Tri-tert-butylphosphine

Reaction

Product Name: Tri-tert-butylphosphine
CAS No.: 13716-12-6
Chemical Name: Tri-tert-butylphosphine
Synonyms: P(t-Bu)3;TTBP;TRI-T-BUTYLPHOSPHINE;Tri-tert-butyL;Tris(tert-butyl)phosphine;Butylphosphine;Uncle Ding Jilin;ri-tert-butylphosphine;Tri-t-butylphosphosphin;TRI-TERT-BUTYLPHOSPHINE
CBNumber: CB9483150
Molecular Formula: C12H27P
Formula Weight: 202.32
MOL File: 13716-12-6.mol

More

Less

Tri-tert-butylphosphine Property

Melting point:: 30-35 °C(lit.)
Boiling point:: 102-103 °C13 mm Hg(lit.)
Density: 0.861 g/mL at 25 °C
Flash point:: 1 °F
storage temp.: Flammables area
form: solid
Specific Gravity: 0.68
Water Solubility: insoluble
Sensitive: Air & Moisture Sensitive
Hydrolytic Sensitivity: 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
BRN: 1738613
InChIKey: BWHDROKFUHTORW-UHFFFAOYSA-N
CAS DataBase Reference: 13716-12-6(CAS DataBase Reference)
NIST Chemistry Reference: Tri-tert-butylphosphine(13716-12-6)

More

Less

Safety

Hazard Codes: F,C
Risk Statements: 17-34-67-65-63-48/20-11
Safety Statements: 26-45-62-36/37/39-25-43-27-16
RIDADR: UN 2846 4.2/PG 1
WGK Germany: 3
F: 10-19-23
HazardClass: 4.2
PackingGroup: I
HS Code: 29319090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H250Catches fire spontaneously if exposed to air

H314Causes severe skin burns and eye damage

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 901438
Product name: Tri-tert-butylphosphine solution
Purity: 1.0?M in THF
Packaging: 25mL
Price: $264
Updated: 2024/03/01

Sigma-Aldrich

Product number: 570958
Product name: Tri-tert-butylphosphine
Purity: 98%
Packaging: 1g
Price: $91.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 570958
Product name: Tri-tert-butylphosphine
Purity: 98%
Packaging: 5g
Price: $232
Updated: 2024/03/01

Alfa Aesar

Product number: 010178
Product name: Tri-tert-butylphosphine
Purity: 98%
Packaging: 1g
Price: $121.65
Updated: 2024/03/01

Alfa Aesar

Product number: 010178
Product name: Tri-tert-butylphosphine
Purity: 98%
Packaging: 5g
Price: $380
Updated: 2024/03/01

More

Less

Tri-tert-butylphosphine Chemical Properties,Usage,Production

Reaction

Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions.

Chemical Properties

Colorless to light yellow liqui

Uses

Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Uses

Valuable ligand for several coupling reactions. This product is offered as the THF solution for more convenient handling.

Tri-tert-butylphosphine Preparation Products And Raw materials

Raw materials

Hexane tert-Butyllithium 2-Chloro-2-methylpropane Lithium bromide Phosphorus trichloride Tetrahydrofuran Diethyl ether Ethyl acetate Copper(I) chloride Dichloromethane Magnesium

Preparation Products

1-(4-Pyridyl)piperazine

More

Less

Tri-tert-butylphosphine Suppliers

Belgium 3 China 289 China Hong Kong 1 Germany 6 India 10 Japan 7 Norway 1 Russia 1 South Korea 3 Switzerland 3 Ukraine 1 United Kingdom 13 United States 32 Global 370

Sungwoo Biopharm Corp. ( Sungwoo Interchem Corp.)

Tel: --
Fax: --
Email: swbp@sungwookr.com
Country: South Korea
ProdList: 35
Advantage: 58

SHINWON CHEMTRADE CO., LTD

Tel: --
Fax: --
Email: info@shinwonchem.com
Country: South Korea
ProdList: 231
Advantage: 43

CHEMICAL LAND21

Tel: --
Fax: --
Email: sales21@chemicalland21.com
Country: South Korea
ProdList: 6303
Advantage: 74

More

Less

View Lastest Price from Tri-tert-butylphosphine manufacturers

Shanghai UCHEM Inc.

