ChemicalBook > CAS DataBase List > (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
Reaction- Product Name
- (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
- CAS No.
- 490023-37-5
- Chemical Name
- (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
- Synonyms
- Reaxys ID: 23113812;3,4-a′]dinaphthalen-4-yl)MethylaMine;3,4-a']dinaphthalen-4-yl)methylamine;(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D;1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS);(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&;3,4-a']dinaphthalen-4-yl)methylamine 97%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
- CBNumber
- CB9465976
- Molecular Formula
- C28H22NO2P
- Formula Weight
- 435.45
- MOL File
- 490023-37-5.mol
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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Property
- Melting point:
- 155-159 °C
- alpha
- +356° (c 0.32, CHCl3)
- Boiling point:
- 635.4±48.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- pka
- 0.08±0.20(Predicted)
- color
- white
- Sensitive
- moisture sensitive
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Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 665355
- Product name
- (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine
- Purity
- 97%
- Packaging
- 100mg
- Price
- $26.24
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1510
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
- Packaging
- 100mg
- Price
- $68
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1510
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
- Packaging
- 500mg
- Price
- $267
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 665355
- Product name
- (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine
- Purity
- 97%
- Packaging
- 500mg
- Price
- $258
- Updated
- 2023/01/07
Matrix Scientific
- Product number
- 090135
- Product name
- N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $492
- Updated
- 2021/12/16
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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Chemical Properties,Usage,Production
Reaction
- The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
- The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.
Uses
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Preparation Products And Raw materials
Raw materials
Preparation Products
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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Suppliers
490023-37-5, (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)Related Search:
Benzophenone
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(R)-MONOPHOS
(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)