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Chloroform-d

Basic information Water peak Application Safety Supplier Related

Chloroform-d Basic information

Product Name:
Chloroform-d
Synonyms:
  • Deuterotrichloromethane
  • Trichloro(2H)methane
  • trichloro-deuterio-methane
  • CHLOROFORM-D >99.95 (ATOM % D) STAB.
  • CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.75ML)
  • CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.25ML)
  • Chloroform-d, 99.8 atom % D, anhydrous
  • CHLOROFORM-D, 99.8 ATOM % D(CONTAINS 1%V/V TMS)
CAS:
865-49-6
MF:
CCl3D
MW:
120.38
EINECS:
212-742-4
Product Categories:
  • Chloroform-d
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Mol File:
865-49-6.mol
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Chloroform-d Chemical Properties

Melting point:
−64 °C(lit.)
Boiling point:
60.9 °C(lit.)
Density 
1.500 g/mL at 25 °C(lit.)
vapor pressure 
211 hPa (20 °C)
refractive index 
n20/D 1.444(lit.)
Flash point:
62°C
storage temp. 
Store at +2°C to +8°C.
solubility 
Miscible with organic solvents, ethyl acetate and acetone.
form 
Liquid
Specific Gravity
1.505
color 
White to beige
Sensitive 
Moisture Sensitive
BRN 
1697633
Exposure limits
ACGIH: TWA 10 ppm
OSHA: Ceiling 50 ppm(240 mg/m3)
NIOSH: IDLH 500 ppm; STEL 2 ppm(9.78 mg/m3)
Stability:
Stable. Incompatible with strong bases, alkali metals, aluminium, magnesium, strong oxidizing agents.
InChIKey
HEDRZPFGACZZDS-MICDWDOJSA-N
LogP
1.5-1.6 at 20-23℃ and pH9
Surface tension
72.3mN/m at 998.5mg/L and 20℃
CAS DataBase Reference
865-49-6(CAS DataBase Reference)
EPA Substance Registry System
Chloroform-d (865-49-6)
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Safety Information

Hazard Codes 
Xn,T
Risk Statements 
22-38-40-48/20/22-48/20-36/38-20/22-63
Safety Statements 
36/37
RIDADR 
UN 1888 6.1/PG 3
WGK Germany 
2
HazardClass 
6.1
PackingGroup 
III
HS Code 
28459000
Toxicity
LD50 orally in Rabbit: 695 mg/kg LD50 dermal Rabbit > 3980 mg/kg

MSDS

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Chloroform-d Usage And Synthesis

Water peak

The position of the water peak in different deuterated reagents is not the same. The water peak of heavy water is about 4.67 ppm. There is a trend that the more water the low field.
Chloroform-D is less soluble with water and the water content is low, so its water peak near 1.59 ppm. Deuterated acetone is about 2.8 ppm and the deuterated dimethylsulfoxide has a water peak of about 3.4 ppm. If water is added to deuterated acetone, the water peak will gradually move to a low field and eventually stop at about 4.7 ppm.

Application

Reagents for nuclear magnetic instruments

Chemical Properties

colourless liquid

Uses

Chloroform-d is widely used in the organic solvent for the NMR analysis.

Uses

Chloroform-d may be used in the synthesis of dichlorofluoromethane-d (DCFM).

Uses

Labelled Chloroform, generally in trimethylsilane solution, used in NMR spectroscopy as a solvent. Unlabelled chloroform has been used an an anaesthetic due to its action on the central nervous system .

Definition

ChEBI: Deuterated chloroform is a deuterated compound that is an isotopologue of chloroform in which the hydrogen atom is replaced with deuterium. Commonly used as a solvent in proton NMR spectroscopy. It has a role as a non-polar solvent, a NMR solvent and a NMR chemical shift reference compound. It is a deuterated compound and a member of chloromethanes.

General Description

Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.

Chloroform-d Preparation Products And Raw materials

Preparation Products

Chloroform-dSupplier

Ningbo cuiying chemical technology co. LTD Gold
Tel
4008-608250 18957423231
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2317559463@qq.com
Products Intro
Product Name:Chloroform-d
CAS:865-49-6
Purity:99.80%D,99.9% Package:10kg;100kg;1000kg
Shanghai Jizhi Biochemical Technology Co. Ltd. Gold
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Products Intro
Product Name:Chloroform-d
CAS:865-49-6
Purity:D,99.8%+0.03% V/V TMS Package:10X0.6mL;10X0.55ml;25mL;100g Remarks:C44710
Meryer (Shanghai) Chemical Technology Co., Ltd. Gold
Tel
021-61259108 18621169109
Email
market03@meryer.com
Products Intro
Product Name:Chloroform D
CAS:865-49-6
Purity:99.80%D,stab. with Ag Package:10*0.6Ml;100Ml Remarks:g
Wuhan eastop Technology Co., ltd.6 Gold
Tel
027-87382885 17702779303
Email
service@isotopechina.com
Products Intro
Product Name:Chloroform-D
CAS:865-49-6
Purity:99.8% Package:5克/RMB 17;6克/RMB 19;10克/RMB 16
Qingdao Tenglong microwave technology co., LTD. Gold
Tel
0532-83818797 18561885118
Email
market@tlwb.com.cn
Products Intro
Product Name:CHLOROFORM-D (D,99.8%) +0.03% V/V TMS
CAS:865-49-6
Purity:99.5% Package:10X0.6ML;50G;100G Remarks:DLM-7TC