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2-CYCLOHEXEN-1-OL

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2-CYCLOHEXEN-1-OL Basic information

Product Name:
2-CYCLOHEXEN-1-OL
Synonyms:
  • CYCLOHEX-2-ENOL
  • 2-CYCLOHEXENOL
  • 2-CYCLOHEXEN-1-OL
  • 2-CYCLOHEXENE-1-OL
  • 1-Cyclohexen-3-ol
  • 3-Hydroxycyclohexene
  • Cyclohexen-3-ol
  • cyclohex-2-ene-1-ol
CAS:
822-67-3
MF:
C6H10O
MW:
98.14
EINECS:
212-501-3
Product Categories:
  • Chiral Alcohols
  • Alkenes
  • Cyclic
  • Organic Building Blocks
Mol File:
822-67-3.mol
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2-CYCLOHEXEN-1-OL Chemical Properties

Melting point:
107-108℃
Boiling point:
164-166 °C(lit.)
Density 
1 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.487(lit.)
Flash point:
137 °F
storage temp. 
Refrigerator, under inert atmosphere
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
14.70±0.20(Predicted)
form 
Liquid
color 
Clear colorless
BRN 
1446187
InChIKey
PQANGXXSEABURG-UHFFFAOYSA-N
CAS DataBase Reference
822-67-3(CAS DataBase Reference)
EPA Substance Registry System
2-Cyclohexen-1-ol (822-67-3)
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
23-24/25
RIDADR 
UN 1987 3/PG 3
WGK Germany 
3
HazardClass 
3.2
PackingGroup 
III
HS Code 
29061990

MSDS

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2-CYCLOHEXEN-1-OL Usage And Synthesis

Chemical Properties

Clear colorless liquid

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 527, 1984 DOI: 10.1016/S0040-4039(00)99928-3

Purification Methods

Purify 2-cyclohexen-1-ol by distillation through a short Vigreux column (p 11). The 2,4-dinitrobenzoyl derivative has m 120.5o, and the phenylurethane has m 107o. [Pedersen et al. Org Synth 48 18 1968, Cook J Chem Soc 1774 1938, Deiding & Hartman J Am Chem Soc 75 3725 1953, Beilstein 6 IV 196.]

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