Reaction
ChemicalBook > CAS DataBase List > (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

Reaction
Product Name
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
CAS No.
490023-37-5
Chemical Name
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
Synonyms
Reaxys ID: 23113812;3,4-a′]dinaphthalen-4-yl)MethylaMine;3,4-a']dinaphthalen-4-yl)methylamine;(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D;1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS);(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&;3,4-a']dinaphthalen-4-yl)methylamine 97%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,98%
CBNumber
CB9465976
Molecular Formula
C28H22NO2P
Formula Weight
435.45
MOL File
490023-37-5.mol
More
Less

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Property

Melting point:
155-159 °C
alpha 
+356° (c 0.32, CHCl3)
Boiling point:
635.4±48.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
pka
0.08±0.20(Predicted)
color 
white
Sensitive 
moisture sensitive
More
Less

Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
665355
Product name
(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine
Purity
97%
Packaging
100mg
Price
$26.24
Updated
2024/03/01
Strem Chemicals
Product number
15-1510
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
Packaging
100mg
Price
$68
Updated
2024/03/01
Strem Chemicals
Product number
15-1510
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
Packaging
500mg
Price
$267
Updated
2024/03/01
Sigma-Aldrich
Product number
665355
Product name
(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine
Purity
97%
Packaging
500mg
Price
$258
Updated
2023/01/07
Activate Scientific
Product number
AS146760
Product name
(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Purity
98%
Packaging
1g
Price
$455
Updated
2021/12/16
More
Less

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Chemical Properties,Usage,Production

Reaction

  1. The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
  2. The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.

Uses

DSM MonoPhos Family of Highly Efficient Privileged Ligands

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Suppliers

A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58

490023-37-5, (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)Related Search:


  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE
  • (S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE
  • (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
  • 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
  • (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a
  • (S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&
  • 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%
  • 3,4-a′]dinaphthalen-4-yl)MethylaMine
  • Reaxys ID: 23113812
  • N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bS)-N-Methyl-N-(phenylmethyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 3,4-a']dinaphthalen-4-yl)methylamine 97%
  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE,99%
  • (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D
  • 1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N-methyl-N-(phenylmethyl)-, (11bS)-
  • (11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
  • (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
  • 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine
  • (11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 3,4-a']dinaphthalen-4-yl)methylamine
  • 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,98%
  • 490023-37-5
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • DSM MonoPhos Phosphoramidites
  • Privileged Ligands
  • Chiral Phosphine
  • CPN