ChemicalBook > CAS DataBase List > 3,4-Diaminobenzonitrile

3,4-Diaminobenzonitrile

Product Name
3,4-Diaminobenzonitrile
CAS No.
17626-40-3
Chemical Name
3,4-Diaminobenzonitrile
Synonyms
BUTTPARK 43\57-88;2-AMino-4-cyanoaniline;3,4-DIAMINOBENZONITRILE;Benzonitrile,3,4-diaMino-;4-Cyanobenzene-1,2-diamine;1,2-DiaMino-4-cyanobenzene;4-Cyano-o-phenylenediaMine;4-Cyano-1,2-phenylenediaMine;3,4-DIAMINOBENZONITRILE 95+%;4-Cyanobenzene-1,2-diamine, 4-Cyanophenylene-1,2-diamine
CBNumber
CB9413669
Molecular Formula
C7H7N3
Formula Weight
133.15
MOL File
17626-40-3.mol
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3,4-Diaminobenzonitrile Property

Melting point:
144-148 °C
Boiling point:
368.7±27.0 °C(Predicted)
Density 
1.24±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Soluble in dichloromethane, methanol and ethyl acetate.
pka
2.35±0.10(Predicted)
form 
Solid
color 
Pale brown
λmax
316nm(THF)(lit.)
Stability:
Store in freezer at -20°C
InChI
InChI=1S/C7H7N3/c8-4-5-1-2-6(9)7(10)3-5/h1-3H,9-10H2
InChIKey
VWLLPPSBBHDXHK-UHFFFAOYSA-N
SMILES
C(#N)C1=CC=C(N)C(N)=C1
CAS DataBase Reference
17626-40-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38-20/21/22
Safety Statements 
26-36-36/37
RIDADR 
3276
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
6.1
PackingGroup 
III
HS Code 
29269090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
653845
Product name
3,4-Diaminobenzonitrile
Purity
97%
Packaging
1g
Price
$57.09
Updated
2025/07/31
Sigma-Aldrich
Product number
653845
Product name
3,4-Diaminobenzonitrile
Purity
97%
Packaging
10g
Price
$305
Updated
2025/07/31
TCI Chemical
Product number
D5194
Product name
3,4-Diaminobenzonitrile
Purity
>98.0%(GC)
Packaging
1g
Price
$38
Updated
2025/07/31
TCI Chemical
Product number
D5194
Product name
3,4-Diaminobenzonitrile
Purity
>98.0%(GC)
Packaging
5g
Price
$149
Updated
2025/07/31
TRC
Product number
D416220
Product name
3,4-Diaminobenzonitrile
Packaging
100mg
Price
$50
Updated
2021/12/16
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3,4-Diaminobenzonitrile Chemical Properties,Usage,Production

Chemical Properties

White to light yellow crystal powde

Uses

A synthetic intermediate

Uses

3,4-Diaminobenzonitrile is usually used like?synthetic intermediate.

Synthesis Reference(s)

Journal of Medicinal Chemistry, 36, p. 1746, 1993 DOI: 10.1021/jm00064a008

Synthesis

6393-40-4

17626-40-3

The general procedure for the synthesis of 3,4-diaminobenzonitrile from 4-amino-3-nitrobenzonitrile was as follows: palladium/carbon catalyst (500 mg, 10% purity) was added to a stirring solution of 4-amino-3-nitrobenzonitrile (2.00 g, 12.3 mmol) in methanol (20 mL). Subsequently, the reaction flask was degassed and filled with hydrogen (using a hydrogen balloon). The reaction mixture was stirred vigorously for 18 hours at 25°C. Upon completion of the reaction, the mixture was degassed under vacuum and backfilled with nitrogen, and this process was repeated three times. Afterwards, the reaction mixture was filtered through a diatomaceous earth pad and the filtrate was concentrated under vacuum to give 3,4-diaminobenzonitrile (1.47 g, 11.04 mmol, 90% yield) as a green oil, which was used directly in the next step of the reaction.

References

[1] Australian Journal of Chemistry, 1994, vol. 47, # 9, p. 1751 - 1770
[2] Journal of Medicinal Chemistry, 1993, vol. 36, # 12, p. 1746 - 1753
[3] Journal of Medicinal Chemistry, 1996, vol. 39, # 4, p. 992 - 998
[4] Bioorganic and Medicinal Chemistry, 2002, vol. 10, # 8, p. 2589 - 2596
[5] Patent: WO2018/81167, 2018, A1. Location in patent: Page/Page column 244

3,4-Diaminobenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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3,4-Diaminobenzonitrile Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
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sales8178@energy-chemical.com
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
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0086-571-85864795
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China
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Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
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+86-10-82967029
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2355560935@qq.com
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China
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12000
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Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956
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0573-85285100
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isenchem@163.com
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China
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
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021-50795055
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sales@accelachem.com
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China
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Shanghai Longsheng chemical Co.,Ltd.
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021-58099652-8005 13585536065
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021-58099609
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bin.wu@shlschem.com
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China
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9883
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Shanghai Harvest Chemical Industrial Co., Ltd.
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021-31038972,31038973 17321035817
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+86-21-51385350
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sales@harvest-chem.com
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China
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2816
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Nanjing Chemlin Chemical Co., Ltd
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025-83697070
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+86-25-83453306
Email
info@chemlin.com.cn
Country
China
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15883
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64
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View Lastest Price from 3,4-Diaminobenzonitrile manufacturers

Career Henan Chemical Co
Product
3,4-Diaminobenzonitrile 17626-40-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

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