Chloroform-d
Chloroform-d Basic information
- Product Name:
- Chloroform-d
- Synonyms:
-
- Deuterotrichloromethane
- Trichloro(2H)methane
- trichloro-deuterio-methane
- CHLOROFORM-D >99.95 (ATOM % D) STAB.
- CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.75ML)
- CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.25ML)
- Chloroform-d, 99.8 atom % D, anhydrous
- CHLOROFORM-D, 99.8 ATOM % D(CONTAINS 1%V/V TMS)
- CAS:
- 865-49-6
- MF:
- CCl3D
- MW:
- 120.38
- EINECS:
- 212-742-4
- Product Categories:
-
- Chloroform-d
- Aldrich 100% NMR Solvents for High Resolution
- Alphabetical Listings
- C
- Chloroform
- High Resolution NMR
- High Throughput NMR
- Labware
- NMR
- NMR Solvents
- NMR Solvents and Reagents
- Solvent by Application
- Solvent by Type
- Solvents
- Organics
- Solvents for High Throughput NMR
- Spectroscopy Solvents (IR
- Stable Isotopes
- Tubes and Accessories
- UV/Vis)
- Aldrich High Purity NMR Solvents for Routine NMR
- Routine NMR
- Mol File:
- 865-49-6.mol
Chloroform-d Chemical Properties
- Melting point:
- −64 °C(lit.)
- Boiling point:
- 60.9 °C(lit.)
- Density
- 1.500 g/mL at 25 °C(lit.)
- vapor pressure
- 211 hPa (20 °C)
- refractive index
- n20/D 1.444(lit.)
- Flash point:
- 62°C
- storage temp.
- Store at +2°C to +8°C.
- solubility
- Miscible with organic solvents, ethyl acetate and acetone.
- form
- Liquid
- Specific Gravity
- 1.505
- color
- White to beige
- Sensitive
- Moisture Sensitive
- BRN
- 1697633
- Exposure limits
- ACGIH: TWA 10 ppm
OSHA: Ceiling 50 ppm(240 mg/m3)
NIOSH: IDLH 500 ppm; STEL 2 ppm(9.78 mg/m3) - Stability:
- Stable. Incompatible with strong bases, alkali metals, aluminium, magnesium, strong oxidizing agents.
- InChIKey
- HEDRZPFGACZZDS-MICDWDOJSA-N
- LogP
- 1.5-1.6 at 20-23℃ and pH9
- Surface tension
- 72.3mN/m at 998.5mg/L and 20℃
- CAS DataBase Reference
- 865-49-6(CAS DataBase Reference)
- EPA Substance Registry System
- Chloroform-d (865-49-6)
Safety Information
- Hazard Codes
- Xn,T
- Risk Statements
- 22-38-40-48/20/22-48/20-36/38-20/22-63
- Safety Statements
- 36/37
- RIDADR
- UN 1888 6.1/PG 3
- WGK Germany
- 2
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 28459000
- Toxicity
- LD50 orally in Rabbit: 695 mg/kg LD50 dermal Rabbit > 3980 mg/kg
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Chloroform-d Usage And Synthesis
Water peak
The position of the water peak in different deuterated reagents is not the same. The water peak of heavy water is about 4.67 ppm. There is a trend that the more water the low field.
Chloroform-D is less soluble with water and the water content is low, so its water peak near 1.59 ppm. Deuterated acetone is about 2.8 ppm and the deuterated dimethylsulfoxide has a water peak of about 3.4 ppm. If water is added to deuterated acetone, the water peak will gradually move to a low field and eventually stop at about 4.7 ppm.
Application
Reagents for nuclear magnetic instruments
Chemical Properties
colourless liquid
Uses
Chloroform-d is widely used in the organic solvent for the NMR analysis.
Uses
Chloroform-d may be used in the synthesis of dichlorofluoromethane-d (DCFM).
Uses
Labelled Chloroform, generally in trimethylsilane solution, used in NMR spectroscopy as a solvent. Unlabelled chloroform has been used an an anaesthetic due to its action on the central nervous system .
Definition
ChEBI: Deuterated chloroform is a deuterated compound that is an isotopologue of chloroform in which the hydrogen atom is replaced with deuterium. Commonly used as a solvent in proton NMR spectroscopy. It has a role as a non-polar solvent, a NMR solvent and a NMR chemical shift reference compound. It is a deuterated compound and a member of chloromethanes.
General Description
Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.
Chloroform-dSupplier
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- Products Intro
- Product Name:Chloroform-d
CAS:865-49-6
Purity:99.80%D,99.9% Package:10kg;100kg;1000kg
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- Products Intro
- Product Name:Chloroform-d
CAS:865-49-6
Purity:D,99.8%+0.03% V/V TMS Package:10X0.6mL;10X0.55ml;25mL;100g Remarks:C44710
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- Products Intro
- Product Name:Chloroform D
CAS:865-49-6
Purity:99.80%D,stab. with Ag Package:10*0.6Ml;100Ml Remarks:g
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- Products Intro
- Product Name:Chloroform-D
CAS:865-49-6
Purity:99.8% Package:5克/RMB 17;6克/RMB 19;10克/RMB 16
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- Products Intro
- Product Name:CHLOROFORM-D (D,99.8%) +0.03% V/V TMS
CAS:865-49-6
Purity:99.5% Package:10X0.6ML;50G;100G Remarks:DLM-7TC
Chloroform-d(865-49-6)Related Product Information
- Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate
- 5α-Cholestane
- NMR REF STD, 0.0485M TRIPHENYLPHOSPHATE IN CHLOROFORM-D, 99.9 ATOM % D,NMR REF STD, 0.0485M TRIPHENYLPHOSPHATEIN CHLOROFORM-D,99.8 ATOM % D
- PHENOL:CHLOROFORM:ISOAMYLALCOHOL 49.5:49 .5:1,PHENOL:CHLOROFORM:ISOAMYL ALC. 125:24:1, FOR MOL. BIOLOGY
- BETA-SITOSTEROL 1X1ML CHLOROFORM 100UG/M L
- Dichloromethane
- 100 MG/ML CHOLESTERYL ACETATE IN CHLOROFORM-D
- Chloroform
- Chloroform-d
- DICHLOROMETHANE D
- CHLOROFORM-D + 1% TMS (V/V)
- ACETONE-D6
- ACETONE CHLOROFORM HEMIHYDRATE DAB, PH. EUR., B.P., N. F., PH. FRANC.
- TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT 98+%
- METHANE (D1)
- DEUTERIUM HYDRIDE
- 0.1% ETHYLBENZENE IN CHLOROFORM-D (540 PP TUBE)
- 30% MENTHOL IN CHLOROFORM-D