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TUTIN

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TUTIN Basic information

Product Name:
TUTIN
Synonyms:
  • (7R,8R)-1aβ,1b,5,6,6a,7aβ-Hexahydro-1bα,6β-dihydroxy-6aα-methyl-8-(1-methylethenyl)spiro[2α,5α-methano-7H-oxireno[3,4]cyclopent[1,2-d]oxepine-7,2'-oxiran]-3(2H)-one
  • (1As-(1aalpha,1bbeta,2beta,5beta,6alpha,6abeta,7beta,7aalpha,8S*))-hexahydro-1B,6-dihydroxy-6A-methyl-8-(1-methylethenyl)spiro(2,5-methano-7H-oxireno(3,4)cyclopent(1,2-D)oxepin-7,2'-oxiran)-3(2alpha H)-one
  • Spiro(2,5-methano-7H-oxireno(3,4)cyclopent(1,2-D)oxepin-7,2'-oxiran)-3(2ah)-one, 1A-beta,1B,5A,6,6A,7A-beta-hexahydro-1B-alpha,6-beta-dihydroxy-8A-isopropenyl-6A-alpha-methyl-
  • Toot poison
  • Tutine
  • Tutu
  • TUTIN
  • Spiro[2,5-methano-7H-oxireno[3,4]cyclopent[1,2-d]oxepin-7,2'-oxiran]-3(2H)-one, hexahydro-1b,6-dihydroxy-6a-methyl-8-(1-methylethenyl)-, (1aS,1bR,2S,2'R,5R,6S,6aR,7aR,8R)-
CAS:
2571-22-4
MF:
C15H18O6
MW:
294.3
Mol File:
2571-22-4.mol
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TUTIN Chemical Properties

Melting point:
209-212°; mp 204-205° (Wakamatsu)
alpha 
D20 +9.25° (alc); D17 +13.9° (c = 0.75, methanol)
Boiling point:
356.07°C (rough estimate)
Density 
1.1975 (rough estimate)
refractive index 
1.4359 (estimate)
storage temp. 
-20°C
pka
12.83±0.70(Predicted)
LogP
1.380 (est)
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Safety Information

Toxicity
LD50 i.p. in female mice: 3.0 mg/kg (Jarboe)
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TUTIN Usage And Synthesis

Uses

Coriaria Lactone can be used in biological study for effects of tutin and its derivatives on GAD and GABA-T in Pseudelatia separata tested as novel active ingredients for pest control. It is also utilized in agricultural use for anti-feedant activities and effects of tutin and its derivatives on mythimna separata and its physiological parameters.

Definition

ChEBI: Tutin is a gamma-lactone.

TUTINSupplier

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