(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

Reaction

Product Name: (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
CAS No.: 490023-37-5
Chemical Name: (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
Synonyms: Reaxys ID: 23113812;3,4-a′]dinaphthalen-4-yl)MethylaMine;3,4-a']dinaphthalen-4-yl)methylamine;(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D;1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS);(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&;3,4-a']dinaphthalen-4-yl)methylamine 97%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,98%
CBNumber: CB9465976
Molecular Formula: C28H22NO2P
Formula Weight: 435.45
MOL File: 490023-37-5.mol

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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Property

Melting point:: 155-159 °C
alpha: +356° (c 0.32, CHCl3)
Boiling point:: 635.4±48.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
pka: 0.08±0.20(Predicted)
color: white
Sensitive: moisture sensitive

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 665355
Product name: (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine
Purity: 97%
Packaging: 100mg
Price: $26.24
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1510
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
Packaging: 100mg
Price: $68
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1510
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
Packaging: 500mg
Price: $267
Updated: 2024/03/01

Sigma-Aldrich

Product number: 665355
Product name: (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine
Purity: 97%
Packaging: 500mg
Price: $258
Updated: 2023/01/07

Matrix Scientific

Product number: 090135
Product name: N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Purity: 95+%
Packaging: 250mg
Price: $492
Updated: 2021/12/16

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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Chemical Properties,Usage,Production

Reaction

The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.

Uses

DSM MonoPhos Family of Highly Efficient Privileged Ligands

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Suppliers

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490023-37-5, (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)Related Search:

Benzophenone (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-MONOPHOS (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE

(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%

(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&

3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%

3,4-a′]dinaphthalen-4-yl)MethylaMine

Reaxys ID: 23113812

N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bS)-N-Methyl-N-(phenylmethyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

3,4-a']dinaphthalen-4-yl)methylamine 97%

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE,99%

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D

1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N-methyl-N-(phenylmethyl)-, (11bS)-

(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine

(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

3,4-a']dinaphthalen-4-yl)methylamine

3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,98%

490023-37-5

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

DSM MonoPhos Phosphoramidites

Privileged Ligands

Chiral Phosphine

CPN