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ChemicalBook >  Product Catalog >  Organic Chemistry >  Amides >  Acyclic polyamines and their derivatives >  (-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE

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(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Basic information

Product Name:
(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE
Synonyms:
  • (-)-BIS[(S)-ALPHA-METHYLBENZYL]AMINE HYDROCHLORIDE
  • (S,S)-(-)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE
  • (S,S)-(-)-BIS(1-PHENYLETHYL)AMINE HYDROCHLORIDE
  • [S-(R*,R*)]-(-)-BIS(-ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE
  • (S,S)-(-)-Bis(α-methylbenzyl)amineHydrochloride
  • (-)-Bis[(S)-1-phenylethyl]amineHCl
  • (-)-bis[(s)-α-methylbenzyl]amine hydrochloride
  • [s-(r*,r*)]-(-)-bis(-α-methylbenzyl)amine hydrochloride
CAS:
40648-92-8
MF:
C16H20ClN
MW:
261.79
Product Categories:
  • chiral
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
Mol File:
40648-92-8.mol
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(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Chemical Properties

Melting point:
261-263 °C(lit.)
refractive index 
-73 ° (C=3, EtOH)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
color 
White to Almost white
optical activity
[α]20/D 73±2°, c = 3% in ethanol
BRN 
4723969
InChI
InChI=1/C16H19N.ClH/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16;/h3-14,17H,1-2H3;1H/t13-,14-;/s3
InChIKey
ZBQCLJZOKDRAOW-FGVWXQOBNA-N
SMILES
C1(=CC=CC=C1)[C@H](C)N[C@@H](C)C1=CC=CC=C1.Cl |&1:6,9,r|
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36-36/37/39
WGK Germany 
3
3
HS Code 
2921.49.5000

MSDS

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(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

(?)-Bis[(S)-1-phenylethyl]amine hydrochloride can be used:

  • To prepare phosphoramidite (Feringa) ligand named (R)-2,2′-binaphthoyl-(S,S)-di-(1-phenylethyl)aminoylphosphine.
  • As a chiral amphiphilic cation to encapsulate polyoxometalates, which act as supramolecular assemblies employed in the asymmetric oxidation of sulfides.
  • As a chiral shift agent in the determination of enantiomeric purity of tris(tetrachlorobenzenediolato) phosphate(V) anion using 31P NMR.

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDESupplier

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