6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID

Product Name: 6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID
CAS No.: 1197-10-0
Chemical Name: 6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID
Synonyms: 6-(Hydroxymethyl)picolinicaci;6-(hydroxymethyl)picolinic acid;6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID;2-Pyridinecarboxylic acid, 6-(hydroxymethyl)-;6-(Hydroxymethyl)pyridine-2-carboxylic acid 95+%;2-Carboxy-6-(hydroxymethyl)pyridine, 6-(Hydroxymethyl)picolinic acid
CBNumber: CB9838277
Molecular Formula: C7H7NO3
Formula Weight: 153.14
MOL File: 1197-10-0.mol

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6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID Property

Melting point:: 137 °C
Boiling point:: 381.2±32.0 °C(Predicted)
Density: 1.404±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 0.96±0.50(Predicted)
Appearance: White to off-white Solid

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Safety

HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: H419710
Product name: 6-(Hydroxymethyl)picolinicAcid
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: H419710
Product name: 6-(Hydroxymethyl)picolinicAcid
Packaging: 100mg
Price: $90
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H29-1-X0
Product name: 6-(Hydroxymethyl)pyridine-2-carboxylic acid
Packaging: 250mg
Price: $145
Updated: 2021/12/16

AK Scientific

Product number: X9395
Product name: 6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLICACID
Packaging: 1g
Price: $192
Updated: 2021/12/16

Apolloscientific

Product number: OR52053
Product name: 6-(Hydroxymethyl)pyridine-2-carboxylic acid 95+%
Packaging: 1g
Price: $196
Updated: 2021/12/16

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6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID Chemical Properties,Usage,Production

Synthesis

41337-81-9

1197-10-0

General procedure for the synthesis of 6-carboxypyridine-2-methanol from ethyl 6-hydroxymethylpyridine-2-carboxylate: ethyl 6-hydroxymethylpyridine-2-carboxylate (200 mg, 1.1 mmol) was dissolved in methanol (1 mL). Subsequently, 2 N NaOH aqueous solution (1 mL) was added slowly and the reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, the reaction mixture was acidified to pH=3 with 2 N HCl. The solvent was removed by concentration under reduced pressure, and the residue was dissolved in methanol and filtered. The filtrate was concentrated under reduced pressure to give 6-carboxypyridine-2-methanol (150 mg, 89% yield, white solid).1H NMR (400 MHz, CD3OD) δ: 5.05 (s, 2H), 8.34 (d, J=8.0 Hz, 1H), 8.47 (d, J=8.0 Hz, 1H), 8.73 (d, J=8.0 Hz, 1H).

References

[1] Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1994, vol. 49, # 8, p. 1127 - 1136
[2] Patent: WO2004/113281, 2004, A1. Location in patent: Page 57
[3] Journal of the American Chemical Society, 1982, vol. 104, # 8, p. 2251 - 2257

6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID Suppliers

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View Lastest Price from 6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID manufacturers

Career Henan Chemical Co

Product: 6-(Hydroxymethyl)picolinic acid 1197-10-0
Price: US $1.00/g
Min. Order: 1g
Purity: 95-99%
Supply Ability: 1ton
Release date: 2020-01-09

1197-10-0, 6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACIDRelated Search:

THIOSTREPTON dimethyl 4-chloropyridine-2,6-dicarboxylate Pyridine-2,6-dicarboxylic acid Chelidamic acid Diethyl 2,6-pyridinedicarboxylate Dimethyl 2,6-Pyridinedicarboxylate 2,6-Pyridinedicarboxylic acid monomethyl ester 4-Pyridoxic acid [4,4'-BIPYRIDINE]-2,2',6,6'-TETRACARBOXYLIC ACID TETRAETHYL ESTER Ethyl2,6-PyridinedicarboxylateMono thiopeptin B DIETHYL 4-CHLORO-2,6-PYRIDINEDICARBOXYLATE 2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE siomycin 6-Hydroxymethyl-pyridine-2-carboxylic acid methyl ester Dimethyl 4-methoxy-2,6-Pyridinedicarboxylate Pyridine-2,4,6-tricarboxylic acid 4-Hydroxymethyl-pyridine-2-carboxylic acid methyl ester

6-HYDROXYMETHYL-PYRIDINE-2-CARBOXYLIC ACID

2-Carboxy-6-(hydroxymethyl)pyridine, 6-(Hydroxymethyl)picolinic acid

6-(hydroxymethyl)picolinic acid

6-(Hydroxymethyl)pyridine-2-carboxylic acid 95+%

2-Pyridinecarboxylic acid, 6-(hydroxymethyl)-

6-(Hydroxymethyl)picolinicaci

1197-10-0

Heterocycle-Pyridine series

Carboxylic Acids

Pyridines

Carboxylic Acids