ChemicalBook > CAS DataBase List > 2-Methoxypropene

2-Methoxypropene

Product Name
2-Methoxypropene
CAS No.
116-11-0
Chemical Name
2-Methoxypropene
Synonyms
MOP;2-methoxyprop-1-ene;ISOPROPENYL METHYL ETHER;2-Methoxyproene;2-METHYOXYPROPENE;CH2=C(CH3)OCH3;CH3C(OCH3):CH2;2-methoxy-propen;2-METHOXYPROPENE;2-methoxy-1-propen
CBNumber
CB9735606
Molecular Formula
C4H8O
Formula Weight
72.11
MOL File
116-11-0.mol
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2-Methoxypropene Property

Melting point:
25°C
Boiling point:
34-36 °C (lit.)
Density 
0.753 g/mL at 25 °C (lit.)
vapor pressure 
27.96 psi ( 55 °C)
refractive index 
n20/D 1.382(lit.)
Flash point:
−21 °F
storage temp. 
2-8°C
solubility 
Chloroform
form 
Liquid
color 
Clear colorless
PH
7 (H2O)
Water Solubility 
negligible
Sensitive 
Light Sensitive
BRN 
1734635
LogP
1.7 at 21℃ and pH8.1-8.4
CAS DataBase Reference
116-11-0(CAS DataBase Reference)
NIST Chemistry Reference
1-Propene, 2-methoxy-(116-11-0)
EPA Substance Registry System
1-Propene, 2-methoxy- (116-11-0)
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Safety

Hazard Codes 
F+,Xn,F
Risk Statements 
12-19-22-11
Safety Statements 
3-16-29-33-7/9-9-18
RIDADR 
UN 1993 3/PG 1
WGK Germany 
1
RTECS 
UD0800000
F 
8-10
Autoignition Temperature
374 °F
TSCA 
Yes
HazardClass 
3
PackingGroup 
I
HS Code 
29091990
Hazardous Substances Data
116-11-0(Hazardous Substances Data)
Toxicity
rabbit,LD50,skin,> 20mL/kg (20mL/kg),American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H224Extremely flammable liquid and vapour

H302Harmful if swallowed

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
174645
Product name
2-Methoxypropene
Purity
97%
Packaging
50g
Price
$72.3
Updated
2024/03/01
Sigma-Aldrich
Product number
174645
Product name
2-Methoxypropene
Purity
97%
Packaging
250g
Price
$148
Updated
2024/03/01
TCI Chemical
Product number
I0303
Product name
2-Methoxypropene
Purity
>95.0%(GC)
Packaging
25mL
Price
$78
Updated
2024/03/01
TCI Chemical
Product number
I0303
Product name
2-Methoxypropene
Purity
>95.0%(GC)
Packaging
100mL
Price
$204
Updated
2024/03/01
Alfa Aesar
Product number
B24083
Product name
2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate
Packaging
50g
Price
$45.1
Updated
2024/03/01
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2-Methoxypropene Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

2-Methoxypropene is used in the synthesis of Macrolactin A, a 24-member macrolide typically employed as an antibiotic. Also used in the synthesis of phenylalanine derivatives used as α4β1 and α4β7 receptor antagonists in the treatment of allergic asthma.

Preparation

2-Methoxypropene is prepared in high yield from Succinic Anhydride, 2,2-Dimethoxypropane, benzoic acid, and Pyridine.

Reactivity Profile

2-Methoxypropene is an electron-rich alkene used in the monoprotection of aliphatic, allylic, and propargylic alcohols, often followed by Claisen or other rearrangements; protection of peroxides, cyanohydrins, α-hydroxy ketones, and phenols; condensation with amines; protection of 1,2- and 1,3-diols, sometimes followed by Prins rearrangements; protection of 1,2-dithiols and α-hydroxy carbamates; participant in pericyclic reactions; formation of 2-methoxyallyl halides and substituted furans.

Toxics Screening Level

The initial threshold screening level (ITSL) for 2-Methoxy-1-propene is 6 μg/m3 based on an annual averaging time.

Precautions

flammable liquid; light-sensitive; should be refrigerated.

2-Methoxypropene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methoxypropene Suppliers

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View Lastest Price from 2-Methoxypropene manufacturers

Hebei Mujin Biotechnology Co.,Ltd
Product
2-Methoxypropene 116-11-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-12
Hebei Weibang Biotechnology Co., Ltd
Product
2-Methoxypropene 116-11-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-20
Hebei Chuanghai Biotechnology Co,.LTD
Product
2-Methoxypropene 116-11-0
Price
US $10.70/kg
Min. Order
10kg
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23

116-11-0, 2-MethoxypropeneRelated Search:

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  • 2-Methoxypropene, stabilized, 97% 250ML
  • 2-Methoxypropene, 95%, stab. with ca 0.5% potassiuM carbonate
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  • TIANFUCHEM--High purity 116-11-0 2-Methoxypropene
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  • Aminocaproic acid impurity 4 (methyl oleyl phthalate)
  • 116-11-0
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