Description References
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Diethyl succinate

Description References
Product Name
Diethyl succinate
CAS No.
123-25-1
Chemical Name
Diethyl succinate
Synonyms
diethyl butanedioate;Clorius;ETHYL SUCCINATE;SUCCINIC ACID DIETHYL ESTER;BUTANEDIOIC ACID DIETHYL ESTER;Diethylester kyseliny jantarove;Diethyl ester of butanedioic acid;FEMA 2377;Diethyl succite;Diethylsuccinat
CBNumber
CB9852963
Molecular Formula
C8H14O4
Formula Weight
174.19
MOL File
123-25-1.mol
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Diethyl succinate Property

Melting point:
-20 °C (lit.)
Boiling point:
218 °C (lit.)
Density 
1.047 g/mL at 25 °C (lit.)
vapor density 
6 (vs air)
vapor pressure 
1.33 hPa (55 °C)
FEMA 
2377 | DIETHYL SUCCINATE
refractive index 
n20/D 1.42(lit.)
Flash point:
195 °F
storage temp. 
Store below +30°C.
solubility 
2.00g/l
form 
Liquid
color 
Clear colorless to yellow
Odor
at 100.00 %. mild fruity cooked apple ylang
Odor Type
fruity
Water Solubility 
Slightly soluble in water.
JECFA Number
617
Merck 
14,8869
BRN 
907645
Dielectric constant
6.6(30℃)
LogP
1.4 at 40℃
CAS DataBase Reference
123-25-1(CAS DataBase Reference)
NIST Chemistry Reference
Diethyl succinate(123-25-1)
EPA Substance Registry System
Butanedioic acid, 1,4-diethyl ester (123-25-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25-22-S24/25
WGK Germany 
2
RTECS 
WM7400000
TSCA 
Yes
HS Code 
29171990
Toxicity
LD50 orally in Rabbit: 8530 mg/kg LD50 dermal Rat > 5000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W237712
Product name
Diethyl succinate
Purity
natural, ≥99%, FG
Packaging
100g
Price
$61.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W237712
Product name
Diethyl succinate
Purity
natural, ≥99%, FG
Packaging
1kg
Price
$209
Updated
2024/03/01
Sigma-Aldrich
Product number
W237712
Product name
Diethyl succinate
Purity
natural, ≥99%, FG
Packaging
5kg
Price
$923
Updated
2024/03/01
Sigma-Aldrich
Product number
W237701
Product name
Diethyl succinate
Purity
≥99%, FCC, FG
Packaging
1kg
Price
$76.5
Updated
2024/03/01
Sigma-Aldrich
Product number
W237701
Product name
Diethyl succinate
Purity
≥99%, FCC, FG
Packaging
5kg
Price
$210
Updated
2024/03/01
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Diethyl succinate Chemical Properties,Usage,Production

Description

Diethyl succinate is obtained by the direct esterification of a carboxylic acid and an alcohol in the presence of concentrated H2SO4 in benzene solution. It has a faint, pleasant odor. It occurs naturally in apple, raspberry, cognac, rum, whiskey, cider, sherry, plum brandy, apple brandy, grape brandy, cherry brandy, cocoa, arrack and red, white, port, strawberry and sparking wines.
It is used as a flavor agent in foods including nonalcoholic/alcoholic beverages, baked goods, frozen dairy, hard/soft candy, gelatins, and puddings.

References

[1] George A. Burdock (2016) Fenaroli’s Hanbook of Flavor Ingredients, Sixth Edition
[2] https://en.wikipedia.org/wiki/Diethyl_succinate

Chemical Properties

Diethyl succinate is the diethyl ester of succinate. It is a colorless liquid with a faint, pleasant odor. miscible with ethanol and ether, soluble in acetone, insoluble in water.

Occurrence

Reported found in apple, raspberry, cognac, rum, whiskey, cider, sherry, plum brandy, apple brandy, grape brandy, cherry brandy, cocoa, arrack and red, white, port, strawberry and sparkling wines.

Uses

Diethyl succinate can be used as solvent; food flavoring agent; organic synthesis intermediate; gas chromatography stationary solution (maximum use temperature 60°C, solvent is ether). Alkyl succinates have been used as ashless dispersants and detergent additives for lubricating oils.

Uses

Diethyl Succinate is a diester molecule present naturally in plant and animal tissues. Used commonly in fragrances and food flavourings.

Preparation

Diethyl succinate is synthesized by esterification of succinic acid and ethanol; by direct esterification of the acid in the presence of concentrated H2SO4 in benzene solution.

Definition

ChEBI: Diethyl succinate is a fatty acid ester.

Aroma threshold values

Aroma characteristics at 1.0%: fruity, waxy, floral and slightly musty.

Taste threshold values

Taste charReported found in apple, raspberry, cognac, rum, whiskey, cider, sherry, plum brandy, apple brandy, grape brandy, cherry brandy, cocoa, arrack and red, white, port, strawberry and sparkling wines. acteristics at 10 to 100 ppm: chemical earthy, fruity with a pulpy mouthfeel

Synthesis Reference(s)

The Journal of Organic Chemistry, 56, p. 6720, 1991 DOI: 10.1021/jo00023a047
Tetrahedron Letters, 28, p. 2393, 1987 DOI: 10.1016/S0040-4039(00)96133-1

General Description

Diethyl succinate(DES) is a diethyl ester with succinate molecules. It has two ester groups and is majorly used in fragrances. It produced by the esterification of succinic acid with ethanol.

Flammability and Explosibility

Non flammable

Biochem/physiol Actions

Taste at 10-100 ppm

Safety Profile

Mildly toxic by ingestion. A skin and eye irritant. Combustible liquid. Reaction with ethyl trifluoroacetate + sodium hydride may cause a fire or explosion. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Purification Methods

Dry the succinate with MgSO4, and distil it at 15mm pressure. [Beilstein 2 IV 1914.]

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View Lastest Price from Diethyl succinate manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
Diethyl succinate 123-25-1
Price
US $50.00/kg
Min. Order
1kg
Purity
99.10%
Supply Ability
50000kg
Release date
2024-04-25
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Diethyl succinate 123-25-1
Price
US $50.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000KG/Week
Release date
2024-04-24
Hebei Yanxi Chemical Co., Ltd.
Product
Diethyl succinate 123-25-1
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-29

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