2-Chlorobenzaldehyde
- Product Name
- 2-Chlorobenzaldehyde
- CAS No.
- 89-98-5
- Chemical Name
- 2-Chlorobenzaldehyde
- Synonyms
- ORTHO CHLORO BENZALDEHYDE;OCBA;O-CHLOROBENZALDEHYDE;OCAD;2-Clorobenzaldeide;usafm-7;USAF m-7;NSC 15347;AKOS BBS-00003191;2-Chlorbenzaldehyd
- CBNumber
- CB9469909
- Molecular Formula
- C7H5ClO
- Formula Weight
- 140.57
- MOL File
- 89-98-5.mol
2-Chlorobenzaldehyde Property
- Melting point:
- 9-11 °C (lit.)
- Boiling point:
- 209-215 °C (lit.)
- Density
- 1.248 g/mL at 25 °C (lit.)
- vapor density
- 4.84 (vs air)
- vapor pressure
- 1.27 mm Hg ( 50 °C)
- refractive index
- n20/D 1.566(lit.)
- Flash point:
- 190 °F
- storage temp.
- Store in RT
- solubility
- 1.8g/l
- form
- Liquid
- color
- Clear colorless to light yellow
- PH
- 2.9 (H2O)(saturated aqueous solution)
- Water Solubility
- 0.1-0.5 g/100 mL at 24 ºC
- Sensitive
- Air Sensitive
- BRN
- 385877
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents, strong bases, iron, strong reducing agents. Moisture and light-sensitive.
- LogP
- 2.44 at 25℃
- CAS DataBase Reference
- 89-98-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzaldehyde, 2-chloro-(89-98-5)
- EPA Substance Registry System
- 2-Chlorobenzaldehyde (89-98-5)
Safety
- Hazard Codes
- C,Xi
- Risk Statements
- 34
- Safety Statements
- 26-45
- RIDADR
- UN 3265 8/PG 3
- WGK Germany
- 1
- RTECS
- CU5075000
- F
- 8-9-23
- Autoignition Temperature
- 746 °F
- Hazard Note
- Irritant
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29130000
- Hazardous Substances Data
- 89-98-5(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: 2160 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 8.20276
- Product name
- 2-Chlorobenzaldehyde
- Purity
- for synthesis
- Packaging
- 250ML
- Price
- $42.5
- Updated
- 2024/03/01
- Product number
- 8.20276
- Product name
- 2-Chlorobenzaldehyde
- Purity
- for synthesis
- Packaging
- 1L
- Price
- $116
- Updated
- 2024/03/01
- Product number
- 124974
- Product name
- 2-Chlorobenzaldehyde
- Purity
- 99%
- Packaging
- 100g
- Price
- $65.6
- Updated
- 2024/03/01
- Product number
- 124974
- Product name
- 2-Chlorobenzaldehyde
- Purity
- 99%
- Packaging
- 500g
- Price
- $73.9
- Updated
- 2024/03/01
- Product number
- C0561
- Product name
- 2-Chlorobenzaldehyde
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $16
- Updated
- 2024/03/01
2-Chlorobenzaldehyde Chemical Properties,Usage,Production
Chemical Properties
2-Chlorobenzaldehyde is a colorless to yellowish liquid with a penetrating odor. Insoluble in water, soluble in benzene, alcohol and ether. 2-Chlorobenzaldehyde is considerably more resistant to oxidation than benzaldehyde. When it is heated with sodium sulfite solution under pressure, benzaldehyde-2-sulfonic acid forms.
Uses
2-Chlorobenzaldehyde has been used in generation of small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and thioureas.
Uses
2-Chlorobenzaldehyde can be used to make alcohols, acids, and dyes; used in the rubber, tanning, and paper industries; used as an intermediate for optical brighteners, agricultural chemicals, and pharmaceuticals.It can also be used to prepare triphenyl methane and related dyes, organic intermediate.
Preparation
2-Chlorobenzaldehyde is produced mainly by chlorination of 2-chlorotoluene to form 2-chlorobenzal chloride, which is then subjected to acid hydrolysis. Metal salts, such as iron(III) chloride, are used as catalysts. The hydrolysis can also be accomplished using formic acid without a catalyst.
2-Chlorobenzaldehyde can also be produced by oxidation of 2-chlorobenzyl chloride with N-oxides of tertiary amines or with dilute nitric acid.
https://pubchem.ncbi.nlm.nih.gov/compound/2-Chlorobenzaldehyde
Application
2-Chlorobenzaldehyde is used acid zinc plating brightener, also be used for organic synthesis, agricultural pesticide and pharmaceutical industries. It is used to synthesize the acaricides clofentezine and flutenzine. 2-Chlorobenzaldehyde undergoes alkynylation with phenylacetylene in the presence of catalytic ligands and dimethylzinc at 0°C to form binaphthyl-derived amino alcohols.
Synthesis Reference(s)
Tetrahedron Letters, 34, p. 8037, 1993 DOI: 10.1016/S0040-4039(00)61444-2
General Description
2-chlorobenzaldehyde is a clear colorless to yellowish liquid. (NTP, 1992)
Air & Water Reactions
2-Chlorobenzaldehyde is moisture and light sensitive. Slightly water soluble.
Reactivity Profile
2-Chlorobenzaldehyde reacts with iron and strong oxidizers, strong bases and strong reducing agents.
Health Hazard
Symptoms of exposure to 2-Chlorobenzaldehyde may include skin, eye and upper respiratory tract irritation. This compound may cause skin, eye and respiratory tract irritation. When heated to decomposition it emits toxic fumes.
Fire Hazard
2-Chlorobenzaldehyde is combustible.
Safety Profile
Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of Cl-. See also ALDEHYDES and CHLORIDES.
Purification Methods
Wash it with 10% Na2CO3 solution, then fractionally distil it in the presence of a small amount of catechol as stabiliser. [Beilstein 7 H 233, 7 IV 561.]
2-Chlorobenzaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Chlorobenzaldehyde manufacturers
- Product
- 2-Chlorobenzaldehyde 89-98-5
- Price
- US $79.00-65.00/kilograms
- Min. Order
- 1kilograms
- Purity
- 99%
- Supply Ability
- 100tons
- Release date
- 2023-02-17
- Product
- 2-Chlorobenzaldehyde 89-98-5
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2024-03-26
- Product
- 2-Chlorobenzaldehyde 89-98-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500mt/year
- Release date
- 2021-11-08