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Cylopropylmethyl chloride

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Cylopropylmethyl chloride Basic information

Product Name:
Cylopropylmethyl chloride
Synonyms:
  • CYCLOPROPYLMETHYL CHLORIDE
  • (CHLOROMETHYL)CYCLOPROPANE
  • Cyclopropane, (chloromethyl)-
  • Cyclopropane,(chloromethyl)-
  • Cylopropylmethylchloride
  • Cyclopropylmethychloride
  • Cyclopropylmethyl Chloride, Pract.
  • 1 -(Chloromethyl)cyclopropane
CAS:
5911-08-0
MF:
C4H7Cl
MW:
90.55
EINECS:
227-632-1
Product Categories:
  • Cycloalkanes
  • Alkyl
  • Halogenated Hydrocarbons
  • Organic Building Blocks
Mol File:
5911-08-0.mol
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Cylopropylmethyl chloride Chemical Properties

Melting point:
-91°C
Boiling point:
87-89 °C(lit.)
Density 
0.98 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.435(lit.)
Flash point:
29 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
soluble in Chloroform, Methanol
form 
clear liquid
color 
Colorless to Almost colorless
Water Solubility 
Not miscible in water.
BRN 
635697
InChIKey
ZVTQWXCKQTUVPY-UHFFFAOYSA-N
CAS DataBase Reference
5911-08-0(CAS DataBase Reference)
NIST Chemistry Reference
(Chloromethyl)cyclopropane(5911-08-0)
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Safety Information

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-26-36/37/39
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
HazardClass 
3
PackingGroup 
II
HS Code 
29035990

MSDS

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Cylopropylmethyl chloride Usage And Synthesis

Chemical Properties

Colorless to pale yellow liquid

Uses

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

Uses

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0

General Description

(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

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