ChemicalBook > CAS DataBase List > Phenyl carbamate

Phenyl carbamate

Product Name
Phenyl carbamate
CAS No.
622-46-8
Chemical Name
Phenyl carbamate
Synonyms
PHENYL CARBAMATE;o-Phenyl carbamate;Phenylcarbamate,98+%;Phenyl carbamate,97%;Phenyl carbaMate 97%;CARBAMICACID,PHENYLESTER;Phenyl carbamate ISO 9001:2015 REACH
CBNumber
CB9777127
Molecular Formula
C7H7NO2
Formula Weight
137.14
MOL File
622-46-8.mol
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Phenyl carbamate Property

Melting point:
149-152 °C(lit.)
Boiling point:
251.96°C (rough estimate)
Density 
1.2528 (rough estimate)
refractive index 
1.5030 (estimate)
storage temp. 
Sealed in dry,Room Temperature
pka
12.33±0.50(Predicted)
Water Solubility 
Soluble in water.
BRN 
2042627
CAS DataBase Reference
622-46-8(CAS DataBase Reference)
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29242998
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
P21404
Product name
Phenyl carbamate
Purity
97%
Packaging
5g
Price
$64.7
Updated
2024/03/01
Sigma-Aldrich
Product number
P21404
Product name
Phenyl carbamate
Purity
97%
Packaging
25g
Price
$287
Updated
2024/03/01
Alfa Aesar
Product number
L00944
Product name
Phenyl carbamate, 98+%
Packaging
5g
Price
$37.65
Updated
2024/03/01
Alfa Aesar
Product number
L00944
Product name
Phenyl carbamate, 98+%
Packaging
25g
Price
$99.65
Updated
2024/03/01
AK Scientific
Product number
7861AF
Product name
Phenyl carbamate
Packaging
1g
Price
$64
Updated
2021/12/16
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Phenyl carbamate Chemical Properties,Usage,Production

Chemical Properties

white to very slightly pink crystalline flakes

Uses

Phenyl Carbamate is a robust, inert to Pd-catalysis reagent which are useful for arene functionalization/site-selective cross-coupling reactions.

Uses

Phenyl carbamate is used as various phenyl carbamate esters derived from amino acids, a dipeptide and amino acid esters and amides were prepared and assessed as potential prodrugs with the aim of protecting phenolic drugs against first-pass metabolism following per oral administration.

A tin-catalyzed transcarbamoylation of primary and secondary alcohols with phenyl carbamate proceeds smoothly in toluene at 90℃ to generate the corresponding carbamates in good yields. This mild method exhibits a broad functional-group tolerance.
Y. Ichikawa, Y. Morishita, S. Kusaba, N. Sakiyama, Y. Matsuda, K. Nakano, H. Kotsuki, Synlett, 2010, 1815-1818.
http://dx.doi.org/10.1055/s-0030-1258102

Definition

ChEBI: Phenyl carbamate is an aromatic ether.

Phenyl carbamate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Phenyl carbamate manufacturers

Hong Kong Tiansheng New Material Trading Co., Ltd
Product
phenyl carbamate 622-46-8
Price
US $100.00/Kg/Bag
Min. Order
1Kg/Bag
Purity
99%
Supply Ability
10KG
Release date
2021-09-14
Hong Kong Tiansheng New Material Trading Co., Ltd
Product
Phenyl carbamate 622-46-8
Price
US $100.00/Kg/Bag
Min. Order
1KG
Purity
99%
Supply Ability
10kg
Release date
2021-09-15
Hong Kong Tiansheng New Material Trading Co., Ltd
Product
Phenyl carbamate 622-46-8
Price
US $100.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2021-09-16