Product: Tri-tert-butylphosphine 13716-12-6
Price: US $589.00/g
Min. Order: 1g
Purity: 0.99
Supply Ability: 1kg
Release date: 2023-10-20

Shaanxi Dideu Medichem Co. Ltd

Product: Tri-tert-butylphosphine 13716-12-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 20T
Release date: 2024-05-26

Weijer International Trade (Hebei) Co., Ltd

Product: Tri-tert-butylphosphine 13716-12-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: >99%
Supply Ability: 2000T
Release date: 2023-03-20

13716-12-6, Tri-tert-butylphosphineRelated Search:

BIS-Tris tert-Butanol Tetrabutylammonium bromide BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) tert-Butyl peroxyacetate Tricine Tris(hydroxymethyl)aminomethane 1,3,5-Tri-tert-butylbenzene Tributylphosphine tert-Butyl acetate T-BUTYLPHOSPHINE TRI-TERT-BUTYLPHOSPHONIUM TETRAPHENYLBORATE Tri-tert-butylphosphine tetrafluoroborate TRI-N-OCTYLPHOSPHINE TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD TRI-T-BUTYL 1 4 7 10-TETRAAZACYCLODODECA Triphenylene Hexafluoroacetone trihydrate

Tri-t-butylphosphine, 99% (10 wt% in hexanes) (Sure/Seal bottle)

Tri-t-butylphosphosphin

Tri-tert-butyL

Phosphine, tris(1,1-dimethylethyl)-

TRI-TERT-BUTYL-PHOSPHANE

TRI-TERT-BUTYLPHOSPHINE

TRI-T-BUTYLPHOSPHINE

tris(1,1-dimethylethyl)phosphine

TRI-TERT-BUTYLPHOSPHINE, 1M IN TOLUENE

TRI-TERT-BUTYLPHOSPHINE, TECH., 90%

TERT-BUTYLPHOSPHINE, ELEC. GR., 99.9995%

Tri-t-butylphosphine,99%

Tri-t-butylphosphine,99%(10wt%inhexane)

Tri-t-butylphosphine,99%(10wt%inhexane)(Sure/Sealbottle)

Tri-t-butylphosphine,min.98%

tri-tert-butylphosphine solution

Tri-t-butylphosphine, 99% (10% in hexanes)

Tri-t-butylphosphine, 99% (10% in methanol)

Tris(tert-butyl)phosphine, 50% solution in toluene

Tris(tert-butyl)phosphine 95%

tri-tert-butyl phosphine (50 % in toluene) ,triter phosphine

Tri-tert-butylphosphine 10wt% in xylen

Tri-t-butylphosphine, 99% (10 wt% in hexanes) (Sure/Seal(TM) bottle)

Uncle Ding Jilin

P(t-Bu)3

Tri-tert-butylphosphine solution 1.0 M in toluene

Tri-tert-butylphosphine (50% in toluene wt/wt)

Tri t butylphosphine(TTB)

TTBP

Tri-t-butylphosphine (10 wt% in hexane) (Sure/Seal bottle)

Tri-t-butylphosphine, Min. 98% (50wt% in toluene)

Butylphosphine

Tri-t-butylphosphine,98% (t-Bu)3P

Tri-t-butylphosphine, 99% (10 wt% in hexanes)

Tri-tert-butylphosphine, 10 wt.% solution in toluene, J&Kseal

Tri-tert-butylphosphine 10% in toluene

ri-tert-butylphosphine

TRI-tert-BUTYLPHOSPHINE, 20% in heptane

Tri-t-butylphosphine, 98% 10% in toluen

TRI-T-BUTYLPHOSPHINE (10% WT. IN HEXANE)

TRI-T-BUTYLPHOSPHINE (10 WT% IN HEXANE) WITH SURE/SEAL

Tris(tert-butyl)phosphine

Tri-tert-butylphosphine,99%

Tri-tert-butylphosphine,95%

Tri-tert-butylphosphine,99% ,(10 wt% in hexane)

Tri-t-butylphosphine, min. 98%

Tri-tert-butylphosphine,TTBP

Tri-tert-butylphosphine ,97%

Tri-tert-butylphosphine ,95% [10wt% in hexane]

Tri-tert-butylphosphine [10wt% in hexane]

Tri-t-butylphosphine, 99% (10 wt% in hexane) (Sure/Seal TM Bottle)

Tri-t-butylphosphine, 99% (10 wt% in toluene)

Tri-t-butylphosphine (20 wt% in toluene)

1mol/l Tri-t-butylphosphine Hexane Solution

Tri-tert-butylphosphine in Toluene 50%

Tri-t-butylphosphine TTBP

Tri-t-butylphosphosphine

Tri-Tert-Butyl Phosphine 32% in o-xylene solution