L(-)-10-Camphorsulfonyl chloride
L(-)-10-Camphorsulfonyl chloride Basic information
- Product Name:
- L(-)-10-Camphorsulfonyl chloride
- Synonyms:
-
- L(-)-10-CAMPHORSULFONYL CHLORIDE
- (-)-CAMPHOR-10-SULFONYL CHLORIDE
- (1R)-(-)-10-CAMPHORSULFONYL CHLORIDE
- (1R)-(-)-CAMPHOR-10-SULPHONYL CHLORIDE
- (1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORIDE
- (1R)-CAMPHOR-10-SULFONIC ACID CHLORIDE
- (1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE
- (-)-10-CAMPHORSULFONYL CHLORIDE
- CAS:
- 39262-22-1
- MF:
- C10H15ClO3S
- MW:
- 250.74
- EINECS:
- 628-057-2
- Product Categories:
-
- Peptide
- Intermediates & Fine Chemicals
- chiral
- Chiral Reagents
- Pharmaceuticals
- Sulfonyl Chlorides
- Bicyclic Monoterpenes
- Biochemistry
- for Resolution of Alcohols & Thiols
- for Resolution of Bases
- Optical Resolution
- Synthetic Organic Chemistry
- Terpenes
- Mol File:
- 39262-22-1.mol
L(-)-10-Camphorsulfonyl chloride Chemical Properties
- Melting point:
- 66-68 °C(lit.)
- alpha
- -33 º (c=3, chloroform)
- Boiling point:
- 349.4±15.0 °C(Predicted)
- Density
- 1.331±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Acetone, Dichloromethane, Ethyl Acetate, Methanol
- form
- Solid
- color
- White
- optical activity
- [α]18/D 33°, c = 3 in chloroform
- Water Solubility
- Decomposes
- Sensitive
- Moisture Sensitive
- BRN
- 3205975
- InChIKey
- BGABKEVTHIJBIW-UHFFFAOYSA-N
- CAS DataBase Reference
- 39262-22-1(CAS DataBase Reference)
Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29147090
MSDS
- Language:English Provider:(1R)-Camphor-10-sulfonic acid chloride
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
L(-)-10-Camphorsulfonyl chloride Usage And Synthesis
Chemical Properties
white to light yellow crystal powde
Uses
A chiral derivative of Camphor.
Uses
L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.
Purification Methods
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
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L(-)-10-Camphorsulfonyl chloride(39262-22-1)Related Product Information
- Ethanesulfonyl chloride
- Calcium chloride
- Benzyl chloride
- Tosyl chloride
- Choline chloride
- Ammonium chloride
- (2R)-Bornane-10,2-sultam
- Sulfuryl chloride
- (-)-CAMPHOR
- 4-Nitrobenzenesulfonyl chloride
- Mepiquat chloride
- Camphor
- (1R)-(-)-10-Camphorsulfonic acid
- Benzenesulfonyl chloride
- Sodium chloride
- Polyvinyl chloride
- L-carnitine
- (1R,2R)-(-)-1,2-Diaminocyclohexane