Dichlorobenzyl chloride 94-99-5
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-15

94-99-5, 2,4-Dichlorobenzyl chlorideRelated Search:

Choline chloride 2-Chloro-5-chloromethylpyridine Ammonium chloride Diethylstilbestrol Benzyl chloride Calcium chloride 4,4'-Bis(chloromethyl)-1,1'-biphenyl Polyvinyl chloride Mepiquat chloride alpha,alpha'-Dichloro-p-xylene 4-Chlorobenzyl chloride Benzyl chloroformate 2,4-Dichlorobenzyl alcohol Sodium chloride BENZAL CHLORIDE 2,4,6-Trichlorobenzoyl chloride Methylene Chloride 2,3-DICHLOROBENZYL CHLORIDE,2,3-DICHLOROBENZYL CHLORIDE 99%

  • 2,4-dichloro-1-(chloromethyl)-benzen
  • 2,4-Dichloro-1-(chloromethyl)benzene
  • 2,4-dichloro-1-chloromethyl-benzene
  • -2,4-Trichlorotoluene
  • benzene,2,4-dichloro-1-(chloromethyl)-
  • Toluene, alpha2,4-trichloro-
  • toluene,α,2,4-trichloro-
  • α,2,4-trichlorotoluene
  • ALPHA,2,4-TRICHLOROTOLUENE
  • AKOS BBS-00004051
  • A 2,4-TRICHLOROTOLUENE
  • 2,4-DICHLOROBENZYL CHLORIDE
  • 2,4-DCBC
  • DICHLOROBENZYL-2,4 CHLORIDE
  • 2,4-dichlorobenzylchlorid
  • à,2,4-trichlorotoluene
  • 2,4,ALPHA-TRICHLOROTOLUENE
  • 2,4-Dichlorbenzylchlorid
  • 2,4-Dichlorobenzoylchloride
  • 7) 2,4-DI CHLORO BENZYL CHLORIDE
  • 2,4-Dichlorobenzyl c
  • 4-Dichlorobenzyl chloride
  • 2,4-Dichlorobenzyl chloride,99%
  • 2,4-Dichlorobenzyl chloride, 99% 100ML
  • 1-ChloroMethyl-2,4-dichlorobenzene
  • NSC 406892
  • 1-(Chloromethyl)-2,4-dichlorobenzene, alpha,2,4-Trichlorotoluene
  • 2,4-Dichlorobenzyl chloride, 98%+
  • 2,4-Dichlorobenzyl Chloride &gt
  • 2,4-dichlorobenzyl
  • Miconazole Impurity 4 (2,4-DichlorobenzylChloride)
  • Oxiconazole USP RC E
  • TIANFU-CHEM 2,4-Dichlorobenzyl chloride
  • 2,4‐DICHLOROBENZYL CHLORIDE Extra Pure
  • 2,4-Dichlorobenzyl chloride 100 μg/ml Methanol
  • Miconazole impurity 10 (2, 4-dichlorochlorobenzyl)
  • 94-99-5
  • 1855-11-0
  • Organic Building Blocks
  • Halogenated Hydrocarbons
  • Building Blocks
  • Aryl
  • C7
  • BENZYL HALIDE
  • Aromatics
  • Miscellaneous Reagents
  • Econazole Nitrate
  • Aromatic Halides (substituted)