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1,3-Butadiene diepoxide

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1,3-Butadiene diepoxide Basic information

Product Name:
1,3-Butadiene diepoxide
Synonyms:
  • 1,3-BUTADIENE DIEPOXIDE
  • 1,2:3,4-Diepoxybutane (I,T)
  • 1,3-Butadiene diepoxide, GC 98%
  • Bioxirane, 2,2-: (1,2:3,4-Diepoxybutane)
  • 2,2'-bioxirane 1,2:3,4-diepoxybutane
  • 1,3-Butadiene diepoxide,1,2,3,4-Diepoxybutane
  • 1,2:3,4-Diepoxybutane 1g [1464-53-5]
  • 1,3-Butadiene diepoxide, 98+%, AcroSeal
CAS:
1464-53-5
MF:
C4H6O2
MW:
86.09
EINECS:
215-979-1
Product Categories:
  • -
Mol File:
1464-53-5.mol
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1,3-Butadiene diepoxide Chemical Properties

Melting point:
2-4 °C(lit.)
Boiling point:
56-58 °C25 mm Hg(lit.)
alpha 
0°(neat)
Density 
1.113 g/mL at 25 °C(lit.)
vapor pressure 
25 mm Hg ( 56 °C)
refractive index 
n20/D 1.434(lit.)
Flash point:
114 °F
storage temp. 
0-6°C
form 
neat
Specific Gravity
1.1
Water Solubility 
Soluble in water (1000 g/L).
Merck 
14,3676
BRN 
79831
CAS DataBase Reference
1464-53-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T+
Risk Statements 
45-46-24/25-26-34-10
Safety Statements 
53-45-36/37/39-28-26
RIDADR 
UN 3384 6.1/PG 1
WGK Germany 
1
RTECS 
EJ8225000
8-10-18
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29109000

MSDS

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1,3-Butadiene diepoxide Usage And Synthesis

Chemical Properties

clear colorless to very slightly yellow liquid

Uses

Diepoxybutane has been used as a research chemical, as a chemical intermediate, as a curing agent for polymers, as a cross-linking agent for textile fabrics, and to prevent microbial spoilage (IARC 1976, HSDB 2009). It has also been used to synthesize erythritol and pharmaceuticals (HSDB 2009). Because of its cross-linking properties, diepoxybutane is used as a test agent in the diagnosis of Fanconi anemia, which is characterized by chromosomal instability (Auerbach et al. 1989).

General Description

Colorless liquid. Used in curing polymers; crosslinking textile fibers and to prevent spoilage.

Air & Water Reactions

Highly Flammable

Reactivity Profile

Epoxides, such as 1,3-BUTADIENE DIEPOXIDE, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Hazard

Probable carcinogen; neoplastigen; tumorigenic; poison; mutagen.

Health Hazard

Severe skin and eye irritant. Accidental minor exposure caused swelling of the eyelids, upper respiratory tract irritation and painful eye irritation 6 hours after exposure.NOTE: The dl- and meso-forms (CAS Registry Numbers 298-18-0 and 564-00-1, respectively) as well as the L(-) form (CAS Registry Number 30031-64-2) have all been determined to be positive animal carcinogens.

Fire Hazard

When heated to decomposition 1,3-BUTADIENE DIEPOXIDE emits acrid smoke and irritating fumes.

Carcinogenicity

Diepoxybutane is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

Regulations

Environmental Protection Agency (EPA)
Comprehensive Environmental Response, Compensation, and Liability Act Reportable quantity (RQ) = 10 lb.
Emergency Planning and Community Right-To-Know Act Reportable quantity (RQ) = 10 lb.
Threshold planning quantity (TPQ) = 500 lb.
Toxics Release Inventory: Diepoxybutane is subject to reporting requirements.
Resource Conservation and Recovery Act
Listed Hazardous Waste: Waste code for which the listing is based wholly or partly on the presence of diepoxybutane = U085. Listed as a hazardous constituent of waste.

1,3-Butadiene diepoxideSupplier

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